{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:52:32Z","timestamp":1787071952196,"version":"build-2736575974"},"reference-count":43,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T00:00:00Z","timestamp":1785801600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T00:00:00Z","timestamp":1785801600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T00:00:00Z","timestamp":1785801600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100010664","name":"H2020 Future and Emerging Technologies","doi-asserted-by":"publisher","award":["964735"],"award-info":[{"award-number":["964735"]}],"id":[{"id":"10.13039\/100010664","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017697","name":"Graphene Flagship","doi-asserted-by":"publisher","award":["881603"],"award-info":[{"award-number":["881603"]}],"id":[{"id":"10.13039\/100017697","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018703","name":"HORIZON EUROPE European Innovation Council","doi-asserted-by":"publisher","award":["101099552"],"award-info":[{"award-number":["101099552"]}],"id":[{"id":"10.13039\/100018703","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-10-LABX-0051"],"award-info":[{"award-number":["ANR-10-LABX-0051"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-18-CE24-0007"],"award-info":[{"award-number":["ANR-18-CE24-0007"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-20-CE24-0015"],"award-info":[{"award-number":["ANR-20-CE24-0015"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-21-ESRE-0025"],"award-info":[{"award-number":["ANR-21-ESRE-0025"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-22-CE09-0012-03"],"award-info":[{"award-number":["ANR-22-CE09-0012-03"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-22-CE24-0022-01"],"award-info":[{"award-number":["ANR-22-CE24-0022-01"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-22-EXSP-0003"],"award-info":[{"award-number":["ANR-22-EXSP-0003"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-22-EXSP-0007"],"award-info":[{"award-number":["ANR-22-EXSP-0007"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-22-EXSP-0009"],"award-info":[{"award-number":["ANR-22-EXSP-0009"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-22-PEEL-0011"],"award-info":[{"award-number":["ANR-22-PEEL-0011"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Swiss National Science Foundation","doi-asserted-by":"publisher","award":["205602"],"award-info":[{"award-number":["205602"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Horizon 2020 European Commission","doi-asserted-by":"publisher","award":["833973"],"award-info":[{"award-number":["833973"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Two-dimensional transition metal dichalcogenide (TMD) interfaces offer a versatile platform for studying quantum phenomena and developing device functionalities. When distinct TMD monolayers are stacked vertically or laterally stitched, their interfaces can exhibit unique electronic band alignments, giving rise to long-lived interlayer excitons, charge transfer effects, and moire\u0301 superlattices with correlated states. Here, we demonstrate that the interface between a large variety of two different epitaxially grown TMD monolayers controls the intensity and sign of the Rashba spin splitting, which is probed using THz spintronic emission. Optimized TMD heterobilayers, such as HfSe2\/PtSe2, show enhanced THz emission that surpasses the spin-to-charge conversion efficiency of bulk TMDs, confirming the presence of Rashba states with large spin splitting at the interface. By combining spin- and angle-resolved photoemission spectroscopy with density functional theory, we reveal that the electronic hybridization between the two different TMD monolayers gives rise to extended in-gap states with strong Rashba spin\u2013orbit coupling. The choice of TMD layers enables to engineer the sign and strength of spin-to-charge conversion in van der Waals heterobilayers, enabling to build efficient and tunable THz spintronic emitters.<\/jats:p>","DOI":"10.1021\/acsnano.6c08362","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T13:03:02Z","timestamp":1785934982000},"page":"22875-22886","source":"Crossref","is-referenced-by-count":0,"title":["Rashba\nEngineering at van der Waals Interfaces"],"prefix":"10.1021","volume":"20","author":[{"given":"Rahul","family":"Sharma","sequence":"first","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soumya","family":"Mukherjee","sequence":"additional","affiliation":[{"name":"Laboratoire de Physique de l\u2019Ecole normale supe\u0301rieure, ENS, Universite\u0301 PSL, CNRS, Sorbonne Universite\u0301, Universite\u0301 de Paris , 24 rue Lhomond , ,","place":["Paris, France, 75005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fatima","family":"Ibrahim","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gae\u0301tan","family":"Verdierre","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Libor","family":"Voja\u0301c\u030cek","sequence":"additional","affiliation":[{"name":"Paul Scherrer Institute PSI , , ,","place":["Villigen, Switzerland, CH-5232"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Mic\u030cica","sequence":"additional","affiliation":[{"name":"Laboratoire de Physique de l\u2019Ecole normale supe\u0301rieure, ENS, Universite\u0301 PSL, CNRS, Sorbonne Universite\u0301, Universite\u0301 de Paris , 24 rue Lhomond , ,","place":["Paris, France, 75005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-1769-4620","authenticated-orcid":true,"given":"Sylvain","family":"Massabeau","sequence":"additional","affiliation":[{"name":"Laboratoire Albert Fert, CNRS, Thales, Universite\u0301 Paris-Saclay , ,","place":["Palaiseau, France, F-91767"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oliver","family":"Paull","sequence":"additional","affiliation":[{"name":"Laboratoire Albert Fert, CNRS, Thales, Universite\u0301 Paris-Saclay , ,","place":["Palaiseau, France, F-91767"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vincent","family":"Polewczyk","sequence":"additional","affiliation":[{"name":"Universite\u0301 Paris-Saclay, UVSQ, CNRS, GEMaC , ,","place":["Versailles, France, 78000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9764-0199","authenticated-orcid":true,"given":"Nicola","family":"Marzari","sequence":"additional","affiliation":[{"name":"Paul Scherrer Institute PSI , , ,","place":["Villigen, Switzerland, CH-5232"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alain","family":"Marty","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Isabelle","family":"Gomes de Moraes","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fre\u0301de\u0301ric","family":"Bonell","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4354-4257","authenticated-orcid":true,"given":"Juliette","family":"Mangeney","sequence":"additional","affiliation":[{"name":"Laboratoire de Physique de l\u2019Ecole normale supe\u0301rieure, ENS, Universite\u0301 PSL, CNRS, Sorbonne Universite\u0301, Universite\u0301 de Paris , 24 rue Lhomond , ,","place":["Paris, France, 75005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jero\u0302me","family":"Tignon","sequence":"additional","affiliation":[{"name":"Laboratoire de Physique de l\u2019Ecole normale supe\u0301rieure, ENS, Universite\u0301 PSL, CNRS, Sorbonne Universite\u0301, Universite\u0301 de Paris , 24 rue Lhomond , ,","place":["Paris, France, 75005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gauthier","family":"Krizman","sequence":"additional","affiliation":[{"name":"Laboratoire de Physique de l\u2019Ecole normale supe\u0301rieure, ENS, Universite\u0301 PSL, CNRS, Sorbonne Universite\u0301, Universite\u0301 de Paris , 24 rue Lhomond , ,","place":["Paris, France, 75005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anupam","family":"Jana","sequence":"additional","affiliation":[{"name":"CNR-IOM Laboratorio TASC , ,","place":["Trieste, Italy, I-34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3208-802X","authenticated-orcid":true,"given":"Jun","family":"Fujii","sequence":"additional","affiliation":[{"name":"CNR-IOM Laboratorio TASC , ,","place":["Trieste, Italy, I-34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivana","family":"Vobornik","sequence":"additional","affiliation":[{"name":"CNR-IOM Laboratorio TASC , ,","place":["Trieste, Italy, I-34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Federico","family":"Mazzola","sequence":"additional","affiliation":[{"name":"University of Padova , , ,","place":["Padova, Italy, 35131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9283-3821","authenticated-orcid":true,"given":"Jing","family":"Li","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA-LETI , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Leticia","family":"Melo Costa","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA-LETI , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olivier","family":"Renault","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA-LETI , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8870-3696","authenticated-orcid":true,"given":"Adrien","family":"Michon","sequence":"additional","affiliation":[{"name":"Universite\u0301 Co\u0302te d\u2019Azur, CNRS, CRHEA, rue Bernard Gre\u0301gory , ,","place":["Valbonne, France, 06560"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Henri","family":"Jaffre\u0300s","sequence":"additional","affiliation":[{"name":"Laboratoire Albert Fert, CNRS, Thales, Universite\u0301 Paris-Saclay , ,","place":["Palaiseau, France, F-91767"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean-Marie","family":"George","sequence":"additional","affiliation":[{"name":"Laboratoire Albert Fert, CNRS, Thales, Universite\u0301 Paris-Saclay , ,","place":["Palaiseau, France, F-91767"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9232-7622","authenticated-orcid":true,"given":"Mairbek","family":"Chshiev","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sukhdeep","family":"Dhillon","sequence":"additional","affiliation":[{"name":"Laboratoire de Physique de l\u2019Ecole normale supe\u0301rieure, ENS, Universite\u0301 PSL, CNRS, Sorbonne Universite\u0301, Universite\u0301 de Paris , 24 rue Lhomond , ,","place":["Paris, France, 75005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8247-4677","authenticated-orcid":true,"given":"Matthieu","family":"Jamet","sequence":"additional","affiliation":[{"name":"Universite\u0301 Grenoble Alpes, CEA, CNRS, IRIG-SPINTEC , ,","place":["Grenoble, France, 38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,4]]},"reference":[{"key":"2026081810312449500_cit1","doi-asserted-by":"publisher","first-page":"35","DOI":"10.1038\/s41586-018-0770-2","article-title":"Scalable energy-efficient magnetoelectric spin\u2013orbit\nlogic","volume":"565","author":"Manipatruni","year":"2019","journal-title":"Nature"},{"key":"2026081810312449500_cit2","doi-asserted-by":"publisher","DOI":"10.1038\/s44306-024-00044-1","article-title":"Recent progress in spin-orbit torque\nmagnetic random-access memory","volume":"2","author":"Nguyen","year":"2024","journal-title":"npj Spintronics"},{"key":"2026081810312449500_cit3","doi-asserted-by":"publisher","first-page":"459","DOI":"10.1016\/0375-9601(71)90196-4","article-title":"Current-induced spin orientation\nof electrons in semiconductors","volume":"35","author":"Dyakonov","year":"1971","journal-title":"Phys. Lett.\nA"},{"key":"2026081810312449500_cit4","first-page":"78","article-title":"Properties of 2D electron\ngas with lifted spectral degeneracy","volume":"39","author":"Bychkov","year":"1984","journal-title":"JETP Lett."},{"key":"2026081810312449500_cit5","doi-asserted-by":"publisher","DOI":"10.1063\/1.3587173","article-title":"Inverse spin-Hall effect induced\nby spin pumping in metallic system","volume":"109","author":"Ando","year":"2011","journal-title":"J. Appl.\nPhys."},{"key":"2026081810312449500_cit6","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3944","article-title":"Spin-to-charge conversion using Rashba coupling at the interface\nbetween non-magnetic materials","volume":"4","author":"Sa\u0301nchez","year":"2013","journal-title":"Nat. Commun."},{"key":"2026081810312449500_cit7","doi-asserted-by":"publisher","first-page":"483","DOI":"10.1038\/nphoton.2016.91","article-title":"Efficient metallic spintronic\nemitters of ultrabroadband terahertz radiation","volume":"10","author":"Seifert","year":"2016","journal-title":"Nat. Photonics"},{"key":"2026081810312449500_cit8","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.120.207207","article-title":"Control of Terahertz Emission by Ultrafast Spin-Charge\nCurrent Conversion at Rashba Interfaces","volume":"120","author":"Jungfleisch","year":"2018","journal-title":"Phys.\nRev. Lett."},{"key":"2026081810312449500_cit9","doi-asserted-by":"publisher","first-page":"663","DOI":"10.1038\/s41586-022-04768-0","article-title":"Two-dimensional materials\nprospects for non-volatile spintronic memories","volume":"606","author":"Yang","year":"2022","journal-title":"Nature"},{"key":"2026081810312449500_cit10","doi-asserted-by":"publisher","DOI":"10.1063\/5.0054865","article-title":"Control of\nspin\u2013charge conversion in van der Waals heterostructures","volume":"9","author":"Galceran","year":"2021","journal-title":"APL Mater."},{"key":"2026081810312449500_cit11","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304243","article-title":"Atomic-Layer Controlled\nTransition from Inverse Rashba\u2013Edelstein Effect to Inverse\nSpin Hall Effect in 2D PtSe2 Probed by THz Spintronic Emission","volume":"36","author":"Abdukayumov","year":"2024","journal-title":"Adv. Mater."},{"key":"2026081810312449500_cit12","doi-asserted-by":"publisher","DOI":"10.1103\/l41n-qxpd","article-title":"Monolayer Control of\nSpin-Charge Conversion in van der Waals Heterostructures","volume":"135","author":"Abdukayumov","year":"2025","journal-title":"Phys. Rev. Lett."},{"key":"2026081810312449500_cit13","doi-asserted-by":"publisher","first-page":"347","DOI":"10.1038\/s41567-018-0406-3","article-title":"Far out-of-equilibrium\nspin populations trigger giant spin injection into atomically thin\nMoS2","volume":"15","author":"Cheng","year":"2019","journal-title":"Nat. Phys."},{"key":"2026081810312449500_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202506031","article-title":"Terahertz Electronic\nand Spin Currents in Wafer-Scale Van der Waals Bi2Se3\/WSe2 Heterostructures\nand Polymorphs","volume":"38","author":"Mic\u030cica","year":"2026","journal-title":"Adv. Mater."},{"key":"2026081810312449500_cit15","doi-asserted-by":"publisher","first-page":"2643","DOI":"10.1039\/C4CS00301B","article-title":"Electronic\nstructures and theoretical modelling of two-dimensional group-VIB\ntransition metal dichalcogenides","volume":"44","author":"Liu","year":"2015","journal-title":"Chem. Soc.\nRev."},{"key":"2026081810312449500_cit16","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2017.33","article-title":"2D transition\nmetal dichalcogenides","volume":"2","author":"Manzeli","year":"2017","journal-title":"Nat. Rev. Mater."},{"key":"2026081810312449500_cit17","doi-asserted-by":"publisher","DOI":"10.1063\/5.0256072","article-title":"Inverse Rashba\nEdelstein THz emission modulation induced by ferroelectricity in CoFeB\/PtSe2\/MoSe2\/\/LiNbO3\nsystems","volume":"13","author":"Massabeau","year":"2025","journal-title":"APL Mater."},{"key":"2026081810312449500_cit18","doi-asserted-by":"publisher","first-page":"2319","DOI":"10.1021\/acsnano.7b07446","article-title":"Beyond van der Waals Interaction: The\nCase of MoSe2 Epitaxially Grown on Few-Layer Graphene","volume":"12","author":"Dau","year":"2018","journal-title":"ACS Nano"},{"key":"2026081810312449500_cit19","doi-asserted-by":"publisher","first-page":"3503","DOI":"10.1021\/jacs.0c12809","article-title":"What Dictates Rashba Splitting in 2D van der Waals\nHeterobilayers","volume":"143","author":"Gupta","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026081810312449500_cit20","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6528\/ab80fe","article-title":"New approach\nfor the molecular beam\nepitaxy growth of scalable WSe2 monolayers","volume":"31","author":"Vergnaud","year":"2020","journal-title":"Nanotechnology"},{"key":"2026081810312449500_cit21","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202301124","article-title":"Spin-Momentum\nLocking\nand Ultrafast Spin-Charge Conversion in Ultrathin Epitaxial Bi1 \u2013\nxSbx Topological Insulator","volume":"10","author":"Rongione","year":"2023","journal-title":"Adv. Sci."},{"key":"2026081810312449500_cit22","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1016\/S0039-6028(00)00441-6","article-title":"A simple tight-binding model of spin\u2013orbit\nsplitting\nof sp-derived surface states","volume":"459","author":"Petersen","year":"2000","journal-title":"Surf. Sci."},{"key":"2026081810312449500_cit23","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/21\/6\/064239","article-title":"A first-principles\nstudy on the Rashba effect in surface systems","volume":"21","author":"Nagano","year":"2009","journal-title":"J. Phys.: Condens. Matter"},{"key":"2026081810312449500_cit24","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.90.115434","article-title":"Microscopic\norigin of the relativistic splitting of surface states","volume":"90","author":"Krasovskii","year":"2014","journal-title":"Phys. Rev. B"},{"key":"2026081810312449500_cit25","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.101.174423","article-title":"Semirealistic tight-binding\nmodel for spin-orbit torques","volume":"101","author":"Manchon","year":"2020","journal-title":"Phys. Rev. B"},{"key":"2026081810312449500_cit26","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.90.165108","article-title":"Theoretical model for Rashba spin-orbit\ninteraction in d electrons","volume":"90","author":"Shanavas","year":"2014","journal-title":"Phys. Rev. B"},{"key":"2026081810312449500_cit27","doi-asserted-by":"publisher","DOI":"10.1088\/2053-1583\/aa7b03","article-title":"Scanning tunneling spectroscopy of van der Waals graphene\/semiconductor\ninterfaces: absence of Fermi level pinning","volume":"4","author":"Le Quang","year":"2017","journal-title":"2D Mater."},{"key":"2026081810312449500_cit28","doi-asserted-by":"publisher","first-page":"1187","DOI":"10.1038\/s41563-019-0467-4","article-title":"Mapping spin\u2013charge\nconversion to the band structure in a topological oxide two-dimensional\nelectron gas","volume":"18","author":"Vaz","year":"2019","journal-title":"Nat. Mater."},{"key":"2026081810312449500_cit29","doi-asserted-by":"publisher","DOI":"10.1088\/1361-648X\/ad5e2b","article-title":"Theory of\nspin and orbital Edelstein effects","volume":"36","author":"Johansson","year":"2024","journal-title":"J. Phys.:Condens.\nMatter"},{"key":"2026081810312449500_cit30","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202300222","article-title":"Edge Conductivity in PtSe2 Nanostructures","volume":"5","author":"Kempt","year":"2024","journal-title":"Small Struct."},{"key":"2026081810312449500_cit31","doi-asserted-by":"publisher","first-page":"11889","DOI":"10.1021\/acs.nanolett.4c03029","article-title":"Field-Free\nSpin\u2013Orbit Torque Switching in Janus Chromium Dichalcogenides","volume":"24","author":"Voja\u0301c\u030cek","year":"2024","journal-title":"Nano Lett."},{"key":"2026081810312449500_cit32","doi-asserted-by":"publisher","DOI":"10.1038\/s41524-021-00498-5","article-title":"High performance\nWannier interpolation of Berry curvature and related quantities with\nWannierBerri code","volume":"7","author":"Tsirkin","year":"2021","journal-title":"npj Comput. Mater."},{"key":"2026081810312449500_cit33","doi-asserted-by":"publisher","DOI":"10.1063\/1.2404663","article-title":"Influence\nof the\nexchange screening parameter on the performance of screened hybrid\nfunctionals","volume":"125","author":"Krukau","year":"2006","journal-title":"J. Chem. Phys."},{"key":"2026081810312449500_cit34","doi-asserted-by":"publisher","DOI":"10.1063\/1.3503972","article-title":"Direct growth of few-layer graphene\non 6H-SiC and 3C-SiC\/Si via propane chemical vapor deposition","volume":"97","author":"Michon","year":"2010","journal-title":"Appl. Phys. Lett."},{"key":"2026081810312449500_cit35","doi-asserted-by":"publisher","DOI":"10.1038\/s41699-025-00554-4","article-title":"Self-limited monolayer graphene growth\non SiC with propane-hydrogen CVD","volume":"9","author":"Mastropasqua","year":"2025","journal-title":"npj 2D Mater.\nAppl."},{"key":"2026081810312449500_cit36","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.17953","article-title":"Projector\naugmented-wave method","volume":"50","author":"Blo\u0308chl","year":"1994","journal-title":"Phys. Rev. B"},{"key":"2026081810312449500_cit37","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.47.558","article-title":"Ab initio molecular\ndynamics for liquid metals","volume":"47","author":"Kresse","year":"1993","journal-title":"Phys. Rev. B"},{"key":"2026081810312449500_cit38","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169","article-title":"Efficient\niterative schemes for ab initio total-energy\ncalculations using a plane-wave basis set","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys.\nRev. B"},{"key":"2026081810312449500_cit39","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","article-title":"Efficiency\nof ab-initio total energy calculations for\nmetals and semiconductors using a plane-wave basis set","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput. Mater. Sci."},{"key":"2026081810312449500_cit40","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865","article-title":"Generalized\nGradient Approximation\nMade Simple","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"2026081810312449500_cit41","doi-asserted-by":"publisher","first-page":"11814","DOI":"10.1021\/jp106469x","article-title":"Improved\nDescription of the Structure of Molecular and Layered Crystals: Ab\nInitio DFT Calculations with van der Waals Corrections","volume":"114","author":"Buc\u030cko","year":"2010","journal-title":"J. Phys. Chem. A"},{"key":"2026081810312449500_cit42","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.56.12847","article-title":"Maximally localized generalized Wannier functions for\ncomposite energy bands","volume":"56","author":"Marzari","year":"1997","journal-title":"Phys. Rev. B"},{"key":"2026081810312449500_cit43","doi-asserted-by":"publisher","first-page":"2309","DOI":"10.1016\/j.cpc.2014.05.003","article-title":"An updated version of wannier90:\nA tool for obtaining maximally-localised Wannier functions","volume":"185","author":"Mostofi","year":"2014","journal-title":"Comput. Phys. Commun."}],"container-title":["ACS Nano"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsnano.6c08362","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/20\/32\/22875\/66379920\/acsnano.6c08362.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/20\/32\/22875\/66379920\/acsnano.6c08362.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:10:37Z","timestamp":1787069437000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/ancac3\/article\/20\/32\/22875\/5242314\/Rashba-Engineering-at-van-der-Waals-Interfaces"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,4]]},"references-count":43,"journal-issue":{"issue":"32","published-online":{"date-parts":[[2026,8,4]]},"published-print":{"date-parts":[[2026,8,18]]}},"URL":"https:\/\/doi.org\/10.1021\/acsnano.6c08362","relation":{},"ISSN":["1936-0851","1936-086X"],"issn-type":[{"value":"1936-0851","type":"print"},{"value":"1936-086X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,4]]}}}