{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T12:13:40Z","timestamp":1789992820669,"version":"4.0.1"},"reference-count":41,"publisher":"American Chemical Society (ACS)","issue":"51","license":[{"start":{"date-parts":[[2020,12,17]],"date-time":"2020-12-17T00:00:00Z","timestamp":1608163200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccbyncnd_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100004396","name":"Thailand Research Fund","doi-asserted-by":"publisher","award":["PHD\/0171\/2556"],"award-info":[{"award-number":["PHD\/0171\/2556"]}],"id":[{"id":"10.13039\/501100004396","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002241","name":"Japan Science and Technology Agency","doi-asserted-by":"publisher","award":["JPMJMI18E3"],"award-info":[{"award-number":["JPMJMI18E3"]}],"id":[{"id":"10.13039\/501100002241","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,12,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Cellulose-based functional materials have gained immense interest due to their low density, hydrophilicity, chirality, and degradability. So far, a facile and scalable preparation of fibrillated cellulose by treating the hydroxy groups of cellulose with citric acid (F-CAC) has been developed and applied as a reinforcing filler for polypropylene composite. Herein, a size-selective preparation of Au nanoparticles (NPs) stabilized by F-CAC is described. By modifying the conditions of transdeposition method, established in our group previously, a transfer of Au NPs from poly(N-vinyl-2-pyrrolidone) (PVP) to F-CAC proceeded up to 96% transfer efficiency with retaining its cluster sizes in EtOH. Meanwhile, the deposition efficiency drastically decreased in the case of nonmodified cellulose, showing the significance of citric acid modification. A shift of binding energy at Au 4f core level X-ray photoelectron spectroscopy from 82.0 to 83.3 eV indicated that the NPs were stabilized on an F-CAC surface rather than by PVP matrix. The reproducible particle size growth was observed when 2-propanol was used as a solvent instead of EtOH, expanding the range of the available particle size with simple manipulation. The thus-obtained Au:F-CAC nanocatalysts exhibited a catalytic activity toward an aerobic oxidation of 1-indonol in toluene to yield 1-indanone quantitatively and were recyclable at least six times, illustrating high tolerance against organic solvents.<\/jats:p>","DOI":"10.1021\/acsomega.0c04894","type":"journal-article","created":{"date-parts":[[2020,12,18]],"date-time":"2020-12-18T03:27:45Z","timestamp":1608262065000},"page":"33206-33213","source":"Crossref","is-referenced-by-count":21,"title":["Size-Controlled Preparation of Gold Nanoparticles\nDeposited on Surface-Fibrillated Cellulose Obtained by Citric Acid\nModification"],"prefix":"10.1021","volume":"5","author":[{"given":"Threeraphat","family":"Chutimasakul","sequence":"first","affiliation":[{"name":"Mahidol University , , ,","place":["Bangkok, Thailand, 10400"]},{"name":"Osaka University , , 2-1 Yamadaoka, Suita , ,","place":["Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4742-8085","authenticated-orcid":true,"given":"Yuta","family":"Uetake","sequence":"additional","affiliation":[{"name":"Osaka University , , 2-1 Yamadaoka, Suita , ,","place":["Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonggol","family":"Tantirungrotechai","sequence":"additional","affiliation":[{"name":"Mahidol University , , ,","place":["Bangkok, Thailand, 10400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9087-5174","authenticated-orcid":true,"given":"Taka-aki","family":"Asoh","sequence":"additional","affiliation":[{"name":"Osaka University , , 2-1 Yamadaoka, Suita , ,","place":["Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8587-2507","authenticated-orcid":true,"given":"Hiroshi","family":"Uyama","sequence":"additional","affiliation":[{"name":"Osaka University , , 2-1 Yamadaoka, Suita , ,","place":["Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5783-4151","authenticated-orcid":true,"given":"Hidehiro","family":"Sakurai","sequence":"additional","affiliation":[{"name":"Osaka University , , 2-1 Yamadaoka, Suita , ,","place":["Osaka, Japan, 565-0871"]},{"name":"Osaka University , , Suita , ,","place":["Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,12,17]]},"reference":[{"key":"2026092106102827700_cit1","doi-asserted-by":"publisher","first-page":"3358","DOI":"10.1002\/anie.200460587","article-title":"Cellulose: Fascinating\nBiopolymer and Sustainable Raw Material","volume":"44","author":"Klemm","year":"2005","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026092106102827700_cit2","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-319-26015-0","volume-title":"In\nCellulose Chemistry and Properties: Fibers, Nanocelluloses and Advanced\nMaterials","author":"Rojas","year":"2016"},{"key":"2026092106102827700_cit3a","doi-asserted-by":"publisher","first-page":"4609","DOI":"10.1021\/acs.chemmater.7b00531","article-title":"Review\nof Hydrogels\nand Aerogels Containing Nanocellulose","volume":"29","author":"De France","year":"2017","journal-title":"Chem.\nMater."},{"key":"2026092106102827700_cit3b","doi-asserted-by":"publisher","first-page":"11575","DOI":"10.1021\/acs.chemrev.7b00627","article-title":"Nanocellulose, a Versatile\nGreen Platform: From Biosources to Materials and Their Applications","volume":"118","author":"Thomas","year":"2018","journal-title":"Chem. Rev."},{"key":"2026092106102827700_cit3c","doi-asserted-by":"publisher","first-page":"2837","DOI":"10.1039\/C7CS00790F","article-title":"Nanocellulose: A Promising Nanomaterial for Advanced\nElectrochemical Energy Storage","volume":"47","author":"Chen","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"2026092106102827700_cit3d","doi-asserted-by":"publisher","first-page":"1531","DOI":"10.1002\/pat.4264","article-title":"Nanocellulose Reinforced\nas Green Agent in Polymer Matrix Composites Applications","volume":"29","author":"Abdul Rashid","year":"2018","journal-title":"Polym. Adv. Technol."},{"key":"2026092106102827700_cit3e","doi-asserted-by":"publisher","first-page":"1804826","DOI":"10.1002\/adma.201804826","article-title":"Nanocellulose for Energy Storage\nSystems: Beyond the Limits of Synthetic Materials","volume":"31","author":"Kim","year":"2019","journal-title":"Adv. Mater."},{"key":"2026092106102827700_cit4a","doi-asserted-by":"publisher","first-page":"1635","DOI":"10.1023\/B:JMSC.0000016162.43897.0a","article-title":"Bio-composites produced\nfrom plant\nmicrofiber bundles with a nanometer unit web-like network","volume":"39","author":"Yano","year":"2004","journal-title":"J. Mater. Sci."},{"key":"2026092106102827700_cit4b","doi-asserted-by":"publisher","first-page":"754","DOI":"10.1002\/adem.200400097","article-title":"Cellulose Fibrils for Polymer Reinforcement","volume":"6","author":"Zimmermann","year":"2004","journal-title":"Adv. Eng. 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Polym."},{"key":"2026092106102827700_cit5b","doi-asserted-by":"publisher","first-page":"109118","DOI":"10.1016\/j.polymdegradstab.2020.109118","article-title":"Cellulose\nModified by Citric Acid Reinforced Poly(Lactic Acid) Resin as Fillers","volume":"175","author":"Cui","year":"2020","journal-title":"Polym. Degrad. Stab."},{"key":"2026092106102827700_cit5c","doi-asserted-by":"publisher","first-page":"2274","DOI":"10.1021\/acsapm.0c00250","article-title":"Citric Acid-Modified\nCellulose-Based Tough and Self-Healable Composite Formed by Two Kinds\nof Noncovalent Bonding","volume":"2","author":"Sinawang","year":"2020","journal-title":"ACS Appl. Polym. Mater."},{"key":"2026092106102827700_cit5d","doi-asserted-by":"publisher","first-page":"109157","DOI":"10.1016\/j.polymdegradstab.2020.109157","article-title":"Composite\nhydrogels reinforced by cellulose-based supramolecular filler","volume":"177","author":"Sugawara","year":"2020","journal-title":"Polym. Degrad. Stab."},{"key":"2026092106102827700_cit5e","doi-asserted-by":"publisher","first-page":"3936","DOI":"10.1021\/acs.biomac.0c01095","article-title":"Supramolecular\nBiocomposite Hydrogels Formed by Cellulose and Host-Guest Polymers\nAssisted by Calcium Ion Complexes","volume":"21","author":"Tsuchiya","year":"2020","journal-title":"Biomacromolecules"},{"key":"2026092106102827700_cit6","doi-asserted-by":"publisher","first-page":"156","DOI":"10.3390\/polym8040156","article-title":"Design and Utility\nof Metal\/Metal Oxide Nanoparticles Mediated by Thioether End-Functionalized\nPolymeric Ligands","volume":"8","author":"Razzaque","year":"2016","journal-title":"Polymer"},{"key":"2026092106102827700_cit7","doi-asserted-by":"publisher","first-page":"1397","DOI":"10.1021\/acs.chemrev.9b00188","article-title":"New Horizon of Nanoparticle\nand Cluster Catalysis with Dendrimers","volume":"120","author":"Yamamoto","year":"2020","journal-title":"Chem.\nRev."},{"key":"2026092106102827700_cit8a","doi-asserted-by":"publisher","first-page":"7979","DOI":"10.1021\/acscatal.6b02446","article-title":"Chiral Ligand-Modified\nMetal Nanoparticles as Unique Catalysts for Asymmetric C\u2013C\nBond-Forming Reactions: How Are Active Species Generated?","volume":"6","author":"Yasukawa","year":"2016","journal-title":"ACS Catal."},{"key":"2026092106102827700_cit8b","doi-asserted-by":"crossref","unstructured":"(b)\n          \n            \n              Smith, C. A.; Narouz, M. R.; Lummis, P. A.; Singh, I.; Nazemi, A.; Li, C.-H.; Crudden, C. M.\n          \n            N-Heterocyclic\nCarbenes in Materials Chemistry. 2019, 119, 4986\u20135056, 10.1021\/acs.chemrev.8b00514.","DOI":"10.1021\/acs.chemrev.8b00514"},{"key":"2026092106102827700_cit9a","doi-asserted-by":"publisher","first-page":"7086","DOI":"10.1021\/ja810045y","article-title":"Effect of\nElectronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis","volume":"131","author":"Tsunoyama","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2026092106102827700_cit9b","doi-asserted-by":"publisher","first-page":"9579","DOI":"10.1038\/s41598-017-10165-9","article-title":"The Impact of the Polymer\nChain Length on the Catalytic Activity of Poly(N-vinyl-2-pyrrolidone)-supported\nGold Nanoclusters","volume":"7","author":"Haesuwannakij","year":"2017","journal-title":"Sci. Rep."},{"key":"2026092106102827700_cit10a","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.molcata.2011.03.019","article-title":"Chitosan-stabilized\ngold, gold-palladium, and gold-platinum nanoclusters as efficient\ncatalysts for aerobic oxidation of alcohols","volume":"341","author":"Murugadoss","year":"2011","journal-title":"J. Mol. Catal. A"},{"key":"2026092106102827700_cit10b","doi-asserted-by":"publisher","first-page":"1238","DOI":"10.1071\/CH12175","article-title":"Gold\/Palladium Bimetallic Alloy Nanoclusters\nStabilized by Chitosan as Highly Efficient and Selective Catalysts\nfor Homocoupling of Arylboronic Acid","volume":"65","author":"Sophiphun","year":"2012","journal-title":"Aust.\nJ. Chem."},{"key":"2026092106102827700_cit11","doi-asserted-by":"publisher","first-page":"8525","DOI":"10.1039\/c7nr00400a","article-title":"Cellulose\u2013gold nanoparticle hybrid materials","volume":"9","author":"Van Rie","year":"2017","journal-title":"Nanoscale"},{"key":"2026092106102827700_cit12a","doi-asserted-by":"publisher","first-page":"1647","DOI":"10.1126\/science.281.5383.1647","article-title":"Onset of\nCatalytic Activity of Gold Clusters on Titania with the Appearance\nof Nonmetallic Properties","volume":"281","author":"Valden","year":"1998","journal-title":"Science"},{"key":"2026092106102827700_cit12b","doi-asserted-by":"publisher","first-page":"2","DOI":"10.1021\/cs100043j","article-title":"Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled\nAu Clusters on Hydroxyapatite: Size Effect in the Sub-2 nm Regime","volume":"1","author":"Liu","year":"2011","journal-title":"ACS Catal."},{"key":"2026092106102827700_cit13a","doi-asserted-by":"publisher","first-page":"9374","DOI":"10.1021\/ja052161e","article-title":"Size-Specific Catalytic Activity of Polymer-Stabilized\nGold Nanoclusters for Aerobic Alcohol Oxidation in Water","volume":"127","author":"Tsunoyama","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"2026092106102827700_cit13b","doi-asserted-by":"publisher","first-page":"528","DOI":"10.1016\/j.cplett.2006.08.066","article-title":"Size effect\non the catalysis of gold clusters dispersed in water for aerobic oxidation\nof alcohol","volume":"429","author":"Tsunoyama","year":"2006","journal-title":"Chem. Phys. Lett."},{"key":"2026092106102827700_cit13c","doi-asserted-by":"publisher","first-page":"23","DOI":"10.1007\/s00706-013-1001-z","article-title":"Size-controlled preparation of gold nanoclusters stabilized\nby high-viscosity hydrophilic polymers using a microflow reactor","volume":"145","author":"Haesuwannakij","year":"2014","journal-title":"Monatsh. Chem."},{"key":"2026092106102827700_cit14a","doi-asserted-by":"publisher","first-page":"4649","DOI":"10.1166\/jnn.2017.13777","article-title":"Size-Controlled Preparation of Gold Nanoclusters on\nHydroxyapatite Through Trans-Deposition Method","volume":"17","author":"Haesuwannakij","year":"2017","journal-title":"J. Nanosci. Nanotechnol."},{"key":"2026092106102827700_cit14b","doi-asserted-by":"publisher","first-page":"2998","DOI":"10.1021\/acscatal.6b03524","article-title":"Partially Fluoride-Substituted Hydroxyapatite\nas a Suitable Support for the Gold-Catalyzed Homocoupling of Phenylboronic\nAcid: An Example of Interface Modification","volume":"7","author":"Haesuwannakij","year":"2017","journal-title":"ACS Catal."},{"key":"2026092106102827700_cit15a","doi-asserted-by":"publisher","first-page":"2463","DOI":"10.1002\/jps.20385","article-title":"Characterization\nof\nPhysico-Mechanical Properties of Indomethacin and Polymers to Assess\ntheir Suitability for Hot-Melt Extrusion Process as a Means to Manufacture\nSolid Dispersion\/Solution","volume":"94","author":"Chokshi","year":"2005","journal-title":"J. Pharm. Sci."},{"key":"2026092106102827700_cit15b","doi-asserted-by":"publisher","first-page":"8","DOI":"10.1016\/j.ijpharm.2006.06.009","article-title":"Prediction\nof solubility parameters using partial least square regression","volume":"325","author":"Tantishaiyakul","year":"2006","journal-title":"Int. J. Pharm."},{"key":"2026092106102827700_cit16a","volume-title":"The three dimensional solubility\nparameter","author":"Hansen","year":"1967"},{"key":"2026092106102827700_cit16b","doi-asserted-by":"crossref","DOI":"10.1201\/9781420006834","volume-title":"Hansen Solubility\nparameters:\nA User\u2019s Handbook","author":"Hansen","year":"2007"},{"key":"2026092106102827700_cit17","doi-asserted-by":"publisher","first-page":"21495","DOI":"10.1002\/adv.21495","article-title":"Thermodynamic Studies on Polyvinylpyrrolidone\nSolution Systems Used for Fabrication of Electrospun Nanostructures:\nEffects of the Solvent","volume":"34","author":"Nasouri","year":"2015","journal-title":"Adv. Polym. Technol."},{"key":"2026092106102827700_cit18","doi-asserted-by":"publisher","first-page":"222","DOI":"10.1016\/j.jcat.2006.04.004","article-title":"The effect\nof gold particle size on AuAu bond length and reactivity toward oxygen\nin supported catalysts","volume":"240","author":"Miller","year":"2006","journal-title":"J. Catal."},{"key":"2026092106102827700_cit19","doi-asserted-by":"publisher","first-page":"6124","DOI":"10.1021\/jacs.5b02034","article-title":"Cellulose Nanocrystals\nas Chiral Inducers: Enantioselective\nCatalysis and Transmission Electron Microscopy 3D Characterization","volume":"137","author":"Kaushik","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"2026092106102827700_cit20","doi-asserted-by":"publisher","first-page":"11293","DOI":"10.1021\/la0478189","article-title":"Colloidal\nGold Nanoparticles as Catalyst for Carbon\u2013Carbon Bond Formation:\nApplication to Aerobic Homocoupling of Phenylboronic Acid in Water","volume":"20","author":"Tsunoyama","year":"2004","journal-title":"Langmuir"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.0c04894","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/5\/51\/33206\/67752433\/acsomega.0c04894.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/5\/51\/33206\/67752433\/acsomega.0c04894.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T11:44:33Z","timestamp":1789991073000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/5\/51\/33206\/496541\/Size-Controlled-Preparation-of-Gold-Nanoparticles"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,12,17]]},"references-count":41,"journal-issue":{"issue":"51","published-online":{"date-parts":[[2020,12,17]]},"published-print":{"date-parts":[[2020,12,29]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.0c04894","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv.12950390.v1","asserted-by":"object"}]},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,12,17]]}}}