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In this work, defect-emissive Mn\u2013Sb\/MnOx quantum nanostructures were synthesized via a green ethanol-assisted colloidal reflux method using oleic acid as a surface-passivating ligand under an inert nitrogen atmosphere. The synthesized nanostructures exhibited an average particle size of \u223c5.3 nm with good colloidal dispersibility and narrow size distribution. Structural characterization by XRD, TEM, SAED, XRF, Raman spectroscopy, and XPS collectively suggests the formation of Mn\u2013Sb-related nanocrystalline domains embedded within MnOx-rich surface environments, indicating a structurally heterogeneous and defect-rich nanoscale system. Optical measurements showed a pronounced absorption feature near 230 nm and effective optical transition energies of 3.9\u20134.1 eV. Because the synthesized material is structurally heterogeneous and contains MnOx-rich surface environments, the estimated optical transition energies should be regarded as effective optical transition energies rather than a true semiconductor band gap. Broad green photoluminescence centered at 518\u2013525 nm was observed, with a maximum photoluminescence quantum yield (PLQY) of 62.3%. The emission is attributed to defect-mediated and interface-assisted radiative recombination associated with Mn\u2013Sb-related nanodomains, MnOx-rich surface species, and ligand-passivated defect states. These findings demonstrate that defect engineering in MnSb-based multiphase quantum dots provides an effective strategy for designing efficient lead-free luminescent nanomaterials.<\/jats:p>","DOI":"10.1021\/acsomega.5c12773","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T11:02:09Z","timestamp":1786446129000},"page":"48950-48958","source":"Crossref","is-referenced-by-count":0,"title":["MnSb-Based Quantum\nDots: Defect-Mediated Photoluminescence\nin Multiphase Nanostructures via Green Colloidal Synthesis"],"prefix":"10.1021","volume":"11","author":[{"given":"Rahma Dika Nasution","family":"Aulia","sequence":"first","affiliation":[{"name":"Universitas Negeri Padang , , ,","place":["Padang, Indonesia, 25131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evelyna Ikhza","family":"Wafiyah","sequence":"additional","affiliation":[{"name":"Universitas Negeri Padang , , ,","place":["Padang, Indonesia, 25131"]},{"name":"National Research and Innovation Agency (BRIN) , , ,","place":["South Tangerang, Indonesia, 15314"]},{"name":"Institut Teknologi Bandung , , ,","place":["Bandung, Indonesia, 40132"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juvani Indah","family":"Putri","sequence":"additional","affiliation":[{"name":"Universitas Negeri Padang , , ,","place":["Padang, Indonesia, 25131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kasmita","family":"Kasmita","sequence":"additional","affiliation":[{"name":"Universitas Negeri Padang , , ,","place":["Padang, Indonesia, 25131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zamahsary","family":"Martha","sequence":"additional","affiliation":[{"name":"Universitas Negeri Padang , , ,","place":["Padang, Indonesia, 25131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3402-433X","authenticated-orcid":true,"given":"Veinardi","family":"Suendo","sequence":"additional","affiliation":[{"name":"Institut Teknologi Bandung , , ,","place":["Bandung, Indonesia, 40132"]},{"name":"Institut Teknologi Bandung , , ,","place":["Bandung, Indonesia, 40132"]},{"name":"Institut Teknologi Bandung , , ,","place":["Bandung, Indonesia, 40132"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1399-7028","authenticated-orcid":true,"given":"Davin","family":"Philo","sequence":"additional","affiliation":[{"name":"National Research and Innovation Agency (BRIN) , , ,","place":["South Tangerang, Indonesia, 15314"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3639-8191","authenticated-orcid":true,"given":"Deski","family":"Beri","sequence":"additional","affiliation":[{"name":"Universitas Negeri Padang , , ,","place":["Padang, Indonesia, 25131"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,11]]},"reference":[{"key":"2026083119115770700_cit1","first-page":"772","article-title":"Interband absorption of light in a semiconductor sphere","volume":"16","author":"Efros","year":"1982","journal-title":"Sov. 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