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Here, the chemical characteristics of As nanophases in the rhizosphere as a hotspot for rice-soil-microbe interactions were fingerprinted at a single-particle resolution, revealing their chemical speciation and interactions with soil microbiota. The initial As particle characteristics (speciation and size) governed bioavailability through distinct transformation pathways mediated by particle-specific elemental associations. Specifically, nanoscale As sulfide and ferrihydrite with adsorbed As resulted in greater rice uptake than their microscale treatments, whereas nanoscale scorodite exhibited a comparable bioavailability. Analyses at the individual nanoparticle level revealed that 75\u201390% of As-bearing particles were associated with other metals regardless of the initial particle type. Within the As particles associated with Fe, the Fe-to-As mass ratios ranged from 27 to 41 despite low co-occurrence probabilities (&amp;lt;30%). The redistributions of As, Fe, and associated elements (e.g., Si\/Mn\/Zr) observed at the individual particle level aligned with the metabolic capacity of enriched rhizosphere microbiomes to drive biogeochemical cycling. Such microscale interactions might contribute to As transformation and plant resistance. By resolving metastable nanophase behavior at critical soil-plant interfaces, this work provides mechanistic insights into their dynamic speciation and bioavailability during key agricultural phases, advancing predictive frameworks for As mobility in agroecosystems.<\/jats:p>","DOI":"10.1021\/acsnano.6c10025","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T09:01:43Z","timestamp":1791450103000},"page":"27795-27806","source":"Crossref","is-referenced-by-count":0,"title":["Arsenic\nFingerprint and Microbiome Reconstruction\nof Rhizosphere-Specific Nanophases in Flooded Paddy Soil"],"prefix":"10.1021","volume":"20","author":[{"given":"Chenxu","family":"Li","sequence":"first","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Miao","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5666-1145","authenticated-orcid":true,"given":"Du","family":"Chen","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-1013-6596","authenticated-orcid":true,"given":"Qianhai","family":"Zhou","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-2400-5693","authenticated-orcid":true,"given":"Chaohuang","family":"Chen","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-5553-1648","authenticated-orcid":true,"given":"Xunheng","family":"Jiang","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6201-2873","authenticated-orcid":true,"given":"Jie","family":"Hou","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhao","family":"Wu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3146-3828","authenticated-orcid":true,"given":"Kun","family":"Yang","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9662-7195","authenticated-orcid":true,"given":"Daohui","family":"Lin","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5044-277X","authenticated-orcid":true,"given":"Lizhong","family":"Zhu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0369-4848","authenticated-orcid":true,"given":"Jiang","family":"Xu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"issue":"6744","key":"2026102008171367300_cit1","doi-asserted-by":"publisher","first-page":"316","DOI":"10.1126\/science.adr5214","article-title":"Global\nsoil pollution by toxic metals threatens agriculture and human\nhealth","volume":"388","author":"Hou","year":"2025","journal-title":"Science"},{"issue":"7","key":"2026102008171367300_cit2","doi-asserted-by":"publisher","first-page":"674","DOI":"10.1038\/s44221-024-00268-9","article-title":"MnO2-modified activated carbon and granular\nnano-TiO2 in tandem succeed in treating domestic well water\narsenic\nat point of use","volume":"2","author":"Duan","year":"2024","journal-title":"Nat. Water"},{"key":"2026102008171367300_cit3","doi-asserted-by":"publisher","first-page":"184","DOI":"10.1126\/science.321.5886.184","article-title":"Arsenic and\npaddy rice: a neglected cancer risk?","volume":"321","author":"Stone","year":"2008","journal-title":"Science"},{"key":"2026102008171367300_cit4","doi-asserted-by":"publisher","first-page":"175896","DOI":"10.1016\/j.scitotenv.2024.175896","article-title":"Predicting the risk\nof arsenic accumulation in soil-rice system in\nAsian monsoon region","volume":"952","author":"Ban","year":"2024","journal-title":"Sci. Total Environ."},{"issue":"6","key":"2026102008171367300_cit5","doi-asserted-by":"publisher","first-page":"766","DOI":"10.1038\/s41893-024-01341-7","article-title":"Escalating arsenic contamination\nthroughout Chinese soils","volume":"7","author":"Zhang","year":"2024","journal-title":"Nat. Sustainable"},{"issue":"6434","key":"2026102008171367300_cit6","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau8299","article-title":"Natural, incidental,\nand engineered nanomaterials and their impacts\non the Earth system","volume":"363","author":"Hochella","year":"2019","journal-title":"Science"},{"issue":"1\u20133","key":"2026102008171367300_cit7","doi-asserted-by":"publisher","first-page":"133","DOI":"10.1016\/S0048-9697(01)00903-2","article-title":"Role of microbes in controlling the speciation\nof arsenic and production\nof arsines in contaminated soils","volume":"285","author":"Turpeinen","year":"2002","journal-title":"Sci. Total\nEnviron."},{"issue":"3","key":"2026102008171367300_cit8","doi-asserted-by":"publisher","first-page":"1763","DOI":"10.1021\/acs.est.1c07039","article-title":"Extraction and quantification\nof nanoparticulate mercury in natural\nsoils","volume":"56","author":"Cai","year":"2022","journal-title":"Environ. Sci. Technol."},{"key":"2026102008171367300_cit9","doi-asserted-by":"publisher","first-page":"109768","DOI":"10.1016\/j.jenvman.2019.109768","article-title":"Effects of long-term\npaddy rice cultivation on soil arsenic speciation","volume":"254","author":"Yang","year":"2020","journal-title":"J. Environ. Manage."},{"issue":"17","key":"2026102008171367300_cit10","doi-asserted-by":"publisher","first-page":"7135","DOI":"10.1021\/es201677z","article-title":"Arsenic speciation and phytoavailability in contaminated soils using\na sequential extraction procedure and XANES spectroscopy","volume":"45","author":"Niazi","year":"2011","journal-title":"Environ. Sci. 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Technol."},{"issue":"44","key":"2026102008171367300_cit13","doi-asserted-by":"publisher","first-page":"19774","DOI":"10.1021\/acs.est.4c05570","article-title":"Size-dependent elemental composition in individual magnetite nanoparticles\ngenerated from coal-fired power plant regulating their pulmonary cytotoxicity","volume":"58","author":"Shi","year":"2024","journal-title":"Environ. Sci. Technol."},{"issue":"5","key":"2026102008171367300_cit14","doi-asserted-by":"publisher","first-page":"2990","DOI":"10.1021\/acs.est.1c02950","article-title":"Distinguishing engineered TiO2 nanomaterials from natural\nTi nanomaterials in soil using spICP-TOFMS and machine learning","volume":"56","author":"Bland","year":"2022","journal-title":"Environ. Sci. Technol."},{"key":"2026102008171367300_cit15","doi-asserted-by":"publisher","first-page":"403","DOI":"10.1016\/j.watres.2018.04.034","article-title":"Arsenic speciation dynamics in paddy rice soil-water environment:\nsources, physico-chemical, and biological factors - A review","volume":"140","author":"Kumarathilaka","year":"2018","journal-title":"Water Res."},{"issue":"1","key":"2026102008171367300_cit16","doi-asserted-by":"publisher","first-page":"52","DOI":"10.1038\/s43586-023-00235-w","article-title":"Inductively coupled plasma mass spectrometry","volume":"3","author":"Van Acker","year":"2023","journal-title":"Nat. Rev. Methods Primers"},{"issue":"41","key":"2026102008171367300_cit17","doi-asserted-by":"publisher","first-page":"18222","DOI":"10.1021\/acs.est.4c03116","article-title":"Aqueous and colloidal dynamics in size-fractionated paddy soil aggregates\nwith multiple metal contaminants under redox alternations","volume":"58","author":"Zhou","year":"2024","journal-title":"Environ. Sci. Technol."},{"issue":"26","key":"2026102008171367300_cit18","doi-asserted-by":"publisher","first-page":"9843","DOI":"10.1021\/acs.est.3c03051","article-title":"Mobilization of Colloid- and Nanoparticle-Bound Arsenic in Contaminated\nPaddy Soils during Reduction and Reoxidation","volume":"57","author":"Hu","year":"2023","journal-title":"Environ. Sci. Technol."},{"issue":"18","key":"2026102008171367300_cit19","doi-asserted-by":"publisher","first-page":"12393","DOI":"10.1021\/acs.est.1c03572","article-title":"Impacts of sediment particle grain size and mercury speciation on\nmercury bioavailability potential","volume":"55","author":"Xu","year":"2021","journal-title":"Environ.\nSci. Technol."},{"issue":"22","key":"2026102008171367300_cit20","doi-asserted-by":"publisher","first-page":"13275","DOI":"10.1021\/acs.est.9b03886","article-title":"Single particle characterization and total elemental concentration\nmeasurements in polar ice using continuous flow analysis-inductively\ncoupled plasma time-of-flight mass spectrometry","volume":"53","author":"Erhardt","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"2026102008171367300_cit21","doi-asserted-by":"publisher","first-page":"16891","DOI":"10.1021\/acs.est.4c05291","article-title":"Generational specific recruitment of arsenic- and antimony-reducing\nmicroorganisms in plant root-associated niches for adapting to metalloid-metal\npollution","volume":"58","author":"Yu","year":"2024","journal-title":"Environ. Sci. Technol."},{"issue":"2","key":"2026102008171367300_cit22","doi-asserted-by":"publisher","first-page":"1001","DOI":"10.1021\/es403877s","article-title":"Arsenic uptake by rice is influenced by microbe-mediated\narsenic\nredox changes in the rhizosphere","volume":"48","author":"Jia","year":"2014","journal-title":"Environ. Sci.\nTechnol."},{"issue":"9","key":"2026102008171367300_cit23","doi-asserted-by":"publisher","first-page":"883","DOI":"10.1016\/j.tibtech.2017.06.014","article-title":"Sphingomonads in microbe-assisted phytoremediation:\ntackling soil pollution","volume":"35","author":"Gatheru Waigi","year":"2017","journal-title":"Trends Biotechnol."},{"issue":"1\u20132","key":"2026102008171367300_cit24","doi-asserted-by":"publisher","first-page":"75","DOI":"10.1007\/s11104-016-2829-x","article-title":"Inoculation of Fe\/Mn-oxidizing\nbacteria enhances Fe\/Mn plaque formation\nand reduces Cd and As accumulation in rice plant tissues","volume":"404","author":"Dong","year":"2016","journal-title":"Plant Soil"},{"key":"2026102008171367300_cit25","doi-asserted-by":"publisher","first-page":"117389","DOI":"10.1016\/j.envpol.2021.117389","article-title":"Arsenic behavior in soil-plant system and its detoxification\nmechanisms\nin plants: A review","volume":"286","author":"Khan","year":"2021","journal-title":"Environ. Pollut."},{"key":"2026102008171367300_cit26","doi-asserted-by":"publisher","first-page":"616","DOI":"10.1021\/acs.est.7b05176","article-title":"Mineralogical controls\non the bioaccessibility of arsenic in Fe(III)\u2013As(V)\ncoprecipitates","volume":"52","author":"Ehlert","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"2026102008171367300_cit27","doi-asserted-by":"publisher","first-page":"136838","DOI":"10.1016\/j.jhazmat.2024.136838","article-title":"Arsenic bioaccessibility\nin environmentally important arsenic minerals","volume":"485","author":"Drahota","year":"2025","journal-title":"J. Hazard. Mater."},{"key":"2026102008171367300_cit28","doi-asserted-by":"publisher","first-page":"145","DOI":"10.1016\/j.jhazmat.2015.04.011","article-title":"Arsenic\nbioaccessibility in contaminated soils: Coupling in vitro\nassays with sequential and HNO3 extraction","volume":"295","author":"Li","year":"2015","journal-title":"J. Hazard. Mater."},{"key":"2026102008171367300_cit29","doi-asserted-by":"publisher","first-page":"128274","DOI":"10.1016\/j.jhazmat.2022.128274","article-title":"Effects of Fe(II)-induced\ntransformation of scorodite on arsenic\nsolubility","volume":"429","author":"Zhou","year":"2022","journal-title":"J. Hazard. Mater."},{"key":"2026102008171367300_cit30","doi-asserted-by":"publisher","first-page":"1550","DOI":"10.3389\/fmicb.2018.01550","article-title":"Reduction and morphological\ntransformation of synthetic nanophase\niron oxide minerals by hyperthermophilic archaea","volume":"9","author":"Kashyap","year":"2018","journal-title":"Front. Microbiol."},{"key":"2026102008171367300_cit31","doi-asserted-by":"publisher","first-page":"121163","DOI":"10.1016\/j.watres.2024.121163","article-title":"Microbial-mediated oxidative\ndissolution of orpiment and realgar\nin circumneutral aquatic environments","volume":"251","author":"Sun","year":"2024","journal-title":"Water\nRes."},{"key":"2026102008171367300_cit32","doi-asserted-by":"publisher","first-page":"183","DOI":"10.1016\/j.cej.2017.09.078","article-title":"The As behavior of natural\narsenical-containing colloidal ferric\noxyhydroxide reacted with sulfate reducing bacteria","volume":"332","author":"Fan","year":"2018","journal-title":"Chem. Eng. J."},{"issue":"8","key":"2026102008171367300_cit33","doi-asserted-by":"publisher","first-page":"3982","DOI":"10.1021\/acs.est.4c11232","article-title":"Nano-scale insights\ninto clay minerals regulating the Fe(II)-catalyzed\nferrihydrite transformation under anoxic conditions","volume":"59","author":"Wei","year":"2025","journal-title":"Environ. Sci. Technol."},{"issue":"15","key":"2026102008171367300_cit34","doi-asserted-by":"publisher","first-page":"8892","DOI":"10.1021\/acs.est.9b00109","article-title":"Coupled kinetics model for microbially mediated arsenic reduction\nand adsorption\/desorption on iron oxides: Role of arsenic desorption\ninduced by microbes","volume":"53","author":"Lin","year":"2019","journal-title":"Environ. Sci. Technol."},{"issue":"21","key":"2026102008171367300_cit35","doi-asserted-by":"publisher","first-page":"6709","DOI":"10.1021\/es061399f","article-title":"Scorodite dissolution\nkinetics: Implications for arsenic release","volume":"40","author":"Harvey","year":"2006","journal-title":"Environ. Sci. Technol."},{"issue":"7","key":"2026102008171367300_cit36","doi-asserted-by":"publisher","first-page":"1666","DOI":"10.1021\/acsearthspacechem.1c00373","article-title":"Mechanism of arsenic partitioning during sulfidation of As-sorbed\nferrihydrite nanoparticles","volume":"6","author":"Kumar","year":"2022","journal-title":"ACS Earth Space\nChem."},{"key":"2026102008171367300_cit37","doi-asserted-by":"publisher","first-page":"2102","DOI":"10.1039\/C9EN01427F","article-title":"FeS colloids \u2013\nformation and mobilization pathways in natural\nwaters","volume":"7","author":"Noe\u0308l","year":"2020","journal-title":"Environ. Sci.: Nano"},{"issue":"1","key":"2026102008171367300_cit38","doi-asserted-by":"publisher","first-page":"184","DOI":"10.1128\/AEM.00417-09","article-title":"Nanosized iron oxide colloids strongly enhance microbial iron reduction","volume":"76","author":"Bosch","year":"2010","journal-title":"Appl. Environ. Microbiol."},{"issue":"3","key":"2026102008171367300_cit39","doi-asserted-by":"publisher","first-page":"529","DOI":"10.1016\/j.gca.2008.10.030","article-title":"Arsenic distribution in the dissolved, colloidal and particulate\nsize fraction of experimental solutions rich in dissolved organic\nmatter and ferric iron","volume":"73","author":"Bauer","year":"2009","journal-title":"Geochim. Cosmochim.\nActa"},{"key":"2026102008171367300_cit40","doi-asserted-by":"publisher","first-page":"827","DOI":"10.1016\/j.plaphy.2021.06.039","article-title":"Exploration of silicate solubilizing bacteria for sustainable\nagriculture\nand silicon biogeochemical cycle","volume":"166","author":"Raturi","year":"2021","journal-title":"Plant Physiol.\nBiochem."},{"key":"2026102008171367300_cit41","doi-asserted-by":"publisher","first-page":"344","DOI":"10.1021\/es970421p","article-title":"Arsenite and Arsenate\nAdsorption on Ferrihydrite: Kinetics, Equilibrium,\nand Adsorption Envelopes","volume":"32","author":"Raven","year":"1998","journal-title":"Environ. Sci. Technol."},{"key":"2026102008171367300_cit42","doi-asserted-by":"publisher","first-page":"12453","DOI":"10.1021\/acs.est.3c03441","article-title":"Quantitative Contribution\nof Oxygen Vacancy Defects to Arsenate Immobilization\non Hematite","volume":"57","author":"Liu","year":"2023","journal-title":"Environ. Sci. Technol."},{"key":"2026102008171367300_cit43","doi-asserted-by":"publisher","first-page":"261","DOI":"10.1016\/j.jenvman.2016.07.068","article-title":"Adsorption Kinetics\nand Isotherms of Arsenite and Arsenate on Hematite\nNanoparticles and Aggregates","volume":"186","author":"Dickson","year":"2017","journal-title":"J. Environ. Manage."},{"issue":"1","key":"2026102008171367300_cit44","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1016\/j.seppur.2007.01.025","article-title":"Adsorption of inorganic\nand organic arsenic from aqueous solutions\nby polymeric Al\/Fe modified montmorillonite","volume":"56","author":"Ramesh","year":"2007","journal-title":"Sep. Purif. Technol."},{"key":"2026102008171367300_cit45","doi-asserted-by":"publisher","first-page":"334","DOI":"10.1016\/j.psep.2019.01.011","article-title":"Safety assessment and application of iron and manganese\nore tailings\nfor the remediation of As-contaminated soil","volume":"125","author":"Lei","year":"2019","journal-title":"Process. Saf. Environ."},{"key":"2026102008171367300_cit46","doi-asserted-by":"publisher","first-page":"592","DOI":"10.1016\/j.psep.2017.08.009","article-title":"Iron oxide and its modified\nforms as an adsorbent for arsenic removal:\nA comprehensive recent advancement","volume":"111","author":"Siddiqui","year":"2017","journal-title":"Process.\nSaf. 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