{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T01:21:21Z","timestamp":1792459281337,"version":"4.5.0"},"reference-count":70,"publisher":"American Chemical Society (ACS)","issue":"9","license":[{"start":{"date-parts":[[2026,2,22]],"date-time":"2026-02-22T00:00:00Z","timestamp":1771718400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["471424360"],"award-info":[{"award-number":["471424360"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,3,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A series of monometallic Al\u00ad(III), Sm\u00ad(III), Dy\u00ad(III), Er\u00ad(III), and Yb\u00ad(III) complexes, featuring tetraphenyldiphosphine monoxide (PPO) as a ligand, were synthesized and characterized. These complexes served as precursors for the construction of heterobimetallic rare earth (RE)\/transition metal (TM) assemblies. Attempts to introduce soft TMs, such as Cu\u00ad(I) and Au\u00ad(I), into the preformed RE\u2013PPO synthons predominantly afforded equilibrium-driven TM-based POP species, underscoring the challenges of incorporating hard and soft metal centers directly. This observation led to an alternative route employing a presynthesized Mo\u2013PPO synthon, which led to the successful formation of RE\/Mo heterobimetallic complexes upon addition of the RE ions. The molecular structures of both mono- and heterobimetallic species were strongly influenced by the solvent environment. Notably, reactions in dichloromethane, a noncoordinating solvent, yielded RE2 complexes featuring chloride bridges, a motif absent when coordinating solvents, such as THF or MeCN were employed. This solvent-dependent structural divergence offers a straightforward strategy for modulating the metal nuclearity within the complexes.<\/jats:p>","DOI":"10.1021\/acsomega.5c13312","type":"journal-article","created":{"date-parts":[[2026,2,22]],"date-time":"2026-02-22T14:52:11Z","timestamp":1771771931000},"page":"15462-15475","source":"Crossref","is-referenced-by-count":4,"title":["Coordination Chemistry\nat the Hard\u2013Soft Interface:\nPhosphine Oxide-Based Rare Earth\/Transition Metal Complexes"],"prefix":"10.1021","volume":"11","author":[{"given":"Rwitabrita","family":"Panda","sequence":"first","affiliation":[{"name":"Karlsruhe Institute of Technology , , Engesserstr. 15 , ,","place":["Karlsruhe, Germany, 76131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franziska","family":"Flecken","sequence":"additional","affiliation":[{"name":"Karlsruhe Institute of Technology , , Engesserstr. 15 , ,","place":["Karlsruhe, Germany, 76131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christina","family":"Papke","sequence":"additional","affiliation":[{"name":"Karlsruhe Institute of Technology , , Engesserstr. 15 , ,","place":["Karlsruhe, Germany, 76131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7992-7797","authenticated-orcid":true,"given":"Christopher E.","family":"Anson","sequence":"additional","affiliation":[{"name":"Karlsruhe Institute of Technology , , Engesserstr. 15 , ,","place":["Karlsruhe, Germany, 76131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9162-6487","authenticated-orcid":true,"given":"Toni","family":"Grell","sequence":"additional","affiliation":[{"name":"Universita\u0300 Degli Studi diMilano , , Via Camillo Golgi 19 , ,","place":["Milan, Italy, 20131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2624-7872","authenticated-orcid":true,"given":"Schirin","family":"Hanf","sequence":"additional","affiliation":[{"name":"Karlsruhe Institute of Technology , , Engesserstr. 15 , ,","place":["Karlsruhe, Germany, 76131"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,2,22]]},"reference":[{"issue":"1","key":"2026081508102546700_cit1","doi-asserted-by":"publisher","first-page":"28","DOI":"10.1021\/cr500208k","article-title":"Multimetallic Catalysis Based on\nHeterometallic Complexes and Clusters","volume":"115","author":"Buchwalter","year":"2015","journal-title":"Chem.\nRev."},{"issue":"22","key":"2026081508102546700_cit2","doi-asserted-by":"publisher","first-page":"16947","DOI":"10.1021\/acscatal.4c03724","article-title":"On-Demand Metal-to-Metal Electron Donation during Zr\u2013Ru\nHeterodinuclear-Catalyzed Amine\u2013Borane Dehydrogenation","volume":"14","author":"Kumawat","year":"2024","journal-title":"ACS Catal."},{"issue":"12","key":"2026081508102546700_cit3","doi-asserted-by":"publisher","first-page":"1859","DOI":"10.1021\/acs.organomet.1c00136","article-title":"Time-Resolved Ultraviolet-Infrared\nExperiments Suggest Fe-Cu Dinuclear Arene Borylation Catalyst Can\nBe Photoactivated","volume":"40","author":"Davis","year":"2021","journal-title":"Organometallics"},{"issue":"1","key":"2026081508102546700_cit4","doi-asserted-by":"publisher","first-page":"605","DOI":"10.1021\/acs.joc.3c02359","article-title":"Mechanism\nand Stereoselectivity Control of Terminal Alkyne Dimerization Activated\nby a Zr\/Co Heterobimetallic Complex: A DFT Study","volume":"89","author":"Sun","year":"2024","journal-title":"J. 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