{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T15:26:18Z","timestamp":1786980378179,"version":"build-2736575974"},"reference-count":63,"publisher":"American Chemical Society (ACS)","issue":"50","license":[{"start":{"date-parts":[[2021,12,10]],"date-time":"2021-12-10T00:00:00Z","timestamp":1639094400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002338","name":"Ministry of Education of the People's Republic of China","doi-asserted-by":"publisher","award":["IRT 1231"],"award-info":[{"award-number":["IRT 1231"]}],"id":[{"id":"10.13039\/501100002338","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21773052"],"award-info":[{"award-number":["21773052"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Zhejiang Province","award":["2018R52051"],"award-info":[{"award-number":["2018R52051"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2021,12,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A new class of aza-crown ether-derived chiral BINOL catalysts were designed, synthesized, and applied in the asymmetric Michael addition of alkenylboronic acids to \u03b1,\u03b2-unsaturated ketones. It was found that introducing aza-crown ethers to the BINOL catalyst could achieve apparently higher enantioselectivity than a similar BINOL catalyst without aza-crown ethers did, although the host\u2013guest complexation of alkali ions by the aza-crown ethers could not further improve the catalysis effectiveness. Under mediation of the aza-crown ether-derived chiral BINOL and in the presence of a magnesium salt, an array of chiral \u03b3,\u03b4-unsaturated ketones were furnished in good enantioselectivities (81\u201395% ees).<\/jats:p>","DOI":"10.1021\/acsomega.1c05875","type":"journal-article","created":{"date-parts":[[2021,12,10]],"date-time":"2021-12-10T03:33:25Z","timestamp":1639107205000},"page":"35093-35103","source":"Crossref","is-referenced-by-count":19,"title":["Crown Ether-Derived Chiral BINOL: Enantioselective\nMichael Addition of Alkenyl Boronic Acids to \u03b1,\u03b2-Unsaturated\nKetones"],"prefix":"10.1021","volume":"6","author":[{"given":"Jia-Ju","family":"Tao","sequence":"first","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Dong","family":"Tang","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Hong","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Wen","family":"Ye","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Yu","family":"Chen","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunsong","family":"Xie","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zibin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1480-9292","authenticated-orcid":true,"given":"Shijun","family":"Li","sequence":"additional","affiliation":[{"name":"Hangzhou Normal University , , ,","place":["Hangzhou, P. R. China, 311121"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2021,12,10]]},"reference":[{"key":"2026081710233012400_cit1a","doi-asserted-by":"publisher","first-page":"4638","DOI":"10.1002\/anie.200704684","article-title":"Asymmetric\norganocatalysis: From\ninfancy to adolescence","volume":"47","author":"Dondoni","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081710233012400_cit1b","doi-asserted-by":"publisher","first-page":"299","DOI":"10.1002\/chin.200727220","article-title":"Organocatalytic asymmetric conjugate\nadditions","volume":"18","author":"Almas\u0327i","year":"2007","journal-title":"Tetrahedron: Asymmetry"},{"key":"2026081710233012400_cit1c","doi-asserted-by":"publisher","first-page":"2065","DOI":"10.1055\/s-2007-983747","article-title":"Organocatalytic enantioselective\nMichael and hetero-Michael reactions","volume":"2007","author":"Vicario","year":"2007","journal-title":"Synthesis"},{"key":"2026081710233012400_cit1d","doi-asserted-by":"publisher","first-page":"1701","DOI":"10.1002\/ejoc.200600653","article-title":"Recent\nAdvances in Asymmetric Organocatalytic 1,4-Conjugate Additions","volume":"2007","author":"Tsogoeva","year":"2007","journal-title":"Eur. J. Org. Chem."},{"key":"2026081710233012400_cit1e","doi-asserted-by":"publisher","first-page":"2390","DOI":"10.1021\/cr400215u","article-title":"Catalytic C-C Bond-Forming Multi-Component Cascade\nor Domino Reactions: Pushing the Boundaries of Complexity in Asymmetric\nOrganocatalysis","volume":"114","author":"Volla","year":"2014","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit2a","first-page":"P249","article-title":"Asymmetric Michael\nAddition and Related Reactions","volume-title":"Stereoselective\nSynthesis of Drugs and Natural Products, 2V Set","author":"Li","year":"2013"},{"key":"2026081710233012400_cit2b","doi-asserted-by":"publisher","first-page":"489","DOI":"10.2174\/13852728113176660149","article-title":"Recent Development\nin the Asymmetric Michael Addition for Carbon-Carbon Bond Formation","volume":"18","author":"Heravi","year":"2014","journal-title":"Curr. Org. Chem."},{"key":"2026081710233012400_cit2c","doi-asserted-by":"publisher","first-page":"369","DOI":"10.1055\/s-2006-926302","article-title":"Catalytic enantioselective construction\nof all-carbon quaternary stereocenters","author":"Trost","year":"2006","journal-title":"Synthesis"},{"key":"2026081710233012400_cit3a","doi-asserted-by":"publisher","first-page":"1279","DOI":"10.1055\/s-2007-966005","article-title":"Recent advances\nin metal-catalyzed asymmetric conjugate additions","volume":"2007","author":"Christoffers","year":"2007","journal-title":"Synthesis"},{"key":"2026081710233012400_cit3b","doi-asserted-by":"publisher","first-page":"7586","DOI":"10.1021\/acs.chemrev.7b00692","article-title":"Recent Advances in\nMetal-Catalyzed Asymmetric 1,4-Conjugate Addition (ACA) of Nonorganometallic\nNucleophiles","volume":"118","author":"Zheng","year":"2018","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit3c","doi-asserted-by":"publisher","first-page":"546","DOI":"10.1039\/c7sc03404k","article-title":"Enantioselective Synthesis of gem-Diarylalkanes by\nTransition Metal-Catalyzed Asymmetric Arylations (TMCAAr)","volume":"9","author":"Jia","year":"2018","journal-title":"Chem. Sci."},{"key":"2026081710233012400_cit4a","doi-asserted-by":"publisher","first-page":"465","DOI":"10.1351\/pac200476030465","article-title":"Rhodium-catalyzed asymmetric addition\nof aryl- and\nalkenylboron reagents to electron-deficient olefins","volume":"76","author":"Hayashi","year":"2004","journal-title":"Pure Appl. Chem."},{"key":"2026081710233012400_cit4b","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1021\/cr020007u","article-title":"Rhodium-Catalyzed Carbon\u2013Carbon\nBond Forming Reactions of Organometallic Compounds","volume":"103","author":"Fagnou","year":"2003","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit4c","doi-asserted-by":"publisher","first-page":"2829","DOI":"10.1021\/cr020022z","article-title":"Rhodium-catalyzed asymmetric 1,4-addition\nand its related asymmetric reactions","volume":"103","author":"Hayashi","year":"2003","journal-title":"Chem.\nRev."},{"key":"2026081710233012400_cit4d","doi-asserted-by":"publisher","first-page":"513","DOI":"10.1016\/j.tetasy.2016.05.004","article-title":"\u03b1\u03b2Rh-catalyzed\nasymmetric 1,4-addition reactions to \u03b1,\u03b2-unsaturated carbonyl\nand related compounds: an update","volume":"27","author":"Heravi","year":"2016","journal-title":"Tetrahedron:\nAsymmetry"},{"key":"2026081710233012400_cit4e","doi-asserted-by":"publisher","first-page":"95","DOI":"10.1021\/cs200562n","article-title":"Rhodium-Catalyzed\nAsymmetric Arylation","volume":"2","author":"Tian","year":"2012","journal-title":"ACS Catal."},{"key":"2026081710233012400_cit5a","doi-asserted-by":"publisher","first-page":"5579","DOI":"10.1021\/ja980666h","article-title":"Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl-\nand Alkenylboronic Acids to Enones","volume":"120","author":"Takaya","year":"1998","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026081710233012400_cit5b","doi-asserted-by":"publisher","first-page":"9086","DOI":"10.1021\/ja303109q","article-title":"\u03b1\u03b2Effect\nof Chiral Diene Ligands in Rhodium-Catalyzed Asymmetric Addition of\nArylboronic Acids to \u03b1,\u03b2-Unsaturated Sulfonyl Compounds","volume":"134","author":"Nishimura","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit5c","doi-asserted-by":"publisher","first-page":"2736","DOI":"10.1021\/jo302656s","article-title":"Enantioselective\nSynthesis of Chiral 3-Aryl-1-indanones through Rhodium-Catalyzed Asymmetric\nIntramolecular 1,4-Addition","volume":"78","author":"Yu","year":"2013","journal-title":"J. Org. Chem."},{"key":"2026081710233012400_cit5d","doi-asserted-by":"publisher","first-page":"331","DOI":"10.1002\/jccs.201700328","article-title":"Rhodium-catalyzed Asymmetric Arylation\nof Nitroalkenes Powered by Simple Chiral Sulfur-Olefin Ligands","volume":"65","author":"Wang","year":"2018","journal-title":"J. Chin. Chem. Soc."},{"key":"2026081710233012400_cit5e","doi-asserted-by":"publisher","first-page":"1518","DOI":"10.1002\/asia.201600143","article-title":"Chiral Phosphorus-Olefin\nLigands for the RhI-Catalyzed Asymmetric Addition of Aryl Boronic\nAcids to Electron-Deficient Olefins","volume":"11","author":"Chen","year":"2016","journal-title":"Chem.\ue5f8Asian\nJ."},{"key":"2026081710233012400_cit5f","doi-asserted-by":"publisher","first-page":"8362","DOI":"10.1039\/c7sc03025h","article-title":"Rhodium-catalyzed\nasymmetric 1,4-addition reactions of aryl boronic acids with nitroalkenes:\nreaction mechanism and development of homogeneous and heterogeneous\ncatalysts","volume":"8","author":"Miyamura","year":"2017","journal-title":"Chem. Sci."},{"key":"2026081710233012400_cit5g","doi-asserted-by":"publisher","first-page":"5869","DOI":"10.1021\/acs.joc.8b00952","article-title":"\u03b3Access to Chiral\nHWE Reagents by Rhodium-Catalyzed Asymmetric Arylation of \u03b3,\u03b4-Unsaturated\n\u03b2-Ketophosphonates","volume":"83","author":"Yin","year":"2018","journal-title":"J. Org. Chem."},{"key":"2026081710233012400_cit5h","doi-asserted-by":"publisher","first-page":"3142","DOI":"10.1002\/adsc.202000211","article-title":"Rhodium-Catalyzed Asymmetric\nConjugate Addition of Organoboronic Acids to Carbonyl-Activated Alkenyl\nAzaarenes","volume":"362","author":"Zhu","year":"2020","journal-title":"Adv. Synth. Catal."},{"key":"2026081710233012400_cit6a","doi-asserted-by":"publisher","first-page":"4547","DOI":"10.1002\/ejoc.200800541","article-title":"Palladium-Catalyzed Asymmetric Conjugate\nAddition of\nAryl-Metal Species","volume":"2008","author":"Gutnov","year":"2008","journal-title":"Eur. J. Org. Chem."},{"key":"2026081710233012400_cit6b","doi-asserted-by":"publisher","first-page":"14996","DOI":"10.1021\/ja401713g","article-title":"Mechanism and Enantioselectivity\nin Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to\n\u03b2-Substituted Cyclic Enones: Insights from Computation and Experiment","volume":"135","author":"Holder","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit6c","doi-asserted-by":"publisher","first-page":"2250","DOI":"10.1021\/acs.orglett.5b00863","article-title":"Palladium-Catalyzed Asymmetric Addition of Arylboronic Acids to Nitrostyrenes","volume":"17","author":"He","year":"2015","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit7a","doi-asserted-by":"publisher","first-page":"2796","DOI":"10.1021\/cr0683515","article-title":"Enantioselective\ncopper-catalyzed conjugate addition\nand allylic substitution reactions","volume":"108","author":"Alexakis","year":"2008","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit7b","doi-asserted-by":"publisher","first-page":"2418","DOI":"10.3762\/bjoc.11.263","article-title":"Copper-catalyzed asymmetric conjugate addition of organometallic\nreagents to extended Michael acceptors","volume":"11","author":"Schmid","year":"2015","journal-title":"Beilstein\nJ. Org. Chem."},{"key":"2026081710233012400_cit7c","doi-asserted-by":"publisher","first-page":"3780","DOI":"10.1039\/d0ob00278j","article-title":"Asymmetric copper-catalyzed conjugate additions of\norganometallic reagents in the syntheses of natural compounds and\npharmaceuticals","volume":"18","author":"Vargova\u0301","year":"2020","journal-title":"Org. Biomol. Chem."},{"key":"2026081710233012400_cit8a","doi-asserted-by":"publisher","first-page":"3244","DOI":"10.1021\/ja043001q","article-title":"Ligand-Catalyzed Asymmetric Alkynylboration\nof Enones: A New Paradigm for Asymmetric Synthesis Using Organoboranes","volume":"127","author":"Wu","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit8b","doi-asserted-by":"publisher","first-page":"4908","DOI":"10.1021\/ja0713734","article-title":"Asymmetric Conjugate\nAlkenylation of Enones Catalyzed by Chiral Diols","volume":"129","author":"Wu","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit9","doi-asserted-by":"publisher","first-page":"5796","DOI":"10.1021\/ol202391r","article-title":"Binaphthol-Catalyzed\nAsymmetric Conjugate Arylboration of Enones","volume":"13","author":"Turner","year":"2011","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit10a","doi-asserted-by":"publisher","first-page":"12660","DOI":"10.1021\/ja0651308","article-title":"Asymmetric\nAllylboration of Ketones Catalyzed by Chiral Diols","volume":"128","author":"Lou","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit10b","doi-asserted-by":"publisher","first-page":"6922","DOI":"10.1021\/ja8018934","article-title":"Asymmetric Petasis\nReactions Catalyzed by Chiral Biphenols","volume":"130","author":"Lou","year":"2008","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026081710233012400_cit10c","doi-asserted-by":"publisher","first-page":"8679","DOI":"10.1002\/anie.200904715","article-title":"The Mechanism and\nan Improved Asymmetric Allylboration of Ketones Catalyzed by Chiral\nBiphenols","volume":"48","author":"Barnett","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081710233012400_cit10d","doi-asserted-by":"publisher","first-page":"4020","DOI":"10.1021\/ol201535b","article-title":"Asymmetric Propargylation of Ketones\nUsing Allenylboronates Catalyzed by Chiral Biphenols","volume":"13","author":"Barnett","year":"2011","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit10e","doi-asserted-by":"publisher","first-page":"5812","DOI":"10.1021\/acs.orglett.5b02954","article-title":"Enantioselective Multicomponent Condensation Reactions\nof Phenols, Aldehydes, and Boronates Catalyzed by Chiral Biphenols","volume":"17","author":"Barbato","year":"2015","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit10f","doi-asserted-by":"publisher","first-page":"1998","DOI":"10.1021\/jacs.6b11937","article-title":"Enantioselective\nSynthesis of Allenes by Catalytic Traceless Petasis Reactions","volume":"139","author":"Jiang","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit11a","doi-asserted-by":"publisher","first-page":"4958","DOI":"10.1021\/ol2020847","article-title":"Enantioselective\nConjugate Addition of Alkenylboronic\nAcids to Indole-Appended Enones","volume":"13","author":"Lundy","year":"2011","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit11b","doi-asserted-by":"publisher","first-page":"6104","DOI":"10.1021\/ol3030605","article-title":"A General Method\nfor the Enantioselective Synthesis of \u03b1-Chiral Heterocycles","volume":"14","author":"Le","year":"2012","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit12","doi-asserted-by":"publisher","first-page":"1535","DOI":"10.1016\/j.tetlet.2017.02.061","article-title":"Enantioselective\nOrganocatalytic Conjugate Addition\nof Organoboron Nucleophiles","volume":"58","author":"Nguyen","year":"2017","journal-title":"Tetrahedron Lett."},{"key":"2026081710233012400_cit13a","doi-asserted-by":"publisher","first-page":"7799","DOI":"10.1039\/c0cc03076g","article-title":"Enantioselective\nconjugate addition of boronic acids to enones catalyzed by O-monoacyltartaric acids","volume":"46","author":"Sugiura","year":"2010","journal-title":"Chem. Commun."},{"key":"2026081710233012400_cit13b","doi-asserted-by":"publisher","first-page":"5172","DOI":"10.1021\/ol502526y","article-title":"O-Monoacyltartaric\nAcid Catalyzed Enantioselective Conjugate Addition of a Boronic Acid\nto Dienones: Application to the Synthesis of Optically Active Cyclopentenones","volume":"16","author":"Sugiura","year":"2014","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit14","doi-asserted-by":"publisher","first-page":"2425","DOI":"10.1021\/ol9006053","article-title":"\u03b1\u03b2Hydroxyl\nGroup-Directed Organocatalytic Asymmetric Michael Addition of \u03b1,\u03b2-Unsaturated\nKetones with Alkenylboronic Acids","volume":"11","author":"Inokuma","year":"2009","journal-title":"Org. Lett."},{"key":"2026081710233012400_cit15","doi-asserted-by":"publisher","first-page":"15438","DOI":"10.1021\/ja0767480","article-title":"Organocatalytic Vinyl and Friedel\u2013Crafts Alkylations\nwith Trifluoroborate Salts","volume":"129","author":"Lee","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit16a","doi-asserted-by":"publisher","first-page":"2723","DOI":"10.1021\/cr020080k","article-title":"Crown Ethers:\nSensors for Ions and Molecular Scaffolds for Materials and Biological\nModels","volume":"104","author":"Gokel","year":"2004","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit16b","doi-asserted-by":"publisher","first-page":"1621","DOI":"10.1039\/c1cs15220c","article-title":"Supramolecular polymers\nconstructed by crown ether-based molecular recognition","volume":"41","author":"Zheng","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"2026081710233012400_cit16c","first-page":"763","article-title":"Self-Assembly of\nMechanically Interlocked Structures via Metal-Mediated Coordination\nCooperating with Host-Guest Recognition","volume":"27","author":"Ye","year":"2015","journal-title":"Prog.\nChem."},{"key":"2026081710233012400_cit16d","doi-asserted-by":"publisher","first-page":"7398","DOI":"10.1021\/cr5005869","article-title":"Development of pseudorotaxanes and rotaxanes: From\nsynthesis to stimuli-responsive motions to applications","volume":"115","author":"Xue","year":"2015","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit16e","doi-asserted-by":"publisher","first-page":"2459","DOI":"10.1039\/c7cs00185a","article-title":"Surveying macrocyclic\nchemistry: From flexible crown ethers to rigid cyclophanes","volume":"46","author":"Liu","year":"2017","journal-title":"Chem. Soc. Rev."},{"key":"2026081710233012400_cit17a","doi-asserted-by":"crossref","DOI":"10.1002\/9783527621781","volume-title":"Supramolecular catalysis","author":"van Leeuwen","year":"2008"},{"key":"2026081710233012400_cit17b","doi-asserted-by":"publisher","first-page":"1660","DOI":"10.1039\/c3cs60027k","article-title":"Supramolecular catalysis. Part 1: Non-covalent interactions\nas a tool for building and modifying homogeneous catalysts","volume":"43","author":"Raynal","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"2026081710233012400_cit17c","doi-asserted-by":"crossref","DOI":"10.1142\/9789811217807_0002","article-title":"Supramolecular\nCatalysts based on Crown Ethers and Polyethers","volume-title":"Supramolecular Catalysts: Design, Fabrication, and Applications","author":"Zhang","year":"2020"},{"key":"2026081710233012400_cit18a","doi-asserted-by":"publisher","first-page":"4334","DOI":"10.1002\/anie.201411593","article-title":"Cation-triggered switchable asymmetric\ncatalysis with chiral aza-crownphos","volume":"54","author":"Ouyang","year":"2015","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026081710233012400_cit18b","doi-asserted-by":"publisher","first-page":"4594","DOI":"10.1039\/c6sc00589f","article-title":"A supramolecularly tunable chiral diphosphine ligand:\napplication to Rh and Ir-catalyzed enantioselective hydrogenation","volume":"7","author":"Zhang","year":"2016","journal-title":"Chem. Sci."},{"key":"2026081710233012400_cit18c","doi-asserted-by":"publisher","first-page":"11038","DOI":"10.1039\/c6cc04474c","article-title":"Supramolecularly\nfine-regulated enantioselective catalysts","volume":"52","author":"Vaquero","year":"2016","journal-title":"Chem.\nCommun."},{"key":"2026081710233012400_cit19","doi-asserted-by":"publisher","first-page":"715","DOI":"10.1002\/poc.3086","article-title":"Preferential cross-coupling\nof naphthol derivatives mediated by copper\u00ad(II)","volume":"26","author":"Kos\u030cc\u030cova\u0301","year":"2013","journal-title":"J. Phys. Org. Chem."},{"key":"2026081710233012400_cit20","doi-asserted-by":"publisher","first-page":"5078","DOI":"10.1021\/jo8007463","article-title":"Theoretical\nstudy of the asymmetric\nconjugate alkenylation of enones catalyzed by binaphthols","volume":"73","author":"Paton","year":"2008","journal-title":"J. Org. Chem."},{"key":"2026081710233012400_cit21","doi-asserted-by":"publisher","first-page":"3337","DOI":"10.1016\/j.tetlet.2015.01.166","article-title":"Experimental mechanistic insight\ninto the BINOL-catalyzed enantioselective conjugate addition of boronates\nto enones","volume":"56","author":"Nguyen","year":"2015","journal-title":"Tetrahedron Lett."},{"key":"2026081710233012400_cit22","doi-asserted-by":"publisher","first-page":"2723","DOI":"10.1021\/cr020080k","article-title":"Crown Ethers: Sensors\nfor Ions and\nMolecular Scaffolds for Materials and Biological Models","volume":"104","author":"Gokel","year":"2004","journal-title":"Chem. Rev."},{"key":"2026081710233012400_cit23","doi-asserted-by":"publisher","first-page":"10244","DOI":"10.1021\/jacs.0c01563","article-title":"\u03b1\u03b2Chiral\nMetallacycles as Catalysts for\nAsymmetric Conjugate Addition of Styrylboronic Acids to \u03b1,\u03b2-Enones","volume":"142","author":"Hong","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026081710233012400_cit24","doi-asserted-by":"publisher","first-page":"4721","DOI":"10.1016\/j.tetlet.2012.06.105","article-title":"\u03b1\u03b2Trifluoroacetic\nanhydride-catalyzed conjugate addition of boronic acids to \u03b1,\u03b2-unsaturated\nketones","volume":"53","author":"Roscales","year":"2012","journal-title":"Tetrahedron Lett."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.1c05875","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/6\/50\/35093\/3667077\/ao1c05875.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/6\/50\/35093\/3667077\/ao1c05875.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:43:23Z","timestamp":1786977803000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/6\/50\/35093\/381024\/Crown-Ether-Derived-Chiral-BINOL-Enantioselective"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,12,10]]},"references-count":63,"journal-issue":{"issue":"50","published-online":{"date-parts":[[2021,12,10]]},"published-print":{"date-parts":[[2021,12,21]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.1c05875","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,12,10]]}}}