{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T09:45:17Z","timestamp":1793612717618,"version":"4.5.0"},"reference-count":29,"publisher":"American Chemical Society (ACS)","issue":"9","license":[{"start":{"date-parts":[[2024,2,20]],"date-time":"2024-02-20T00:00:00Z","timestamp":1708387200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100009943","name":"Universidad Central de Venezuela","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009943","id-type":"DOI","asserted-by":"publisher"}]},{"name":"PDVSA-Intevep"},{"name":"Petr?leos de Venezuela S.A"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2024,3,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Hydrogen sulfide (H2S) mitigation through the use of additives in a laboratory-scale evaluation of steam injection in batch reactors was studied using extra heavy crude oil. For this purpose, additives based on biogenic amines from a fishing effluent were used with methanol and ethanol as solvents in a previous extraction of industrial fishmeal waste. The study of the extracts using high-performance liquid chromatography (HPLC) permitted the determination that the methanol-based extract with 48 h of decomposition had the highest biogenic amine content, totaling 1472 ppm. In addition, methanol extractions were more efficient, with an average biogenic amine content of 592 ppm. Subsequent evaluations were carried out for sand\/oil\/water\/scavenging additive systems, where solutions of commercial organic compounds, analytical-grade histamine, and biogenic amine extracts were used. These evaluations were performed at a constant temperature of 247 \u00b0C and under an initial pressurization of methane gas of 215 psig, with a reaction time of 24 h. Characterization of gaseous effluents for each system allowed us to determine that the methods in which biogenic amine extracts were used with methanol were more effective in H2S scavenging because they had the lowest gas concentration at the end of the reaction time. Within this group, the most effective was the C1 extract, with a H2S reduction from 1700 to 150 ppm, representing 91% removal. The biogenic amine family produced by decomposition in conjunction with histamine has a synergistic effect in tests under vapor injection conditions when comparing the results with analytical-grade histamine solution-based additives and commercial additives. This study shows that using steam injection technology to use biogenic amines in H2S mitigation is feasible.<\/jats:p>","DOI":"10.1021\/acsomega.3c09235","type":"journal-article","created":{"date-parts":[[2024,2,20]],"date-time":"2024-02-20T16:05:00Z","timestamp":1708445100000},"page":"10671-10679","source":"Crossref","is-referenced-by-count":4,"title":["New Trends for\nHydrogen Sulfide Scavenging Using Natural\nCompounds as Biogenic Amines"],"prefix":"10.1021","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-5005-0833","authenticated-orcid":true,"given":"Yefrenck E.","family":"Castro","sequence":"first","affiliation":[{"name":"Universidad Central de Venezuela , , Ciudad Universitaria de Caracas , ,","place":["Caracas, Venezuela, 1053"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alfredo","family":"Viloria","sequence":"additional","affiliation":[{"name":"Universidad Central de Venezuela , , Ciudad Universitaria de Caracas , ,","place":["Caracas, Venezuela, 1053"]},{"name":"Yachay Tech University , , Hda. San Jose\u0301 s\/n y Proyecto Yachay , ,","place":["Urcuqui\u0301, Ecuador, 100119"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2024,2,20]]},"reference":[{"key":"2026081709152748600_cit1","doi-asserted-by":"publisher","first-page":"219","DOI":"10.1016\/j.fuel.2015.04.065","article-title":"Aquathermolysis of Heavy Oil: A Review and Perspective\non Catalyst Development","volume":"157","author":"Muraza","year":"2015","journal-title":"Fuel"},{"key":"2026081709152748600_cit2","volume-title":"Aquathermolysis: A Synopsis\nof Work on the Chemical Reaction between Water (Steam) and Heavy Oil\nSands during Simulated Steam Stimulation","author":"Hyne","year":"1986","edition":"1"},{"issue":"6","key":"2026081709152748600_cit3","doi-asserted-by":"publisher","first-page":"339","DOI":"10.1002\/cben.201600026","article-title":"A Comprehensive Review of H2S Scavenger Technologies from Oil and Gas Streams","volume":"4","author":"Agbroko","year":"2017","journal-title":"ChemBioEng Rev."},{"issue":"32","key":"2026081709152748600_cit4","doi-asserted-by":"publisher","first-page":"10898","DOI":"10.1002\/anie.201905580","article-title":"Data-Driven Identification\nof Hydrogen Sulfide Scavengers","volume":"58","author":"Yang","year":"2019","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026081709152748600_cit5","doi-asserted-by":"crossref","unstructured":"Ali, S. M. F.\n           In Steam Injection\nTheories \u2013 A Unified Approach, SPE California Regional\nMeeting, 1982.","DOI":"10.2523\/10746-MS"},{"key":"2026081709152748600_cit6","doi-asserted-by":"publisher","first-page":"363","DOI":"10.1111\/j.1747-5457.1983.tb00589.x","article-title":"Gas Evolution\nand Change of Oil Composition during Steam Flooding of Oil Reservoirs","volume":"5","author":"Akstinat","year":"1982","journal-title":"J. Pet. Geol."},{"key":"2026081709152748600_cit7","doi-asserted-by":"crossref","unstructured":"Ovalles, C.; Vallejos, C.; Va\u0301squez, T.; Martinis, J.; Perez-Perez, A.; Cotte, E.; Castellanos, L.; Rodri\u0301guez, H. In Extra-Heavy\nCrude Oil Downhole\nUpgrading Process Using Hydrogen Donors under Steam Injection Conditions, SPE International Thermal Operations and Heavy Oil Symposium, 2001.","DOI":"10.2118\/69692-MS"},{"issue":"1\u20132","key":"2026081709152748600_cit8","doi-asserted-by":"publisher","first-page":"30","DOI":"10.1016\/j.petrol.2010.01.002","article-title":"Induced H2S\nFormation\nduring Steam Injection Recovery Process of Heavy Oil from the Liaohe\nBasin, NE China","volume":"71","author":"Zhu","year":"2010","journal-title":"J. Pet. Sci. Eng."},{"issue":"15","key":"2026081709152748600_cit9","doi-asserted-by":"publisher","first-page":"7488","DOI":"10.3390\/app12157488","article-title":"Experimental\nMeasurements and Numerical Simulation of H2S Generation\nduring Cyclic Steam Stimulation Process of Offshore Heavy Oil from\nBohai Bay, China","volume":"12","author":"Wang","year":"2022","journal-title":"Appl. Sci."},{"issue":"11","key":"2026081709152748600_cit10","doi-asserted-by":"publisher","first-page":"4019","DOI":"10.1007\/s13202-021-01293-0","article-title":"Enhanced Aquathermolysis\nof Extra-Heavy Oil by Application\nof Transition Metal Oxides Submicro-Particles in Relation to Steam\nInjection Processes","volume":"11","author":"Zhang","year":"2021","journal-title":"J. Pet. Explor. Prod. Technol."},{"key":"2026081709152748600_cit11","doi-asserted-by":"publisher","first-page":"426","DOI":"10.1016\/j.fuel.2013.05.098","article-title":"High Temperature\nReactions of Water with Heavy Oil and Bitumen: Insights into Aquathermolysis\nChemistry during Steam-Assisted Recovery","volume":"113","author":"Montgomery","year":"2013","journal-title":"Fuel"},{"issue":"13","key":"2026081709152748600_cit12","doi-asserted-by":"publisher","first-page":"12165","DOI":"10.1021\/acsomega.2c08103","article-title":"Study of the Reaction Mechanism of\nTriazines and Associated Species for H 2 S Scavenging","volume":"8","author":"Roma\u0301n","year":"2023","journal-title":"ACS Omega"},{"issue":"6","key":"2026081709152748600_cit13","doi-asserted-by":"publisher","first-page":"663","DOI":"10.1515\/revce-2019-0049","article-title":"Research\nAdvancements in Sulfide Scavengers for Oil and Gas Sectors","volume":"37","author":"Saji","year":"2021","journal-title":"Rev. Chem. Eng."},{"key":"2026081709152748600_cit14","first-page":"23","article-title":"Effect of Mineral Compounds of Sands\non Acid Gases Generation at Steam Injection Conditions","volume":"26","author":"Castro","year":"2019","journal-title":"Rev. Ing. 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Sci. Food\nAgric."},{"issue":"6","key":"2026081709152748600_cit19","doi-asserted-by":"publisher","first-page":"3123","DOI":"10.1002\/fsn3.2271","article-title":"Formation of Biogenic Amines in Fish: Dietary Intakes\nand Health Risk Assessment","volume":"9","author":"El-Ghareeb","year":"2021","journal-title":"Food Sci. Nutr."},{"key":"2026081709152748600_cit20","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1016\/B978-0-12-824296-4.00002-5","article-title":"Sustainable\nFish and Seafood Production and Processing","volume-title":"Sustainable Fish Production and Processing","author":"Saleh","year":"2022"},{"issue":"3\u20134","key":"2026081709152748600_cit21","doi-asserted-by":"publisher","first-page":"280","DOI":"10.1016\/j.jfca.2006.06.009","article-title":"Extraction of Bioactive Amines from\nGrated Parmesan Cheese Using Acid, Alkaline and Organic Solvents","volume":"20","author":"Custo\u0301dio","year":"2007","journal-title":"J. Food Compos. 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Cienc. Ing."},{"issue":"7","key":"2026081709152748600_cit26","doi-asserted-by":"publisher","first-page":"5323","DOI":"10.1021\/acs.energyfuels.5b02646","article-title":"Experimental Determination\nof In Situ Hydrogen Sulfide Production during Thermal Recovery Processes","volume":"30","author":"Lin","year":"2016","journal-title":"Energy Fuels"},{"key":"2026081709152748600_cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2020.119817","article-title":"The Water Gas Shift\nReaction: Catalysts and Reaction Mechanism","volume":"288","author":"Baraj","year":"2021","journal-title":"Fuel"},{"issue":"4","key":"2026081709152748600_cit28","doi-asserted-by":"publisher","first-page":"1421","DOI":"10.1021\/ie061180+","article-title":"Enthalpy and\nSolubility Data of H2S\nin Water at Conditions of Interest for Geological Sequestration","volume":"46","author":"Koschel","year":"2007","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026081709152748600_cit29","doi-asserted-by":"crossref","unstructured":"Lamoureux-Var, V.; Lorant, F. In H2S Artificial Formation as a Result of Steam Injection\nfor\nEOR: A Compositional Kinetic Approach, SPE International\nThermal Operations and Heavy Oil Symposium, 2005.","DOI":"10.2118\/97810-MS"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.3c09235","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/9\/9\/10671\/4433049\/ao3c09235.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/9\/9\/10671\/4433049\/ao3c09235.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T13:27:20Z","timestamp":1786973240000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/9\/9\/10671\/411015\/New-Trends-for-Hydrogen-Sulfide-Scavenging-Using"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,2,20]]},"references-count":29,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2024,2,20]]},"published-print":{"date-parts":[[2024,3,5]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.3c09235","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,2,20]]}}}