{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,26]],"date-time":"2026-02-26T18:36:39Z","timestamp":1772130999774,"version":"3.50.1"},"reference-count":61,"publisher":"American Chemical Society (ACS)","issue":"49","license":[{"start":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T00:00:00Z","timestamp":1764720000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004586","name":"Funda??o Carlos Chagas Filho de Amparo ? Pesquisa do Estado do Rio de Janeiro","doi-asserted-by":"publisher","award":["E-26\/200.249\/2023"],"award-info":[{"award-number":["E-26\/200.249\/2023"]}],"id":[{"id":"10.13039\/501100004586","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ACS Omega"],"published-print":{"date-parts":[[2025,12,16]]},"DOI":"10.1021\/acsomega.5c07780","type":"journal-article","created":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T18:55:51Z","timestamp":1764788151000},"page":"60450-60456","source":"Crossref","is-referenced-by-count":0,"title":["New Molecular Geometries with Pentagonal-Pyramidal Structure"],"prefix":"10.1021","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9472-3899","authenticated-orcid":true,"given":"Ricardo R.","family":"Oliveira","sequence":"first","affiliation":[{"name":"Chemistry Institute","place":["Rio de Janeiro, Brazil"]},{"name":"Federal University of Rio de Janeiro","place":["Rio de Janeiro, Brazil"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2489-8559","authenticated-orcid":true,"given":"Wania","family":"Wolff","sequence":"additional","affiliation":[{"name":"Physics Institute","place":["Rio de Janeiro, Brazil"]},{"name":"Federal University of Rio de Janeiro","place":["Rio de Janeiro, Brazil"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4046-1963","authenticated-orcid":true,"given":"Amir L.","family":"Perlin","sequence":"additional","affiliation":[{"name":"Chemistry Institute","place":["Rio de Janeiro, Brazil"]},{"name":"Federal University of Rio de Janeiro","place":["Rio de Janeiro, Brazil"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2025,12,3]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC04754F"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00489"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.3c01973"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/ja412109h"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/jp5088064"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03816"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37058-y"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198109913"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jo010438x"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.09.008"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198913211"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608795"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1038\/nature14566"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1038\/s41550-019-0941-6"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.3847\/2041-8213\/abe874"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP03254J"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-2966.2012.21097.x"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1051\/0004-6361\/202038139"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.3847\/1538-4357\/abf93e"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1051\/0004-6361\/202039744"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/ja00002a006"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jp053907y"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.0c07931"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP04247B"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1016\/j.comptc.2017.03.020"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202100940"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.3390\/atoms11030056"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/jp0545288"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.3847\/0004-637X\/821\/1\/4"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1093\/mnras\/staa3181"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1093\/mnras\/stac679"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1080\/00268976.2023.2225644"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.0c00686"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12749"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1039\/b305686d"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1039\/C4CP04323E"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1007\/s00894-025-06457-x"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/ct050093g"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.23235"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/ct500744k"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.8b00772"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-020-2548-5"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP04060D"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP06313B"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.9b01107"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1002\/qua.26553"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ01022J"},{"key":"ref48\/cit48","volume-title":"Gaussian 09, Revision A.01","author":"Frisch M. J.","year":"2009"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1063\/1.478522"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1063\/1.478401"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.2c09098"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(82)80012-2"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1063\/1.1676139"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00917-7"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1063\/1.470645"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1021\/ja00484a075"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/ja9813921"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1021\/ic00278a009"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.0c03529"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-3055(08)60575-4"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1021\/ja504771d"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.5c07780","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.5c07780","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T09:31:31Z","timestamp":1765877491000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acsomega.5c07780"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,3]]},"references-count":61,"journal-issue":{"issue":"49","published-print":{"date-parts":[[2025,12,16]]}},"alternative-id":["10.1021\/acsomega.5c07780"],"URL":"https:\/\/doi.org\/10.1021\/acsomega.5c07780","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2025-rtrzm","asserted-by":"object"}]},"ISSN":["2470-1343","2470-1343"],"issn-type":[{"value":"2470-1343","type":"print"},{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,3]]}}}