{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:52:23Z","timestamp":1787071943795,"version":"build-2736575974"},"reference-count":55,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T00:00:00Z","timestamp":1785974400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003141","name":"Consejo Nacional de Humanidades, Ciencias y Tecnolog?as","doi-asserted-by":"publisher","award":["315787"],"award-info":[{"award-number":["315787"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003141","name":"Consejo Nacional de Humanidades, Ciencias y Tecnolog?as","doi-asserted-by":"publisher","award":["SIP-20251243"],"award-info":[{"award-number":["SIP-20251243"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003141","name":"Consejo Nacional de Humanidades, Ciencias y Tecnolog?as","doi-asserted-by":"publisher","award":["SIP-20251331"],"award-info":[{"award-number":["SIP-20251331"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003141","name":"Consejo Nacional de Humanidades, Ciencias y Tecnolog?as","doi-asserted-by":"publisher","award":["SIP-2377"],"award-info":[{"award-number":["SIP-2377"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010567","name":"Secretar?a de Estado de Ciencia, Tecnolog?a e Innovaci?n","doi-asserted-by":"publisher","award":["SECTEI-093-2023"],"award-info":[{"award-number":["SECTEI-093-2023"]}],"id":[{"id":"10.13039\/501100010567","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010567","name":"Secretar?a de Estado de Ciencia, Tecnolog?a e Innovaci?n","doi-asserted-by":"publisher","award":["SECTEI-243-2020"],"award-info":[{"award-number":["SECTEI-243-2020"]}],"id":[{"id":"10.13039\/501100010567","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>This study investigates the potential of conditioned Jatropha curcas shell residues as sustainable and cost-effective bioadsorbents for the removal of Cr(III) from aqueous solutions. Adsorption performance was evaluated under varying conditions of pH (3.05 and 3.89), temperature (30 and 50 \u00b0C), and particle size (250 and 420 \u03bcm). BET analysis revealed that smaller particles (250 \u03bcm) exhibited a higher surface area (2.175 m2\/g) and pore volume (0.019 cm3\/g) compared to larger ones. FTIR spectroscopy confirmed enhanced exposure of hydroxyl (\u2212OH) and carboxylate (\u2212COO\u2013) groups after mild conditioning, promoting effective Cr(III) interactions. ANOVA results indicated a highly significant model (F = 1228.114, p &amp;lt; 0.0001), and Pearson correlation identified pH and particle size as the most influential variables. The Langmuir isotherm best described the equilibrium data, with a maximum adsorption capacity (Qmax) of 13.81 mg\/g for 250 \u03bcm particles. The proposed adsorption mechanism involved electrostatic attraction, ion exchange, and surface complexation with a final pH increase to 5.96. Under optimal conditions, a maximum Cr(III) removal efficiency of 98.75% was achieved. Importantly, this study introduces a dual-valorization strategy that transforms Jatropha curcas shells, an agroindustrial waste, into both an efficient bioadsorbent and a potential solid biofuel. Jatropha curcas shell analysis demonstrated that the spent shells retain a significantly higher heating value (15.4 MJ\/kg), enabling their direct use in energy recovery applications without requiring conversion to biochar. This approach reduces processing steps while maintaining energetic value, enhancing the practicality and sustainability of the process. The proposed method offers a simple, nontoxic, and scalable solution to integrate heavy metal remediation with post-treatment energy recovery, contributing to zero-waste circular bioeconomy schemes and sustainable wastewater management.<\/jats:p>","DOI":"10.1021\/acsomega.5c06869","type":"journal-article","created":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T01:01:30Z","timestamp":1786064490000},"page":"47237-47251","source":"Crossref","is-referenced-by-count":0,"title":["Evaluation of Cr(III)\nAdsorption Using Activated\n                    <i>Jatropha curcas<\/i>\n                    Shell: Kinetics and Energy Recovery"],"prefix":"10.1021","volume":"11","author":[{"given":"Violeta Y.","family":"Mena-Cervantes","sequence":"first","affiliation":[{"name":"Instituto Polite\u0301cnico Nacional , , Av. Acueducto S\/N, Col. La Laguna Ticoma\u0301n , c.p. ,","place":["Ciudad de Me\u0301xico, Me\u0301xico, 07340"]},{"name":"Laboratorio Nacional de Desarrollo y Aseguramiento de la Calidad de Biocombustibles (LaNDACBio) , c.p. ,","place":["Ciudad de Me\u0301xico, Mexico, 07340"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mario A.","family":"Gonza\u0301lez Espinosa","sequence":"additional","affiliation":[{"name":"Instituto Polite\u0301cnico Nacional , , Av. Acueducto S\/N, Col. La Laguna Ticoma\u0301n , c.p. ,","place":["Ciudad de Me\u0301xico, Me\u0301xico, 07340"]},{"name":"Laboratorio Nacional de Desarrollo y Aseguramiento de la Calidad de Biocombustibles (LaNDACBio) , c.p. ,","place":["Ciudad de Me\u0301xico, Mexico, 07340"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Edwin J.","family":"Barrios Go\u0301mez","sequence":"additional","affiliation":[{"name":"Laboratorio Nacional de Desarrollo y Aseguramiento de la Calidad de Biocombustibles (LaNDACBio) , c.p. ,","place":["Ciudad de Me\u0301xico, Mexico, 07340"]},{"name":"Campo Experimental Zacatepec-INIFAP Carretera Zacatepec-Galeana S\/N, Km 0.5 Col. Centro , , c.p. ,","place":["Morelos, Mexico, 62780"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3021-1186","authenticated-orcid":true,"given":"Fidel A.","family":"Aguilar-Aguilar","sequence":"additional","affiliation":[{"name":"Instituto Polite\u0301cnico Nacional , , Av. Acueducto S\/N, Col. La Laguna Ticoma\u0301n , c.p. ,","place":["Ciudad de Me\u0301xico, Me\u0301xico, 07340"]},{"name":"Laboratorio Nacional de Desarrollo y Aseguramiento de la Calidad de Biocombustibles (LaNDACBio) , c.p. ,","place":["Ciudad de Me\u0301xico, Mexico, 07340"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandra S.","family":"Morales-Garci\u0301a","sequence":"additional","affiliation":[{"name":"Instituto Polite\u0301cnico Nacional , , Av. Acueducto S\/N, Col. La Laguna Ticoma\u0301n , c.p. ,","place":["Ciudad de Me\u0301xico, Me\u0301xico, 07340"]},{"name":"Laboratorio Nacional de Desarrollo y Aseguramiento de la Calidad de Biocombustibles (LaNDACBio) , c.p. ,","place":["Ciudad de Me\u0301xico, Mexico, 07340"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-5247-9658","authenticated-orcid":true,"given":"Rau\u0301l","family":"Herna\u0301ndez-Altamirano","sequence":"additional","affiliation":[{"name":"Instituto Polite\u0301cnico Nacional , , Av. Acueducto S\/N, Col. 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Clean Prod."},{"issue":"3","key":"2026081810490902300_cit15","doi-asserted-by":"publisher","first-page":"489","DOI":"10.1007\/s40899-017-0130-7","article-title":"Enhanced Chromium(VI)\nRemoval Using Banana Peel Dust: Isotherms, Kinetics and Thermodynamics\nStudy","volume":"4","author":"Mondal","year":"2018","journal-title":"Sustain Water Resour Manag."},{"issue":"6","key":"2026081810490902300_cit16","doi-asserted-by":"publisher","first-page":"844","DOI":"10.3390\/w14060844","article-title":"Equilibrium,\nKinetics and Thermodynamics of Chromium (VI) Adsorption on Inert Biomasses\nof Dioscorea Rotundata and Elaeis Guineensis","volume":"14","author":"Villabona-Orti\u0301z","year":"2022","journal-title":"Water"},{"issue":"1","key":"2026081810490902300_cit17","doi-asserted-by":"publisher","first-page":"9","DOI":"10.22507\/pml.v10n1a1","article-title":"Absorcio\u0301n de\nCromo Hexavalente En Soluciones Acuosas Por Cascaras de Naranja (Citrus\nSinensis)","volume":"10","author":"Tejada Tovar","year":"2015","journal-title":"Produccio\u0301n + Limpia"},{"key":"2026081810490902300_cit18","doi-asserted-by":"publisher","first-page":"160957","DOI":"10.1016\/j.scitotenv.2022.160957","article-title":"Interactions between Cr(VI) and the\nHydrochar: The Electron Transfer Routes, Adsorption Mechanisms, and\nthe Accelerating Effects of Wood Vinegar","volume":"863","author":"Wang","year":"2023","journal-title":"Sci.\nTotal Environ."},{"key":"2026081810490902300_cit19","doi-asserted-by":"publisher","first-page":"107518","DOI":"10.1016\/j.biombioe.2024.107518","article-title":"Thermal, Structural,\nand Compositional Evaluation of Coyol Shell Pretreatments for Enhanced\nLignocellulosic Biomass Utilization","volume":"193","author":"Aguilar-Aguilar","year":"2025","journal-title":"Biomass\nBioenergy"},{"issue":"11","key":"2026081810490902300_cit20","doi-asserted-by":"publisher","first-page":"1","DOI":"10.4236\/oalib.1101988","article-title":"Adsorption\nKinetics and Mechanisms\nof Cypermethrin and Dichlorovos on Heterogeneous Activated Carbon\nPorous Media","volume":"2","author":"Uzoije","year":"2015","journal-title":"OAlib"},{"issue":"17","key":"2026081810490902300_cit21","doi-asserted-by":"publisher","first-page":"5267","DOI":"10.3390\/molecules26175267","article-title":"Effect of Pore Size Distribution\nand Amination on Adsorption Capacities\nof Polymeric Adsorbents","volume":"26","author":"Liu","year":"2021","journal-title":"Molecules"},{"key":"2026081810490902300_cit22","doi-asserted-by":"publisher","first-page":"109011","DOI":"10.1016\/j.buildenv.2022.109011","article-title":"Influence\nof Pore Volume and Surface Area on Benzene Adsorption Capacity of\nActivated Carbons in Indoor Environments","volume":"216","author":"Zhang","year":"2022","journal-title":"Build\nEnviron."},{"issue":"23","key":"2026081810490902300_cit23","doi-asserted-by":"publisher","first-page":"4565","DOI":"10.3390\/en12234565","article-title":"A Statistical Approach to Determine\nOptimal Models\nfor IUPAC-Classified Adsorption Isotherms","volume":"12","author":"Rahman","year":"2019","journal-title":"Energies"},{"issue":"2","key":"2026081810490902300_cit24","doi-asserted-by":"publisher","first-page":"37","DOI":"10.26807\/ia.v10i2.234","article-title":"Disminucio\u0301n\nde cromo y cobre\nen aguas residuales utilizando ca\u0301scaras (naranja y banano)\ncomo bioadsorbente","volume":"10","author":"Ponce","year":"2022","journal-title":"infoAnali\u0301tica"},{"key":"2026081810490902300_cit25","doi-asserted-by":"publisher","first-page":"17265","DOI":"10.1007\/s00289-024-05523-3","article-title":"NaOH-Treated Rice Husk,\na Lignocellulosic Biomaterial for Removal of Cr(VI) from Polluted\nWater","volume":"81","author":"Kaur","year":"2024","journal-title":"Polym. 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