{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T01:39:36Z","timestamp":1792546776623,"version":"4.5.0"},"reference-count":84,"publisher":"American Chemical Society (ACS)","issue":"27","license":[{"start":{"date-parts":[[2022,6,27]],"date-time":"2022-06-27T00:00:00Z","timestamp":1656288000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2022,7,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>This study describes the preparation of new bimetallic (Fe\/Co)\u2013organic framework (Bi-MOF) nanocatalysts with different percentages of iron\/cobalt for their use and reuse in adsorption, antibacterial, antioxidant, and catalytic applications following the principles of green chemistry. The prepared catalysts were characterized using several techniques, including X-ray powder diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and scanning electron microscopy. These techniques proved the formation of MOFs, and the average crystallite sizes were 25.3\u201353.1, 27.6\u201367.2, 3.0\u201318.9, 3.0\u201312.9, and 3.0\u201323.6 nm for the Fe-MOF, Co-MOF, 10%Fe:90%Co-MOF, 50%Fe:50%Co-MOF, and 90%Fe:10%Co-MOF samples, respectively. The nanoscale (Fe\/Co) Bi-MOF catalysts as efficient heterogeneous solid catalysts showed high catalytic activity with excellent yields and short reaction times in the catalytic reactions of quinoxaline and dibenzoxanthene compounds, in addition to their antioxidant and antibacterial activities. Furthermore, the nanoscale (Fe\/Co) Bi-MOF catalysts efficiently removed toxic metal pollutants (Pb2+, Hg2+, Cd2+, and Cu2+) from aqueous solutions with high adsorption capacity.<\/jats:p>","DOI":"10.1021\/acsomega.2c01770","type":"journal-article","created":{"date-parts":[[2022,6,27]],"date-time":"2022-06-27T16:22:05Z","timestamp":1656346925000},"page":"23421-23444","source":"Crossref","is-referenced-by-count":80,"title":["Fe\/Co-MOF Nanocatalysts: Greener Chemistry Approach\nfor the Removal of Toxic Metals and Catalytic Applications"],"prefix":"10.1021","volume":"7","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2818-9613","authenticated-orcid":true,"given":"Fares T.","family":"Alshorifi","sequence":"first","affiliation":[{"name":"Sana\u2019a University , , ,","place":["Sana\u2019a, Yemen, 15452"]},{"name":"Mansoura University , , ,","place":["Mansoura, Egypt, 0020"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shady M.","family":"El Dafrawy","sequence":"additional","affiliation":[{"name":"Mansoura University , , ,","place":["Mansoura, Egypt, 0020"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Awad I.","family":"Ahmed","sequence":"additional","affiliation":[{"name":"Mansoura University , , ,","place":["Mansoura, Egypt, 0020"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,6,27]]},"reference":[{"key":"2026081710143189900_cit1","doi-asserted-by":"publisher","first-page":"3153","DOI":"10.1021\/cm301427w","article-title":"Stability and hydrolyzation of metal\norganic frameworks with paddle-wheel SBUs upon hydration","volume":"24","author":"Tan","year":"2012","journal-title":"J. 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