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However, the lack of a precise nanoscale integration approach and the limited understanding of interfacial interaction mechanisms hinder its further development. Herein, we describe a sequential assembly strategy to construct a strongly coupled dual antenna (Bi2Se3\/Au nanobipyramids)-reactor (Rh) for photocatalytic nitrogen reduction. This architecture enables strong coupling between topological surface states (TSS) and localized surface plasmonic resonance (LSPR), accompanied by directional interfacial electron transfer. Benefiting from such strong coupling, the constructed Bi2Se3\/Au dual antenna unit exhibits broadband light-harvesting capability, and the synergistically enhanced localized electromagnetic field further promotes electron enrichment on the Rh nanoparticles. Meanwhile, the Ohmic contact formed at the Bi2Se3\/Au interface facilitates the smooth injection of plasmon-induced hot electrons from Au into Bi2Se3 while suppressing the reverse transfer of TSS-excited electrons from Bi2Se3 to Au, enabling unidirectional interfacial electron transfer and effectively improving energetic electron utilization. Consequently, the optimized Bi2Se3\/Au\u2013Rh composite achieves a NH3 production rate of 122.7 \u03bcmol g\u20131 h\u20131 under visible\u2013near-infrared irradiation, which is approximately 23.6, 2.1, and 1.7 times as high as those of pure Rh (antenna-free system), Bi2Se3\u2013Rh (single-antenna system without LSPR), and bulk Bi2Se3\/Au\u2013Rh (single-antenna system without TSS), respectively. This work provides a promising strategy for designing topological-plasmonic hybrid photocatalysts toward solar-driven nitrogen fixation.<\/jats:p>","DOI":"10.1021\/acsnano.6c10508","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T15:01:30Z","timestamp":1787151690000},"page":"26179-26194","source":"Crossref","is-referenced-by-count":1,"title":["Strong Coupling\nbetween Topological Surface States\nand Localized Surface Plasmonic Resonance in a Dual Antenna-Reactor\nfor Enhanced N2 Photofixation"],"prefix":"10.1021","volume":"20","author":[{"given":"Ruoning","family":"Zhan","sequence":"first","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Senlin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5364-725X","authenticated-orcid":true,"given":"Mengqiu","family":"Cai","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Fang","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinying","family":"Hu","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8670-8397","authenticated-orcid":true,"given":"Xiuqiang","family":"Xie","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8290-0915","authenticated-orcid":true,"given":"Nan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,19]]},"reference":[{"key":"2026092909135430200_cit1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar6611","article-title":"Beyond Fossil Fuel\u2013Driven Nitrogen Transformations","volume":"360","author":"Chen","year":"2018","journal-title":"Science"},{"key":"2026092909135430200_cit2","doi-asserted-by":"publisher","first-page":"11334","DOI":"10.1039\/D3CS01075A","article-title":"Light-Driven\nNitrogen Fixation Routes for Green Ammonia Production","volume":"53","author":"Collado","year":"2024","journal-title":"Chem. Soc. 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Mater."},{"key":"2026092909135430200_cit46","doi-asserted-by":"publisher","first-page":"18417","DOI":"10.1021\/ja308030h","article-title":"Iodide-Mediated\nControl of Rhodium Epitaxial Growth on Well-Defined Noble Metal Nanocrystals:\nSynthesis, Characterization, and Structure-Dependent Catalytic Properties","volume":"134","author":"Sneed","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026092909135430200_cit47","doi-asserted-by":"publisher","first-page":"7734","DOI":"10.1021\/jacs.3c14586","article-title":"Construction of Gold\/Rhodium Freestanding Superstructures as Antenna-Reactor\nPhotocatalysts for Plasmon-Driven Nitrogen Fixation","volume":"146","author":"Yang","year":"2024","journal-title":"J. Am. Chem. 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