{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T12:23:28Z","timestamp":1788351808340,"version":"build-2803163510"},"reference-count":56,"publisher":"American Chemical Society (ACS)","issue":"17","license":[{"start":{"date-parts":[[2020,4,23]],"date-time":"2020-04-23T00:00:00Z","timestamp":1587600000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccby_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100005416","name":"Norges Forskningsr\u00e5d","doi-asserted-by":"publisher","award":["262229"],"award-info":[{"award-number":["262229"]}],"id":[{"id":"10.13039\/501100005416","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,5,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Single-crystal X-ray structures were obtained for the copper and \u03bc-oxodiiron complexes of 2,3,7,8,12,13,17,18-octafluoro-5,10,15-triphenylcorrole, hereafter denoted as Cu[F8TPC] and {Fe[F8TPC]}2O. A comparison with the crystal structures of other undecasubstituted Cu corroles, including those with H, Ar, Br, I, and CF3 as \u03b2-substituents, showed that the degree of saddling increases in the order: H \u2272 F &amp;lt; Ar \u2272 Br \u2272 I &amp;lt; CF3. In other words, Cu[F8TPC] is marginally more saddled than \u03b2-unsubstituted Cu triarylcorroles, but substantially less saddled than Cu undecaarylcorroles, \u03b2-octabromo-meso-triarylcorroles, and \u03b2-octaiodo-meso-triarylcorroles, and far less saddled than Cu \u03b2-octakis(trifluoromethyl)-meso-triarylcorroles. As for {Fe[F8TPC]}2O, the moderate quality of the structure did not allow us to draw firm conclusions in regard to bond length alternations in the corrole skeleton and hence also the question of ligand noninnocence. The Fe\u2013O bond distances, 1.712(8) and 1.724(8), however, are essentially identical to those observed for {Fe[TPFPC]}2O, where TPFPC3\u2013 is the trianion of 5,10,15-tris(pentafluorophenyl)corrole, suggesting that a partially noninnocent electronic structural description may be applicable for both compounds.<\/jats:p>","DOI":"10.1021\/acsomega.0c01035","type":"journal-article","created":{"date-parts":[[2020,4,23]],"date-time":"2020-04-23T07:41:45Z","timestamp":1587627705000},"page":"10176-10182","source":"Crossref","is-referenced-by-count":10,"title":["Molecular Structure of Copper and \u03bc-Oxodiiron Octafluorocorrole Derivatives:\nInsights into Ligand Noninnocence"],"prefix":"10.1021","volume":"5","author":[{"given":"Kolle E.","family":"Thomas","sequence":"first","affiliation":[{"name":"UiT\u2500The Arctic University of Norway , , ,","place":["Troms\u00f8, Norway, N-9037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0272-454X","authenticated-orcid":true,"given":"Nicholas S.","family":"Settineri","sequence":"additional","affiliation":[{"name":"Lawrence Berkeley National Laboratory , , , ,","place":["Berkeley, California, United States, 94720-8229"]},{"name":"University of California Berkeley , , , ,","place":["Berkeley, California, United States, 94720"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simon J.","family":"Teat","sequence":"additional","affiliation":[{"name":"Lawrence Berkeley National Laboratory , , , ,","place":["Berkeley, California, United States, 94720-8229"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Erik","family":"Steene","sequence":"additional","affiliation":[{"name":"UiT\u2500The Arctic University of Norway , , ,","place":["Troms\u00f8, Norway, N-9037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1161-6364","authenticated-orcid":true,"given":"Abhik","family":"Ghosh","sequence":"additional","affiliation":[{"name":"UiT\u2500The Arctic University of Norway , , ,","place":["Troms\u00f8, Norway, N-9037"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,4,23]]},"reference":[{"key":"2026090208082238100_cit1","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1016\/s0010-8545(00)80170-8","article-title":"Differences between the four halide\nligands, and discussion remarks on trigonal-bipyramidal complexes,\non oxidation states, and on diagonal elements of one-electron energy","volume":"1","author":"J\u00f8rgensen","year":"1966","journal-title":"Coord. 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