{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:55:24Z","timestamp":1787072124790,"version":"build-2736575974"},"reference-count":25,"publisher":"American Chemical Society (ACS)","issue":"7","license":[{"start":{"date-parts":[[2025,2,10]],"date-time":"2025-02-10T00:00:00Z","timestamp":1739145600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100009383","name":"Islamic Azad University, Arak Branch","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009383","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002725","name":"Amirkabir University of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018993","name":"Rajamangala University of Technology Phra Nakhon","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100018993","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007504","name":"Istanbul Teknik ?niversitesi","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007504","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2025,2,25]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The main objective of this research is to investigate the electrochemical characteristics of Ni\u2013Cu-plated polyester when MnO2 is deposited on it and serves as a flexible electrode. For this purpose, the Ni\u2013Cu-plated polyester electrode fabrics prepared in this way were deposited with MnO2 over different immersion times. The conductive polyester electrode that was prepared underwent immersion in an aqueous solution of KMnO4 (0.1 M) for durations of 5, 10, and 30 min. The electrical resistance of the prepared samples was measured using a two-point probe technique. Additionally, the electrochemical properties of the Ni\u2013Cu-plated polyester with MnO2 deposition were examined using a three-electrode cell setup under ambient conditions. The surface structure and elemental composition of the sample electrodes were examined with a scanning electron microscope (SEM). In this research, the asymmetric supercapacitor cell (ASC) consisting of a Ni\u2013Cu\/MnO2-deposited textile as the cathode electrode and active carbon-coated activated carbon cloth as the anode electrode was assembled. Also, the symmetric supercapacitor cell (SSC) using Ni\u2013Cu\/MnO2 deposited polyester as both the anode and cathode was assembled. Cyclic voltammetry (CV), galvanostatic charging\u2013discharging (GCD), and electrochemical impedance spectroscopy (EIS) measurements were utilized to assess and compare the electrochemical performance. The areal specific capacitances of the ASC at current densities of 2, 4, 8, and 16 mA cm\u20132 were calculated to be 558.6, 481.9, 435.5, and 330 mF cm\u20132, respectively. In comparison, the achieved storage results related to ASC are far higher than those of SSC. The results are discussed in the text in detail.<\/jats:p>","DOI":"10.1021\/acsomega.4c10183","type":"journal-article","created":{"date-parts":[[2025,2,10]],"date-time":"2025-02-10T21:01:21Z","timestamp":1739221281000},"page":"7091-7101","source":"Crossref","is-referenced-by-count":5,"title":["MnO2\/Ni\u2013Cu-Plated Polyester Fabric\nas a Free-Standing Electrode in Supercapacitor Applications"],"prefix":"10.1021","volume":"10","author":[{"given":"Sheila","family":"Shahidi","sequence":"first","affiliation":[{"name":"Islamic Azad University, Arak Branch , , ,","place":["Arak, Iran, 38361-1-9131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fatma","family":"Kalaoglu","sequence":"additional","affiliation":[{"name":"Istanbul Technical University , , ,","place":["Istanbul, Turkey, 34437"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1593-2751","authenticated-orcid":true,"given":"Leila","family":"Naji","sequence":"additional","affiliation":[{"name":"Amirkabir University of Technology (Tehran Polytechnic) , , ,","place":["Tehran, Iran, 15916-3-4311"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alireza","family":"Rahmanian","sequence":"additional","affiliation":[{"name":"Amirkabir University of Technology (Tehran Polytechnic) , , ,","place":["Tehran, Iran, 15916-3-4311"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3288-910X","authenticated-orcid":true,"given":"Rattanaphol","family":"Mongkholrattanasit","sequence":"additional","affiliation":[{"name":"Rajamangala University of Technology Phra Nakhon , , ,","place":["Bangkok, Thailand, 10300"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,2,10]]},"reference":[{"key":"2026081811201428400_cit1","doi-asserted-by":"publisher","first-page":"262","DOI":"10.1016\/j.electacta.2018.07.036","article-title":"A high-performance,\nall-textile and spirally wound asymmetric supercapacitors based on\ncore\u2013sheath structured MnO2 nanoribbons and cotton-derived\ncarbon cloth","volume":"285","author":"Wan","year":"2018","journal-title":"Electrochim. Acta"},{"key":"2026081811201428400_cit2","doi-asserted-by":"publisher","first-page":"180","DOI":"10.1016\/j.apsusc.2019.05.054","article-title":"Fabrication of MnO2-carbonized cotton yarn\nderived hierarchical porous active carbon flexible supercapacitor\nelectrodes for potential applications in cable-type devices","volume":"487","author":"Ullah","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"2026081811201428400_cit3","doi-asserted-by":"publisher","first-page":"486","DOI":"10.1016\/j.electacta.2016.05.082","article-title":"Hydrothermal\nsynthesis and electrochemical performance of MnO2\/graphene\/polyester\ncomposite electrode materials for flexible supercapacitors","volume":"209","author":"Guo","year":"2016","journal-title":"Electrochim. Acta"},{"key":"2026081811201428400_cit4","doi-asserted-by":"publisher","first-page":"151789","DOI":"10.1016\/j.jallcom.2019.151789","article-title":"Design and synthesis\nof tremella-like Ni\u2013Co\u2013S\nflakes on co-coated cotton textile as high-performance electrode for\nflexible supercapacitor","volume":"814","author":"Wang","year":"2020","journal-title":"J. Alloys Compd."},{"key":"2026081811201428400_cit5","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1016\/j.jpowsour.2018.09.030","article-title":"Novel high-performance asymmetric\nsupercapacitors based on nickel-cobalt composite and PPy for flexible\nand wearable energy storage","volume":"402","author":"Wen","year":"2018","journal-title":"J. Power Sources"},{"key":"2026081811201428400_cit6","doi-asserted-by":"publisher","first-page":"634","DOI":"10.1016\/j.carbon.2018.09.011","article-title":"A MnO2 nanosheet\/single-wall carbon nanotube\nhybrid fiber for wearable\nsolid-state supercapacitors","volume":"140","author":"Li","year":"2018","journal-title":"Carbon"},{"key":"2026081811201428400_cit7","doi-asserted-by":"publisher","first-page":"593","DOI":"10.1016\/j.jallcom.2018.09.383","article-title":"Super flexible\nelectrospun carbon\/nickel nanofibrous film electrode\nfor supercapacitors","volume":"774","author":"Lu","year":"2019","journal-title":"J. Alloys Compd."},{"key":"2026081811201428400_cit8","doi-asserted-by":"publisher","first-page":"157","DOI":"10.1016\/j.jpowsour.2018.08.014","article-title":"Yarn-form electrodes\nwith high capacitance and cycling stability based on hierarchical\nnanostructured nickel-cobalt mixed oxides for weavable fiber-shaped\nsupercapacitors","volume":"400","author":"Wei","year":"2018","journal-title":"J. Power Sources"},{"key":"2026081811201428400_cit9","doi-asserted-by":"publisher","first-page":"75","DOI":"10.1016\/j.ensm.2017.09.013","article-title":"A non-polarity\nflexible asymmetric\nsupercapacitor with nickel nanoparticle@ carbon nanotube three-dimensional\nnetwork electrodes","volume":"11","author":"Jiang","year":"2018","journal-title":"Energy Storage Mater."},{"key":"2026081811201428400_cit10","doi-asserted-by":"publisher","first-page":"318","DOI":"10.1016\/j.est.2018.03.015","article-title":"In-situ growth of MnO2 nanorods forest on\ncarbon textile as efficient electrode\nmaterial for supercapacitors","volume":"17","author":"Shah","year":"2018","journal-title":"J. Energy Storage"},{"key":"2026081811201428400_cit11","doi-asserted-by":"publisher","first-page":"986","DOI":"10.1016\/j.jallcom.2018.12.254","article-title":"Flexible all-solid\nplanar fibrous cellulose nonwoven fabric-based\nsupercapacitor via capillarity-assisted graphene\/MnO2 assembly","volume":"782","author":"Li","year":"2019","journal-title":"J. Alloys Compd."},{"key":"2026081811201428400_cit12","doi-asserted-by":"publisher","first-page":"1047","DOI":"10.1016\/j.cej.2019.04.202","article-title":"Hierarchical\nMnO2\/activated carbon cloth electrode prepared by synchronized\nelectrochemical activation and oxidation for flexible asymmetric supercapacitors","volume":"372","author":"Zhang","year":"2019","journal-title":"Chem. Eng. J."},{"key":"2026081811201428400_cit13","doi-asserted-by":"publisher","first-page":"12","DOI":"10.1016\/j.electacta.2018.12.181","article-title":"High-performance flexible MnO2@ carbonized cotton textile\nelectrodes for enlarged operating potential window symmetrical supercapacitors","volume":"299","author":"Wang","year":"2019","journal-title":"Electrochim. 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Text."},{"key":"2026081811201428400_cit17","doi-asserted-by":"publisher","first-page":"104146","DOI":"10.1016\/j.est.2022.104146","article-title":"Systematic study of influencing parameters on the in-situ electrochemical\ngrowth of three-dimensional graphene on carbon cloth for supercapacitor\napplications","volume":"49","author":"Rahmanian","year":"2022","journal-title":"J. Energy Storage"},{"key":"2026081811201428400_cit18","doi-asserted-by":"publisher","first-page":"9","DOI":"10.1016\/j.electacta.2018.05.108","article-title":"Facile and fast\nmicrowave-assisted fabrication of activated and porous carbon cloth\ncomposites with graphene and MnO2 for flexible asymmetric\nsupercapacitors","volume":"280","author":"Jeon","year":"2018","journal-title":"Electrochim. Acta"},{"key":"2026081811201428400_cit19","doi-asserted-by":"publisher","first-page":"128450","DOI":"10.1016\/j.colsurfa.2022.128450","article-title":"Graphene oxide-assisted\nelectrochemical growth of Ni (OH)2 nanoflowers on nickel\nfoam as electrode material for high-performance\nsupercapacitors","volume":"640","author":"Rahmanian","year":"2022","journal-title":"Colloids Surf., A"},{"key":"2026081811201428400_cit20","doi-asserted-by":"publisher","first-page":"321","DOI":"10.1016\/j.electacta.2018.12.103","article-title":"High rate\ncapability electrode constructed by anchoring CuCo2S4 on graphene aerogel skeleton toward quasi-solid-state supercapacitor","volume":"298","author":"Tian","year":"2019","journal-title":"Electrochim. 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J."},{"key":"2026081811201428400_cit23","doi-asserted-by":"publisher","first-page":"136746","DOI":"10.1016\/j.electacta.2020.136746","article-title":"The construction\nof sea urchin spines-like polypyrrole arrays on cotton-based fabric\nelectrode via a facile electropolymerization for high performance\nflexible solid-state supercapacitors","volume":"354","author":"Sun","year":"2020","journal-title":"Electrochim.\nActa"},{"key":"2026081811201428400_cit24","doi-asserted-by":"publisher","first-page":"794","DOI":"10.1016\/j.electacta.2018.12.042","article-title":"A stretchable and hydrophobic polypyrrole\/knitted\ncotton fabric electrode\nfor all-solid-state supercapacitor with excellent strain capacitance","volume":"297","author":"Wang","year":"2019","journal-title":"Electrochim. Acta"},{"key":"2026081811201428400_cit25","doi-asserted-by":"publisher","first-page":"469","DOI":"10.1039\/C0NJ00712A","article-title":"Porous\nnano-MnO2: large\nscale synthesis via a facile quick-redox procedure and application\nin a supercapacitor","volume":"35","author":"Wang","year":"2011","journal-title":"New J. Chem."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.4c10183","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/10\/7\/7091\/40796872\/ao4c10183.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/10\/7\/7091\/40796872\/ao4c10183.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:22:38Z","timestamp":1787070158000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/10\/7\/7091\/3652286\/MnO2-Ni-Cu-Plated-Polyester-Fabric-as-a-Free"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,10]]},"references-count":25,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2025,2,10]]},"published-print":{"date-parts":[[2025,2,25]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.4c10183","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,10]]}}}