{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T12:12:58Z","timestamp":1788437578256,"version":"build-2803163510"},"reference-count":93,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T00:00:00Z","timestamp":1787184000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004794","name":"Centre National de la Recherche Scientifique","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100004794","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Computational studies suggest that the maximum density of water at 277 K and the divergence from experimentally measured compressibility at 228 K at 1 bar arise from the competition between low and high-density molecular populations. However, the relationships among these anomalies, including the minimum density at 203 K, are still debated. Using molecular dynamics with the TIP4P\/2005 model, we investigate the pressure\u2013temperature behavior of metastable water along isothermal and isobaric lines to show that in both cases the density and compressibility anomalies result from the emergence, coexistence and extinction of low and high-density percolating clusters. We connect these behaviors with distinct stages of metastable water phase separation, which occur in regions of steep increase in sample density. Our results are consistent with liquid\u2013liquid critical point scenarios while establishing a phenomenological percolation-based framework that systematically organizes water anomalies across diverse temperatures and pressures. This framework may explain percolation transitions observed in oxide and metallic glasses, providing a perspective to describe amorphous transformations in pure substances.<\/jats:p>","DOI":"10.1021\/acsomega.6c03046","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T16:02:04Z","timestamp":1787241724000},"page":"51042-51054","source":"Crossref","is-referenced-by-count":0,"title":["Unravelling Water\nAnomalies Using a Percolation Approach"],"prefix":"10.1021","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8194-6532","authenticated-orcid":true,"given":"Anwar","family":"Hasmy","sequence":"first","affiliation":[{"name":"Universite\u0301 de Montpellier, CNRS , , ,","place":["Montpellier, France, 34095"]},{"name":"Universidad Simo\u0301n Boli\u0301var , , Valle de Sartenejas , ,","place":["Caracas, Venezuela, 1080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bernard","family":"Hehlen","sequence":"additional","affiliation":[{"name":"Universite\u0301 de Montpellier, CNRS , , ,","place":["Montpellier, France, 34095"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6008-7249","authenticated-orcid":true,"given":"Ricardo","family":"Paredes","sequence":"additional","affiliation":[{"name":"Instituto Venezolano de Investigaciones Cienti\u0301ficas , , Apdo. 21827 ,","place":["Caracas, Venezuela, 1020A"]},{"name":"Universidad Iberoamericana , , ,","place":["Ciudad de Me\u0301xico, Mexico, 01219"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,20]]},"reference":[{"key":"2026090307163102200_cit1","doi-asserted-by":"publisher","first-page":"8368","DOI":"10.1073\/pnas.1602375113","article-title":"How van der Waals interactions\ndetermine the unique properties of water","volume":"113","author":"Morawietz","year":"2016","journal-title":"Proc.\nNatl. 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U.S.A."},{"key":"2026090307163102200_cit5","doi-asserted-by":"publisher","first-page":"8998","DOI":"10.1038\/ncomms9998","article-title":"The structural origin of anomalous\nproperties of liquid\nwater","volume":"6","author":"Nilsson","year":"2015","journal-title":"Nat. Commun."},{"key":"2026090307163102200_cit6","doi-asserted-by":"publisher","first-page":"324","DOI":"10.1038\/360324a0","article-title":"Phase behavior of\nmetastable water","volume":"360","author":"Poole","year":"1992","journal-title":"Nature"},{"key":"2026090307163102200_cit7","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1038\/nature13405","article-title":"Metastable Liquid-Liquid Transition in a Molecular\nModel of Water","volume":"510","author":"Palmer","year":"2014","journal-title":"Nature"},{"key":"2026090307163102200_cit8","doi-asserted-by":"publisher","first-page":"289","DOI":"10.1126\/science.abb9796","article-title":"Second critical point in two realistic\nmodels of water","volume":"369","author":"Debenedetti","year":"2020","journal-title":"Science"},{"key":"2026090307163102200_cit9","doi-asserted-by":"publisher","first-page":"978","DOI":"10.1126\/science.abb9385","article-title":"Experimental observation of the liquid-liquid transition in bulk\nsupercooled water under pressure","volume":"370","author":"Kim","year":"2020","journal-title":"Science"},{"key":"2026090307163102200_cit10","doi-asserted-by":"publisher","first-page":"442","DOI":"10.1038\/s41467-023-36091-1","article-title":"Liquid-liquid\nphase\nseparation in supercooled water from ultrafast heating of low-density\namorphous ice","volume":"14","author":"Amann-Winkel","year":"2023","journal-title":"Nat. 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