{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T23:08:18Z","timestamp":1791846498743,"version":"4.3.4"},"reference-count":63,"publisher":"American Chemical Society (ACS)","issue":"45","license":[{"start":{"date-parts":[[2022,10,31]],"date-time":"2022-10-31T00:00:00Z","timestamp":1667174400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/100018895","name":"National Institute of Technology, Raipur","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100018895","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2022,11,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A new mixed-ligand H-bonded coordination polymer {[Cu2(Or)2(Bimb)3]\u00b74H2O}n (KA@CP-S) has been prepared hydrothermally using basic copper carbonate with 1,4-bis\u00ad[(1H-imidazol-1-yl)\u00admethyl]\u00adbenzene (Bimb) and potassium orotate (OrK) ligands. According to topological studies, KA@CP-S has a new topology with a three-connected uninodal net with point symbol (PS) {82\u00b712}2{8}3. The KA@CP-S was employed as a catalyst for screening of a series of harmful cationic, anionic, and neutral organic dyes in contaminated water. The photocatalytic degradation study shows that it exhibits good catalytic efficiency for cationic dyes like Crystal Violet (CV, 75.8%), Methyl Violet (MV, 76.8%), and Rhodamine 6G (Rh6G, 86.5%) and Rose Bengal (RB, 76.1%), which is an anionic dye, while for a neutral dye, its catalytic efficiency is only 72% (Neutral Red) at ambient temperature. The effect of pH on photocatalytic degradation was also analyzed. The degradation experiment reveals that the detection limits of KA@CP-S for mostly catalyzed colorant concentrations in contaminated water are 0.60 ppm (CV), 0.20 ppm (RB), 0.33 ppm (MV), and 0.20 ppm (Rh6G) at pH 12, 4, and 10. The degradation of dyes follows pseudo-first-order kinetics. The excellent catalytic property and regeneration ability of KA@CP-S make it a potential and efficient future remedial material for the detection and separation of toxic dyes from wastewater contaminated by industrial effluents.<\/jats:p>","DOI":"10.1021\/acsomega.2c04669","type":"journal-article","created":{"date-parts":[[2022,10,31]],"date-time":"2022-10-31T13:21:05Z","timestamp":1667222465000},"page":"41120-41136","source":"Crossref","is-referenced-by-count":63,"title":["Synthesis of a\nMixed-Ligand H\u2011Bonded Cu Coordination\nPolymer: Exploring the pH-Dependent High Photocatalytic Degradation\nof Rhodamine 6G, Methyl Violet, Crystal Violet, and Rose Bengal Dyes\nunder Room Illumination"],"prefix":"10.1021","volume":"7","author":[{"family":"Somnath","sequence":"first","affiliation":[{"name":"National Institute of Technology Raipur , , Great Eastern Road , , ,","place":["Raipur, Chhattisgarh, India, 492010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7446-0232","authenticated-orcid":true,"given":"Musheer","family":"Ahmad","sequence":"additional","affiliation":[{"name":"Aligarh Muslim University , , , ,","place":["Aligarh, Uttar Pradesh, India, 202002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3292-3948","authenticated-orcid":true,"given":"Kafeel Ahmad","family":"Siddiqui","sequence":"additional","affiliation":[{"name":"National Institute of Technology Raipur , , Great Eastern Road , , ,","place":["Raipur, Chhattisgarh, India, 492010"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,10,31]]},"reference":[{"key":"2026081710064695400_cit1a","doi-asserted-by":"publisher","first-page":"1392","DOI":"10.1021\/ic102057p","article-title":"Structure and gas sorption\nbehavior of a new three-dimensional\nporous magnesium formate","volume":"50","author":"Mallick","year":"2011","journal-title":"Inorg. 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