{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T12:08:33Z","timestamp":1789992513215,"version":"4.0.1"},"reference-count":55,"publisher":"American Chemical Society (ACS)","issue":"49","license":[{"start":{"date-parts":[[2020,12,2]],"date-time":"2020-12-02T00:00:00Z","timestamp":1606867200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccbyncnd_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2015M3D3A1A01065436"],"award-info":[{"award-number":["2015M3D3A1A01065436"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2019R1A2C1084021"],"award-info":[{"award-number":["2019R1A2C1084021"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,12,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Copper-catalyzed aerobic oxidation conditions were employed to promote the C\u2013C bond cleavage of \u03b2-alkoxy alcohols and \u03b2-1 compounds (lignin model compounds). Besides these compounds, various 1,2 and 1,3-diols were successfully converted to aldehydes. We propose the Cu(I)-catalyzed mechanism explaining the C\u2013C cleavage of these 1,2 and 1,3-dihydroxy compounds and \u03b2-alkoxy alcohols based on XPS data. Although our reaction conditions do not include large excess of bases and elaborated ligand-modified catalysts, copper salts with\/without Me-TBD show good catalytic activities for C\u2013C bond cleavage of various lignin model compounds.<\/jats:p>","DOI":"10.1021\/acsomega.0c04162","type":"journal-article","created":{"date-parts":[[2020,12,2]],"date-time":"2020-12-02T14:35:52Z","timestamp":1606919752000},"page":"31684-31691","source":"Crossref","is-referenced-by-count":13,"title":["Copper-Catalyzed Oxidative Cleavage of the C\u2013C\nBonds of \u03b2-Alkoxy Alcohols and \u03b2-1 Compounds"],"prefix":"10.1021","volume":"5","author":[{"given":"Si Ae","family":"Kim","sequence":"first","affiliation":[{"name":"Ajou University , , ,","place":["Suwon, Korea, 16499"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seong Eon","family":"Kim","sequence":"additional","affiliation":[{"name":"Ajou University , , ,","place":["Suwon, Korea, 16499"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu Kwon","family":"Kim","sequence":"additional","affiliation":[{"name":"Ajou University , , ,","place":["Suwon, Korea, 16499"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4471-2328","authenticated-orcid":true,"given":"Hye-Young","family":"Jang","sequence":"additional","affiliation":[{"name":"Ajou University , , ,","place":["Suwon, Korea, 16499"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,12,2]]},"reference":[{"key":"2026092106120411400_cit1","doi-asserted-by":"publisher","first-page":"211","DOI":"10.1016\/j.jbiotec.2016.11.016","article-title":"Biotechnological\nproduction of aromatic compounds of\nthe extended shikimate pathway from renewable biomass","volume":"257","author":"Lee","year":"2017","journal-title":"J. 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