{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T15:58:07Z","timestamp":1791302287720,"version":"4.1.0"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T00:00:00Z","timestamp":1789776000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100009232","name":"Debreceni Egyetem","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009232","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011019","name":"Nemzeti Kutat?si Fejleszt?si ?s Innov?ci?s Hivatal","doi-asserted-by":"publisher","award":["2025-1.2.1-HU-RIZONT-2025-00006"],"award-info":[{"award-number":["2025-1.2.1-HU-RIZONT-2025-00006"]}],"id":[{"id":"10.13039\/501100011019","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011019","name":"Nemzeti Kutat?si Fejleszt?si ?s Innov?ci?s Hivatal","doi-asserted-by":"publisher","award":["K-14750"],"award-info":[{"award-number":["K-14750"]}],"id":[{"id":"10.13039\/501100011019","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A novel series of multiblock copolymers composed of alternating poly(N-acryloylmorpholine) (PNAM) and poly(N-isopropylacrylamide) (PNIPAM) segments were synthesized using reversible addition\u2013fragmentation chain-transfer (RAFT) polymerization to explore the relationship between molecular architecture and thermoresponsive behavior. The synthesis was conducted stepwise, enabling precise control over block length and composition. Comprehensive characterization was performed using matrix-assisted laser desorption\/ionization time-of-flight mass spectrometry (MALDI-TOF MS) with our previously reported data processing methodology, supported by 1H NMR and size-exclusion chromatography (SEC). This detailed structural analysis enabled rigorous evaluation of the sequential RAFT synthesis and provided the molecular-level information required to establish quantitative structure\u2013property relationships in the multiblock copolymers. The designed and experimentally determined degrees of polymerization showed excellent correlation (r = 0.983), confirming high synthetic precision. Turbidimetry measurements revealed tunable lower critical solution temperature (LCST)-type phase transitions, where alternating PNIPAM and PNAM blocks produced systematic, reversible shifts in aggregation temperature. This iterative approach enables the predictive design of block copolymers with tailored thermoresponsive properties, offering significant potential for applications in drug delivery, tissue engineering, and smart materials.<\/jats:p>","DOI":"10.1021\/acsomega.6c02801","type":"journal-article","created":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T14:01:28Z","timestamp":1789826488000},"page":"58742-58751","source":"Crossref","is-referenced-by-count":0,"title":["MALDI-TOF Mass\nSpectrometric Characterization of Polyacrylamide\nMultiblock Copolymers Reveals Structure\u2013Property Relationships"],"prefix":"10.1021","volume":"11","author":[{"given":"Veronika","family":"Pardi-To\u0301th","sequence":"first","affiliation":[{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]},{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A\u0301kos","family":"Kuki","sequence":"additional","affiliation":[{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gergo\u030b","family":"Ro\u0301th","sequence":"additional","affiliation":[{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ma\u0301te\u0301","family":"Benedek","sequence":"additional","affiliation":[{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]},{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8568-914X","authenticated-orcid":true,"given":"Tibor","family":"Nagy","sequence":"additional","affiliation":[{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5274-6117","authenticated-orcid":true,"given":"Sa\u0301ndor","family":"Ke\u0301ki","sequence":"additional","affiliation":[{"name":"University of Debrecen , , Egyetem te\u0301r 1 , ,","place":["Debrecen, Hungary, H-4032"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,19]]},"reference":[{"issue":"3","key":"2026100610475282200_cit1","doi-asserted-by":"publisher","first-page":"1674","DOI":"10.1039\/C5SC03505H","article-title":"Block copolymers: controlling nanostructure\nto generate functional materials \u2013 synthesis, characterization,\nand engineering","volume":"7","author":"Epps Iii","year":"2016","journal-title":"Chem. Sci."},{"issue":"11","key":"2026100610475282200_cit2","doi-asserted-by":"publisher","first-page":"744","DOI":"10.1038\/nmat997","article-title":"Self-assembly of functional nanostructures from ABC\ntriblock copolymers","volume":"2","author":"Ludwigs","year":"2003","journal-title":"Nat. Mater."},{"key":"2026100610475282200_cit3","doi-asserted-by":"publisher","first-page":"122914","DOI":"10.1016\/j.polymer.2020.122914","article-title":"Emerging trends in\nsolution self-assembly of block copolymers","volume":"207","author":"Deng","year":"2020","journal-title":"Polymer"},{"issue":"13","key":"2026100610475282200_cit4","doi-asserted-by":"publisher","first-page":"5849","DOI":"10.1021\/acs.macromol.2c00878","article-title":"Aggregation Behavior of Nonsymmetrically\nEnd-Capped\nThermoresponsive Block Copolymers in Aqueous Solutions: Between Polymer\nCoils and Micellar States","volume":"55","author":"Prause","year":"2022","journal-title":"Macromolecules"},{"issue":"17","key":"2026100610475282200_cit5","doi-asserted-by":"publisher","first-page":"1874","DOI":"10.1002\/pol.20210430","article-title":"Block copolymer solution self-assembly: Recent advances,\nemerging trends, and applications","volume":"59","author":"Karayianni","year":"2021","journal-title":"J. Polym.\nSci."},{"issue":"9","key":"2026100610475282200_cit6","doi-asserted-by":"publisher","first-page":"4925","DOI":"10.1002\/anie.202010501","article-title":"Effect of Hydrophilic Monomer Distribution on Self-Assembly\nof a pH-Responsive Copolymer: Spheres, Worms and Vesicles from a Single\nCopolymer Composition","volume":"60","author":"Zhang","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"issue":"8","key":"2026100610475282200_cit7","doi-asserted-by":"publisher","first-page":"503","DOI":"10.1080\/10601325.2024.2345918","article-title":"RAFT mediated dispersion copolymerization\nof glycidyl methacrylate and octadecyl methacrylate","volume":"61","author":"Goswami","year":"2024","journal-title":"J. Macromol. Sci., Part A"},{"issue":"1","key":"2026100610475282200_cit8","doi-asserted-by":"publisher","first-page":"753","DOI":"10.1007\/s10973-012-2344-0","article-title":"Thermal degradation\nkinetics of thermoresponsive\npoly(N-isopropylacrylamide-co-N,N-dimethylacrylamide) copolymers prepared\nvia RAFT polymerization","volume":"111","author":"Bauri","year":"2013","journal-title":"J. Therm. Anal. Calorim."},{"key":"2026100610475282200_cit9","doi-asserted-by":"crossref","first-page":"229","DOI":"10.1016\/B978-0-08-101750-0.00008-8","article-title":"8 - Polyacrylamide\nand related polymers","volume-title":"Engineering Of Biomaterials\nFor Drug Delivery Systems","author":"Kavitha","year":"2018"},{"issue":"1","key":"2026100610475282200_cit10","doi-asserted-by":"publisher","first-page":"42","DOI":"10.3390\/molecules27010042","article-title":"Spotlight on the Life Cycle of Acrylamide-Based Polymers\nSupporting Reductions in Environmental Footprint: Review and Recent\nAdvances","volume":"27","author":"Braun","year":"2022","journal-title":"Molecules"},{"issue":"1","key":"2026100610475282200_cit11","doi-asserted-by":"publisher","first-page":"1444990","DOI":"10.1155\/2024\/1444990","article-title":"Macromolecular\nPoly(N-isopropylacrylamide) (PNIPAM)\nin Cancer Treatment and Beyond","volume":"2024","author":"Throat","year":"2024","journal-title":"Adv. Polym.\nTechnol."},{"issue":"6","key":"2026100610475282200_cit12","doi-asserted-by":"publisher","first-page":"872","DOI":"10.1021\/acsmacrolett.0c00342","article-title":"100th Anniversary\nof Macromolecular\nScience Viewpoint: Poly(N-isopropylacrylamide)-Based Thermally Responsive\nMicelles","volume":"9","author":"Luo","year":"2020","journal-title":"ACS Macro Lett."},{"issue":"51","key":"2026100610475282200_cit13","doi-asserted-by":"publisher","first-page":"15342","DOI":"10.1002\/anie.201506663","article-title":"Poly (N-isopropylacrylamide) Phase\nDiagrams: Fifty Years of Research","volume":"54","author":"Halperin","year":"2015","journal-title":"Angew. Chem.,\nInt. Ed."},{"issue":"13","key":"2026100610475282200_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202404266","article-title":"Tailored Nucleation-Growth\nStrategy for Precise Self-Assembly of\nBlock Copolymers","volume":"31","author":"Hu","year":"2025","journal-title":"Chem. Eur. J."},{"issue":"4","key":"2026100610475282200_cit15","doi-asserted-by":"publisher","first-page":"487","DOI":"10.1007\/s00289-008-0029-4","article-title":"Thermal response\nof low molecular weight poly-(N-isopropylacrylamide) polymers in aqueous\nsolution","volume":"62","author":"Pamies","year":"2009","journal-title":"Polym. Bull."},{"issue":"4","key":"2026100610475282200_cit16","doi-asserted-by":"publisher","first-page":"1492","DOI":"10.1002\/pola.21256","article-title":"Effects\nof end group polarity and molecular weight on the lower critical solution\ntemperature of poly(N-isopropylacrylamide)","volume":"44","author":"Furyk","year":"2006","journal-title":"J. Polym. Sci., Part A: Polym. Chem."},{"issue":"10","key":"2026100610475282200_cit17","doi-asserted-by":"publisher","first-page":"1699","DOI":"10.1007\/s00396-018-4391-y","article-title":"Effect\nof N-isopropylacrylamide thermoresponsive blocks on the rheological\nproperties of water-soluble thermoassociative copolymers synthesized\nvia RAFT polymerization","volume":"296","author":"Di\u0301az-Silvestre","year":"2018","journal-title":"Colloid Polym. Sci."},{"issue":"46","key":"2026100610475282200_cit18","doi-asserted-by":"publisher","first-page":"6247","DOI":"10.1039\/C9PY01311C","article-title":"Preparation of hydrophobically\nmodified associating multiblock copolymers via a one-pot aqueous RAFT\npolymerization","volume":"10","author":"St Thomas","year":"2019","journal-title":"Polym. Chem."},{"issue":"13","key":"2026100610475282200_cit19","doi-asserted-by":"publisher","first-page":"5019","DOI":"10.1039\/D4SC00399C","article-title":"Enhanced synthesis\nof multiblock\ncopolymers via acid-triggered RAFT polymerization","volume":"15","author":"Antonopoulou","year":"2024","journal-title":"Chem. Sci."},{"issue":"6080","key":"2026100610475282200_cit20","doi-asserted-by":"publisher","first-page":"434","DOI":"10.1126\/science.1215368","article-title":"Multiblock\nPolymers: Panacea or Pandora\u2019s Box?","volume":"336","author":"Bates","year":"2012","journal-title":"Science"},{"issue":"3","key":"2026100610475282200_cit21","doi-asserted-by":"publisher","first-page":"223","DOI":"10.1039\/D2PY01097F","article-title":"Thermoresponsive\nblock copolymers of increasing architecture complexity: a review on\nstructure\u2013property relationships","volume":"14","author":"Constantinou","year":"2023","journal-title":"Polym.\nChem."},{"issue":"24","key":"2026100610475282200_cit22","doi-asserted-by":"publisher","first-page":"10136","DOI":"10.1021\/acs.macromol.8b01933","article-title":"Self-Assembly of Thermosensitive\nAmphiphilic Pentablock Terpolymer PNIPAMx-b-PtBA90-b-PPO36-b-PtBA90-b-PNIPAMx\nin Dilute Aqueous Solution","volume":"51","author":"Lv","year":"2018","journal-title":"Macromolecules"},{"issue":"13","key":"2026100610475282200_cit23","doi-asserted-by":"publisher","first-page":"6489","DOI":"10.1021\/acs.macromol.1c00627","article-title":"Self-assembly\nof the Thermosensitive and pH-Sensitive Pentablock Copolymer PNIPAMx-b-P(tBA-co-AA)90-b-PPO36-b-P(tBA-co-AA)90-b-PNIPAMx\nin Dilute Aqueous Solutions","volume":"54","author":"Lv","year":"2021","journal-title":"Macromolecules"},{"issue":"9","key":"2026100610475282200_cit24","doi-asserted-by":"publisher","first-page":"2932","DOI":"10.1002\/pen.26074","article-title":"Thickening\nbehavior of thermo-associative water soluble multiblock copolymers\nunder redox RAFT polymerization","volume":"62","author":"Maldonado-Textle","year":"2022","journal-title":"Polym. Eng.\nSci."},{"issue":"6","key":"2026100610475282200_cit25","doi-asserted-by":"publisher","first-page":"2713","DOI":"10.1021\/ma902709p","article-title":"Alternating\nAmphiphilic Multiblock Copolymers: Controlled Synthesis via RAFT Polymerization\nand Aqueous Solution Characterization","volume":"43","author":"Hadjiantoniou","year":"2010","journal-title":"Macromolecules"},{"issue":"51","key":"2026100610475282200_cit26","doi-asserted-by":"publisher","first-page":"14649","DOI":"10.1021\/acs.langmuir.7b02810","article-title":"Association\nBehavior of Poly(ethylene oxide)\u2013Poly(propylene\noxide) Alternating Multiblock Copolymers in Water toward Thermally\nInduced Phase Separation","volume":"33","author":"Horiuchi","year":"2017","journal-title":"Langmuir"},{"key":"2026100610475282200_cit27","doi-asserted-by":"publisher","first-page":"521","DOI":"10.1016\/j.jcis.2023.03.013","article-title":"Phase behavior\nof medium-length hydrophobically associating PEO-PPO multiblock copolymers\nin aqueous media","volume":"641","author":"Huysecom","year":"2023","journal-title":"J. Colloid Interface Sci."},{"issue":"11","key":"2026100610475282200_cit28","doi-asserted-by":"publisher","first-page":"4250","DOI":"10.1021\/acs.biomac.8b01020","article-title":"Impact of Polymer Bioconjugation on Protein Stability\nand Activity Investigated with Discrete Conjugates: Alternatives to\nPEGylation","volume":"19","author":"Morgenstern","year":"2018","journal-title":"Biomacromolecules"},{"issue":"16","key":"2026100610475282200_cit29","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302093","article-title":"RAFT-Mediated Emulsion Polymerization-Induced Self-Assembly\nfor the Synthesis of Core-Degradable Waterborne Particles","volume":"62","author":"Galanopoulo","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026100610475282200_cit30","doi-asserted-by":"publisher","first-page":"218","DOI":"10.1016\/j.polymer.2016.08.072","article-title":"From well-defined poly(N-acryloylmorpholine)-stabilized\nnanospheres to uniform mannuronan- and guluronan-decorated nanoparticles\nby RAFT polymerization-induced self-assembly","volume":"106","author":"Chaduc","year":"2016","journal-title":"Polymer"},{"issue":"40","key":"2026100610475282200_cit31","doi-asserted-by":"publisher","first-page":"14413","DOI":"10.1021\/ja905123t","article-title":"Micelles for Delivery of Nitric Oxide","volume":"131","author":"Jo","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2026100610475282200_cit32","doi-asserted-by":"publisher","first-page":"100248","DOI":"10.1016\/j.giant.2024.100248","article-title":"The triumvirate\nof effective and rapid synthesis, analysis, and artificial intelligence\nto explore the structure-property relationship of copolymers","volume":"17","author":"Nagy","year":"2024","journal-title":"Giant"},{"issue":"3","key":"2026100610475282200_cit33","doi-asserted-by":"publisher","first-page":"1906","DOI":"10.1021\/jacs.2c11757","article-title":"Oxygen-Enhanced\nAtom Transfer Radical Polymerization through the Formation of a Copper\nSuperoxido Complex","volume":"145","author":"Parkatzidis","year":"2023","journal-title":"J. Am. Chem. Soc."},{"issue":"23","key":"2026100610475282200_cit34","doi-asserted-by":"publisher","first-page":"1706441","DOI":"10.1002\/adma.201706441","article-title":"Advanced Materials\nby Atom Transfer Radical Polymerization","volume":"30","author":"Matyjaszewski","year":"2018","journal-title":"Adv.\nMater."},{"issue":"13","key":"2026100610475282200_cit35","doi-asserted-by":"publisher","first-page":"1479","DOI":"10.1039\/C7PY02001E","article-title":"Nitroxide radical\npolymers \u2013 a versatile material\nclass for high-tech applications","volume":"9","author":"Hansen","year":"2018","journal-title":"Polym. Chem."},{"issue":"5","key":"2026100610475282200_cit36","doi-asserted-by":"publisher","first-page":"2682","DOI":"10.1021\/acs.analchem.6b05136","article-title":"Extension of the Kendrick\nMass Defect Analysis of Homopolymers to\nLow Resolution and High Mass Range Mass Spectra Using Fractional Base\nUnits","volume":"89","author":"Fouquet","year":"2017","journal-title":"Anal. Chem."},{"issue":"10","key":"2026100610475282200_cit37","doi-asserted-by":"publisher","first-page":"6479","DOI":"10.1021\/acs.analchem.8b04976","article-title":"Mass-Remainder\nAnalysis (MARA): An Improved Method for Elemental Composition Assignment\nin Petroleomics","volume":"91","author":"Nagy","year":"2019","journal-title":"Anal. Chem."},{"issue":"4","key":"2026100610475282200_cit38","doi-asserted-by":"publisher","first-page":"1199","DOI":"10.1021\/acs.macromol.9b02409","article-title":"Multistep\nMass-Remainder Analysis and its Application in Copolymer Blends","volume":"53","author":"Nagy","year":"2020","journal-title":"Macromolecules"},{"issue":"21","key":"2026100610475282200_cit39","doi-asserted-by":"publisher","first-page":"9984","DOI":"10.1021\/acs.macromol.1c01552","article-title":"Polydispersity\nRatio and Its Application for the Characterization of Poloxamers","volume":"54","author":"Ro\u0301th","year":"2021","journal-title":"Macromolecules"},{"issue":"1","key":"2026100610475282200_cit40","doi-asserted-by":"publisher","first-page":"42","DOI":"10.3390\/pr10010042","article-title":"A Short-Cut Data Mining Method for the Mass Spectrometric Characterization\nof Block Copolymers","volume":"10","author":"Kuki","year":"2022","journal-title":"Processes"},{"issue":"2","key":"2026100610475282200_cit41","doi-asserted-by":"publisher","first-page":"293","DOI":"10.1021\/jasms.2c00311","article-title":"MALINTO: A\nNew MALDI Interpretation\nTool for Enhanced Peak Assignment and Semiquantitative Studies of\nComplex Synthetic Polymers","volume":"34","author":"Saller","year":"2023","journal-title":"J. Am. Soc. Mass\nSpectrom."},{"issue":"22","key":"2026100610475282200_cit42","doi-asserted-by":"publisher","first-page":"2404","DOI":"10.1002\/macp.201200169","article-title":"Copolymer Composition Determined\nby LC-MALDI-TOF MS Coupling and \u201cMassChrom2D\u201d Data Analysis","volume":"213","author":"Weidner","year":"2012","journal-title":"Macromol. Chem. Phys."},{"issue":"1","key":"2026100610475282200_cit43","doi-asserted-by":"publisher","first-page":"1055","DOI":"10.1038\/s41597-025-05379-w","article-title":"Enabling data-driven design of block\ncopolymer self-assembly","volume":"12","author":"Magosso","year":"2025","journal-title":"Sci. Data"},{"issue":"28","key":"2026100610475282200_cit44","doi-asserted-by":"publisher","first-page":"10504","DOI":"10.1021\/acs.analchem.2c02913","article-title":"Enhanced Copolymer\nCharacterization\nfor Polyethers Using Gel Permeation Chromatography Combined with Artificial\nNeural Networks","volume":"95","author":"Nagy","year":"2023","journal-title":"Anal. Chem."},{"issue":"36","key":"2026100610475282200_cit45","doi-asserted-by":"publisher","first-page":"19801","DOI":"10.1021\/acs.analchem.5c03495","article-title":"Rapid Copolymer\nAnalysis of Unresolved Mass Spectra by Artificial Intelligence","volume":"97","author":"Ro\u0301th","year":"2025","journal-title":"Anal. Chem."},{"issue":"10","key":"2026100610475282200_cit46","doi-asserted-by":"publisher","first-page":"5223","DOI":"10.1021\/acs.analchem.5b00146","article-title":"COCONUT\u2500An\nEfficient Tool\nfor Estimating Copolymer Compositions from Mass Spectra","volume":"87","author":"Engler","year":"2015","journal-title":"Anal. Chem."},{"issue":"S2","key":"2026100610475282200_cit47","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.8654","article-title":"Automatic\npeak assignment and visualisation of copolymer\nmass spectrometry data using the \u2018genetic algorithm\u2019","volume":"34","author":"Town","year":"2020","journal-title":"Rapid Commun. Mass Spectrom."},{"key":"2026100610475282200_cit48","doi-asserted-by":"publisher","first-page":"63","DOI":"10.1016\/j.jtice.2018.07.045","article-title":"LCST phase\ntransition kinetics of aqueous poly(N-isopropylacrylamide) solution","volume":"93","author":"Pham","year":"2018","journal-title":"J. Taiwan Inst. Chem. Eng."},{"issue":"4","key":"2026100610475282200_cit49","doi-asserted-by":"publisher","first-page":"1600470","DOI":"10.1002\/macp.201600470","article-title":"The Dependence of the Cloud Point,\nClearing Point,\nand Hysteresis of Poly(N-isopropylacrylamide) on Experimental Conditions:\nThe Need for Standardization of Thermoresponsive Transition Determinations","volume":"218","author":"Osva\u0301th","year":"2017","journal-title":"Macromol. Chem. Phys."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c02801","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/39\/58742\/68563295\/acsomega.6c02801.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/39\/58742\/68563295\/acsomega.6c02801.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T15:25:59Z","timestamp":1791300359000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/39\/58742\/5433237\/MALDI-TOF-Mass-Spectrometric-Characterization-of"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,19]]},"references-count":49,"journal-issue":{"issue":"39","published-online":{"date-parts":[[2026,9,19]]},"published-print":{"date-parts":[[2026,10,6]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c02801","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,19]]}}}