{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T08:22:21Z","timestamp":1788337341770,"version":"build-2803163510"},"reference-count":48,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2020,9,1]],"date-time":"2020-09-01T00:00:00Z","timestamp":1598918400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,9,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Composite materials have revealed remarkable activities in various catalytic applications. However, choosing an appropriate material to enhance the catalytic activity and stability is a major challenge in the field of catalysis. In this article, we reported vanadium phosphorus oxide (VPO)\/\u03b2-SiC as a stable composite material with good catalytic activity. VPO\/\u03b2-SiC composite materials with different compositions were fabricated by the impregnation technique to investigate the catalytic activity and stability of these materials in liquid-phase reactions. The physiochemical characteristics of the prepared catalysts were analyzed by several spectroscopic methods. The catalytic activities of VPO\/\u03b2-SiC composites were studied in a solvent-free oxidation of methanol using tert-butyl hydroperoxide (TBHP) as an oxidant. The reaction conditions were optimized by changing various reaction parameters. Under optimized reaction conditions, the 10 wt % VPO\/\u03b2-SiC composite showed 100% conversion with 89.8% selectivity to formaldehyde.<\/jats:p>","DOI":"10.1021\/acsomega.0c01921","type":"journal-article","created":{"date-parts":[[2020,9,1]],"date-time":"2020-09-01T15:47:17Z","timestamp":1598975237000},"page":"22808-22815","source":"Crossref","is-referenced-by-count":8,"title":["Facile Synthesis and Synergetic Interaction of VPO\/\u03b2-SiC Composites\ntoward Solvent-Free Oxidation of Methanol to Formaldehyde"],"prefix":"10.1021","volume":"5","author":[{"given":"Gopa","family":"Mishra","sequence":"first","affiliation":[{"name":"Institute of Minerals and Materials Technology, CSIR, C&MC , , ,","place":["Bhubaneswar, Odisha, India, 751013"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gobinda C.","family":"Behera","sequence":"additional","affiliation":[{"name":"M.P.C. Autonomous College , , Takhatpur , , ,","place":["Baripada, Odisha, India, 757003"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saroj Kumar","family":"Singh","sequence":"additional","affiliation":[{"name":"CSIR\u2500Institute of Minerals and Materials Technology , , , ,","place":["Bhubaneswar, Odisha, India, 751013"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7807-5561","authenticated-orcid":true,"given":"Kulamani","family":"Parida","sequence":"additional","affiliation":[{"name":"SOA University , , , ,","place":["Bhubaneswar, Odisha, India, 751030"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,9,1]]},"reference":[{"key":"2026090204033723700_cit1","doi-asserted-by":"publisher","first-page":"3725","DOI":"10.1021\/acsomega.9b04408","article-title":"Facile Synthesis of\nAg\/Pd Nanoparticle-Loaded Poly(ethylene imine) Composite Hydrogels\nwith Highly Efficient Catalytic Reduction of 4-Nitrophenol","volume":"5","author":"Feng","year":"2020","journal-title":"ACS Omega"},{"key":"2026090204033723700_cit2","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6528\/ab53c1","article-title":"Facile preparation of a self-assembled Artemia cyst shell\u2013TiO2\u2013MoS2 porous composite structure with highly\nefficient catalytic reduction of nitro compounds for waste water treatment","volume":"31","author":"Zhao","year":"2020","journal-title":"Nanotechnology"},{"key":"2026090204033723700_cit3","doi-asserted-by":"publisher","first-page":"15091","DOI":"10.1039\/D0RA01884H","article-title":"Fabrication of CS\/GA\/RGO\/Pd\ncomposite hydrogels for highly efficient catalytic reduction of organic\npollutants","volume":"10","author":"Ge","year":"2020","journal-title":"RSC Adv."},{"key":"2026090204033723700_cit4","doi-asserted-by":"publisher","first-page":"992","DOI":"10.1016\/j.cclet.2019.08.047","article-title":"Highly efficient catalytic performances\nof nitro compounds via hierarchical PdNPs-loaded MXene\/polymer\nnanocomposites synthesized through electro spinning strategy for wastewater\ntreatment","volume":"31","author":"Yin","year":"2020","journal-title":"Chin. Chem. Lett."},{"key":"2026090204033723700_cit5","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2018.06.033Inpress","article-title":"On developing ferrisilicate catalysts supported on silicon carbide\n(SiC) foam catalysts for continuous catalytic wet peroxide oxidation\n(CWPO) reactions","author":"Ou","year":"2018","journal-title":"Catal. Today"},{"key":"2026090204033723700_cit6","doi-asserted-by":"publisher","first-page":"22325","DOI":"10.1021\/jp402663z","article-title":"Organically Doped Silver Nanoparticles\nDeposited on Titania Nano fibers: Enhanced Catalytic Methanol Oxidation","volume":"117","author":"Aouat","year":"2013","journal-title":"J. Phys. Chem. C"},{"key":"2026090204033723700_cit7","doi-asserted-by":"publisher","first-page":"149","DOI":"10.1023\/A:1019009129184","article-title":"Selective oxidation\nof methane to methanol and formaldehyde over V2O5\/SiO2 catalysts. Role of NO in the gas phase","volume":"56","author":"Ban\u0303ares","year":"1998","journal-title":"Catal. Lett."},{"key":"2026090204033723700_cit8","doi-asserted-by":"publisher","first-page":"161","DOI":"10.1007\/s10562-004-7932-6","article-title":"Selective Oxidation of Methanol to Formaldehyde using\nModified Iron-Molybdate Catalysts","volume":"98","author":"Kim","year":"2004","journal-title":"Catal. Lett."},{"key":"2026090204033723700_cit9","doi-asserted-by":"publisher","first-page":"441","DOI":"10.1016\/j.cattod.2004.10.029","article-title":"Selective\noxidation of methanol to formaldehyde over V\u2013Mg\u2013O catalysts","volume":"100","author":"Isaguliants","year":"2005","journal-title":"Catal. 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Synergism between palladium and silver in methanol and carbon monoxide\noxidation over an alumina-supported palladium-silver catalyst","volume":"103","author":"McCabe","year":"1987","journal-title":"J. Catal."},{"key":"2026090204033723700_cit13","doi-asserted-by":"publisher","first-page":"4108","DOI":"10.1039\/b821216n","article-title":"Facile synthesis of\nhierarchically porous carbons and their application as a catalyst\nsupport for methanol oxidation","volume":"19","author":"Zhao","year":"2009","journal-title":"J. Mater. Chem."},{"key":"2026090204033723700_cit14","doi-asserted-by":"publisher","first-page":"323","DOI":"10.1006\/jcat.1994.1071","article-title":"Reactivity of Supported Vanadium Oxide Catalysts: The\nPartial Oxidation of Methanol","volume":"146","author":"Deo","year":"1994","journal-title":"J. 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Catal."},{"key":"2026090204033723700_cit22","doi-asserted-by":"publisher","first-page":"373","DOI":"10.1080\/01614948508064740","article-title":"Vanadium\u2500Phosphorus oxide\ncatalysts for the selective oxidation of C4 hydrocarbons\nto maleic anhydride","volume":"27","author":"Hodnett","year":"1985","journal-title":"Catal. Rev."},{"key":"2026090204033723700_cit23","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/0166-9834(91)85024-P","article-title":"Effect of promoters and reactant concentration on the\nselective oxidation of n-butane to maleic anhydride using vanadium\nphosphorus oxide catalysts","volume":"72","author":"Hutchings","year":"1991","journal-title":"Appl. Catal."},{"key":"2026090204033723700_cit24","doi-asserted-by":"publisher","first-page":"232","DOI":"10.1006\/jcat.2000.3115","article-title":"Amorphous Vanadium\nPhosphate Catalysts from Supercritical Antisolvent Precipitation","volume":"197","author":"Hutchings","year":"2001","journal-title":"J. Catal."},{"key":"2026090204033723700_cit25","doi-asserted-by":"publisher","first-page":"245","DOI":"10.1016\/j.apcata.2011.11.016","article-title":"Liquid phase catalytic\noxidation of benzyl alcohol to benzaldehyde over vanadium phosphate\ncatalyst","volume":"413","author":"Behera","year":"2012","journal-title":"Appl. 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Lett."},{"key":"2026090204033723700_cit29","doi-asserted-by":"publisher","first-page":"975","DOI":"10.1007\/s11144-018-01530-4","article-title":"Synthesis\nand catalytic activity of vanadium phosphorous oxides systems supported\non silicon carbide for the selective oxidation of n butane to maleic\nanhydride","volume":"126","author":"Shcherban","year":"2019","journal-title":"React. Kinet., Mech. Catal."},{"key":"2026090204033723700_cit30","doi-asserted-by":"publisher","first-page":"2426","DOI":"10.1016\/j.poly.2010.05.005","article-title":"Magnetic and catalytic properties\nof the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4)2(HPO4)2]\u00b72H2O","volume":"29","author":"Venegas-Yazigi","year":"2010","journal-title":"Polyhedron"},{"key":"2026090204033723700_cit31","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1016\/j.apcata.2012.02.014","article-title":"A.Real-time Raman monitoring of liquid-phase cyclohexene\nepoxidation over alumina-supported vanadium and phosphorous catalysts","volume":"421\u2013422","author":"Mikolajska","year":"2012","journal-title":"Appl. Catal., A"},{"key":"2026090204033723700_cit32","doi-asserted-by":"publisher","first-page":"4863","DOI":"10.1039\/c3ra00092c","article-title":"Sustainable\nand efficient protocol for the synthesis of a RGO\u2013VPO composite\nwith synergetic stability and reactivity","volume":"3","author":"Behera","year":"2013","journal-title":"RSC\nAdv."},{"key":"2026090204033723700_cit33","doi-asserted-by":"publisher","first-page":"190","DOI":"10.1016\/j.jcat.2012.02.004","article-title":"Facile\nfabrication of aluminum-promoted vanadium phosphate: a highly active\nheterogeneous catalyst for isopropylation of toluene to cymene","volume":"289","author":"Behera","year":"2012","journal-title":"J. Catal."},{"key":"2026090204033723700_cit34","doi-asserted-by":"publisher","first-page":"270","DOI":"10.1016\/j.cej.2011.11.047","article-title":"Selective gas phase\noxidation of methanol to formaldehyde over aluminum promoted vanadium\nphosphate","volume":"180","author":"Behera","year":"2012","journal-title":"Chem. Eng. J."},{"key":"2026090204033723700_cit35","doi-asserted-by":"publisher","first-page":"291","DOI":"10.1016\/S0920-5861(02)00315-2","article-title":"The beneficial effect of cobalt on VPO catalysts","volume":"78","author":"Cornaglia","year":"2003","journal-title":"Catal. Today"},{"key":"2026090204033723700_cit36","doi-asserted-by":"publisher","first-page":"1558","DOI":"10.1039\/c3cy20801j","article-title":"Tungstate promoted vanadium phosphate\ncatalysts for the gas phase oxidation of methanol to formaldehyde","volume":"3","author":"Behera","year":"2013","journal-title":"Catal.: Sci. Technol."},{"key":"2026090204033723700_cit37","doi-asserted-by":"publisher","first-page":"179","DOI":"10.1021\/cm000524y","article-title":"Tunable One-Pot Syntheses of Hexagonal-, Cubic-, and\nLamellar-Mesostructured Vanadium\u2013Phosphorus Oxides","volume":"13","author":"Mizuno","year":"2001","journal-title":"Chem. Mater."},{"key":"2026090204033723700_cit38","doi-asserted-by":"publisher","first-page":"176","DOI":"10.1016\/j.jcrysgro.2003.08.026","article-title":"Parameters determining\ncrystallinity in \u03b2-SiC thin films prepared by catalytic chemical\nvapor deposition","volume":"260","author":"Zhao","year":"2004","journal-title":"J. Cryst. Growth"},{"key":"2026090204033723700_cit39","doi-asserted-by":"publisher","DOI":"10.1186\/1556-276X-6-454","article-title":"Surface charges and optical characteristic\nof colloidal cubic SiCnanocrystals","volume":"6","author":"Li","year":"2011","journal-title":"Nanoscale\nRes. 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Catal.,\nA"},{"key":"2026090204033723700_cit41","doi-asserted-by":"publisher","first-page":"41","DOI":"10.1038\/368041a0","article-title":"Role of the product in the transformation\nof a catalyst to its active state","volume":"368","author":"Hutchings","year":"1994","journal-title":"Nature"},{"key":"2026090204033723700_cit42","doi-asserted-by":"publisher","first-page":"14299","DOI":"10.1039\/c2dt31468a","article-title":"Liquid phase esterification\nof acetic acid over WO3 promoted \u03b2-SiC in a solvent\nfree system","volume":"41","author":"Mishra","year":"2012","journal-title":"Dalton Trans."},{"key":"2026090204033723700_cit43","doi-asserted-by":"publisher","first-page":"C2-823","DOI":"10.1051\/jp4:1991297","article-title":"Growth Mechanism of Epitaxial Silicon\nCarbide Produced Using Rapid Thermal CVD","volume":"02","author":"Ruddell","year":"1991","journal-title":"J.\nPhys. IV France"},{"key":"2026090204033723700_cit44","doi-asserted-by":"publisher","first-page":"5049","DOI":"10.1166\/jnn.2011.4109","article-title":"Magnetic properties of nanocrystalline\n\u03b2-SiC","volume":"11","author":"Mishra","year":"2011","journal-title":"J. Nanosci. Nanotechnol."},{"key":"2026090204033723700_cit45","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1023\/A:1006734100499","article-title":"Characterization of silicon carbide\nand silicon powders by XPS and zeta potential measurement","volume":"20","author":"Binner","year":"2001","journal-title":"J. Mater. Sci. Lett."},{"key":"2026090204033723700_cit46","doi-asserted-by":"publisher","first-page":"52","DOI":"10.1006\/jcat.1996.0123","article-title":"A Comparison of the Reactivity of \u201cNonequilibrated\u201d\nand \u201cEquilibrated\u201d V\u2013P\u2013O Catalysts: Structural\nEvolution, Surface Characterization, and Reactivity in the Selective\nOxidation of n-Butane and n-Pentane","volume":"160","author":"Albonetti","year":"1996","journal-title":"J. Catal."},{"key":"2026090204033723700_cit47","doi-asserted-by":"publisher","first-page":"28","DOI":"10.1006\/jcat.1995.1228","article-title":"Evolution\nof a VPO Catalyst in n-Butane Oxidation Reaction During the Activation\nTime","volume":"156","author":"Abon","year":"1995","journal-title":"J. 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Catal.,\nA"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.0c01921","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/5\/36\/22808\/67656882\/acsomega.0c01921.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/5\/36\/22808\/67656882\/acsomega.0c01921.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T08:03:43Z","timestamp":1788336223000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/5\/36\/22808\/1371693\/Facile-Synthesis-and-Synergetic-Interaction-of-VPO"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,9,1]]},"references-count":48,"journal-issue":{"issue":"36","published-online":{"date-parts":[[2020,9,1]]},"published-print":{"date-parts":[[2020,9,15]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.0c01921","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,9,1]]}}}