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Pesquisa do Estado de S??o Paulo","doi-asserted-by":"publisher","award":["2023\/05718-9"],"award-info":[{"award-number":["2023\/05718-9"]}],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001807","name":"Funda????o de Amparo ?? Pesquisa do Estado de S??o Paulo","doi-asserted-by":"publisher","award":["2025\/08634-6"],"award-info":[{"award-number":["2025\/08634-6"]}],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Accurate temperature sensing at the nanoscale has become a powerful tool to monitor heat dissipation in miniaturized systems, driving the development of noncontact luminescent thermometers with high sensitivity. EuIII\/TbIII-based coordination polymers are particularly attractive for thermometry due to their structural tunability, which allows the correlation of structural and electronic parameters with thermometric performance. Herein, we compare the luminescence thermometry of a series of one-dimensional coordination polymers, [Ln(tfa)3(\u03bc-dppeo)]n, [Ln(tfa)3(\u03bc-dppbo)]n, [Ln(hfa)3(\u03bc-dppeo)]n, and [Ln(hfa)3(\u03bc-dppbo)]n (Ln = EuIII, TbIII; tfa\u2013: trifluoroacetylacetonate; hfa\u2013: hexafluoroacetylacetonate; L: [(diphenylphosphoryl)R](diphenyl)phosphine oxide, R = ethyl - dppeo - or butyl - dppbo), focusing on the combined effects of bridge and terminal ligand scaffold as well as lanthanide (LnIII) molar ratio. For each system, the TbIII\/EuIII ratio was adjusted to {Tb0.25Eu0.75}n or {Tb0.75Eu0.25}n, enabling systematic evaluation of ratiometric thermometry based on the TbIII\u00a05D4 \u2192 7F5 and EuIII\u00a05D0 \u2192 7F2 emissions. Structural variations induced by the terminal and bridge ligands modulate crystal packing, local coordination microsymmetry, and LnIII\u2013LnIII distances. Coordination polymers with higher TbIII content exhibit enhanced thermometric performance, reaching a maximum relative thermal sensitivity of 5.20% K\u20131 at 305 K for [Tb0.75Eu0.25(hfa)3(\u03bc-dppbo)]n. The increase of the TbIII amount potentializes the TbIII-to-EuIII energy transfer and enhances the activation energy of the luminescence thermal quenching. These results demonstrate that controlling the ligand scaffold and LnIII molar ratio enables effective modulation of thermal sensitivity and operating range in EuIII\/TbIII coordination polymers.<\/jats:p>","DOI":"10.1021\/acsomega.6c03259","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T20:32:27Z","timestamp":1783715547000},"page":"43849-43862","source":"Crossref","is-referenced-by-count":0,"title":["Modulating Luminescence\nThermometry of the EuIII\/TbIII Pair in Coordination\nPolymers through\nLigand Structure and Lanthanide(III) Molar Ratio"],"prefix":"10.1021","volume":"11","author":[{"given":"Gabriel J. S.","family":"Araujo","sequence":"first","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Talita C.","family":"Souza","sequence":"additional","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefano A.","family":"de Andrade","sequence":"additional","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Je\u0301ssica F.","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergio F. N.","family":"Coelho","sequence":"additional","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7841-8480","authenticated-orcid":true,"given":"Pedro H. O.","family":"Santiago","sequence":"additional","affiliation":[{"name":"University of Sa\u0303o Paulo , , , ,","place":["Sa\u0303o Carlos, Sa\u0303o Paulo, Brazil, 13566-590"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0676-3098","authenticated-orcid":true,"given":"Javier","family":"Ellena","sequence":"additional","affiliation":[{"name":"University of Sa\u0303o Paulo , , , ,","place":["Sa\u0303o Carlos, Sa\u0303o Paulo, Brazil, 13566-590"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Italo O.","family":"Mazali","sequence":"additional","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1963-9854","authenticated-orcid":true,"given":"Leonardo F.","family":"Saraiva","sequence":"additional","affiliation":[{"name":"Sa\u0303o Paulo State University (UNESP), School of Science and Technology , , , ,","place":["Sa\u0303o Paulo, Sa\u0303o Paulo, Brazil, 19060-900"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1501-8815","authenticated-orcid":true,"given":"Airton G.","family":"Bispo-Jr","sequence":"additional","affiliation":[{"name":"University of Sa\u0303o Paulo , , , ,","place":["Sa\u0303o Paulo, Sa\u0303o Paulo, Brazil, 05508-000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1285-6765","authenticated-orcid":true,"given":"Fernando A.","family":"Sigoli","sequence":"additional","affiliation":[{"name":"State University of Campinas , , , ,","place":["Campinas, Sa\u0303o Paulo, Brazil, 13083-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,10]]},"reference":[{"key":"2026072810110429800_cit1","doi-asserted-by":"publisher","first-page":"4746","DOI":"10.1021\/acs.nanolett.7b01433","article-title":"Tethering Luminescent\nThermometry and Plasmonics: Light Manipulation to Assess Real-Time\nThermal Flow in Nanoarchitectures","volume":"17","author":"Brites","year":"2017","journal-title":"Nano Lett."},{"key":"2026072810110429800_cit2","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2022.941861","article-title":"Luminescence\nThermometry for Brain\nActivity Monitoring: A Perspective","volume":"10","author":"Rodr\u0131guez-Sevilla","year":"2022","journal-title":"Front. 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Chem. Chem. Phys."},{"key":"2026072810110429800_cit13","doi-asserted-by":"publisher","first-page":"15559","DOI":"10.1021\/ja407219k","article-title":"A highly sensitive mixed lanthanide\nmetal-organic framework self-calibrated luminescent thermometer","volume":"135","author":"Rao","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026072810110429800_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/adts.202000176","article-title":"Framework for Ratiometric Single\nIon Luminescent Thermometers\u2500Thermodynamic and Kinetic Guidelines\nfor Optimized Performance","volume":"3","author":"Suta","year":"2020","journal-title":"Adv. Theory Simul."},{"key":"2026072810110429800_cit15","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2022.100485","article-title":"Luminescent lanthanide coordination\npolymers with transformative\nenergy transfer processes for physical and chemical sensing applications","volume":"51","author":"Hasegawa","year":"2022","journal-title":"J. Photochem. Photobiol. C, Photochem. Rev."},{"key":"2026072810110429800_cit16","doi-asserted-by":"publisher","first-page":"3799","DOI":"10.1021\/acs.inorgchem.2c04053","article-title":"Controllable Synthesis of TbIII Metal\u2013Organic\nFrameworks with Reversible Luminescence Sensing for Benzaldehyde Vapor","volume":"62","author":"Wang","year":"2023","journal-title":"Inorg. Chem."},{"key":"2026072810110429800_cit17","doi-asserted-by":"publisher","first-page":"4992","DOI":"10.1021\/acs.analchem.2c05224","article-title":"Highly\npH-Responsive\nSensor Based on a EuIII Metal\u2013Organic Framework\nwith Efficient Recognition of Arginine and Lysine in Living Cells","volume":"95","author":"Wang","year":"2023","journal-title":"Anal. Chem."},{"key":"2026072810110429800_cit18","doi-asserted-by":"publisher","first-page":"4140","DOI":"10.1021\/acs.inorgchem.5c05760","article-title":"A Stable EuIII Metal\u2013Organic\nFramework Sensor for the Fluorescence Detection of Tryptophan and\nCancer Biomarker in Living Cells","volume":"65","author":"Huang","year":"2026","journal-title":"Inorg. Chem."},{"key":"2026072810110429800_cit19","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29163914","article-title":"Tailoring Energy Transfer in Mixed\nEu\/Tb Metal\u2013Organic Frameworks\nfor Ratiometric Temperature Sensing","volume":"29","author":"Tang","year":"2024","journal-title":"Molecules"},{"key":"2026072810110429800_cit20","doi-asserted-by":"publisher","DOI":"10.1016\/j.sna.2024.115969","article-title":"Precision across\ntemperatures: Eu\/Tb luminescent thermometer with exceptionally high\nand stable sensitivity from 180 to 320\u202fK","volume":"379","author":"Ivanova","year":"2024","journal-title":"Sens. Actuators, A"},{"key":"2026072810110429800_cit21","doi-asserted-by":"publisher","first-page":"1048","DOI":"10.1039\/b406082m","article-title":"Taking advantage of luminescent lanthanide\nions","volume":"34","author":"Bu\u0308nzli","year":"2005","journal-title":"Chem. Soc. Rev."},{"key":"2026072810110429800_cit22","doi-asserted-by":"publisher","first-page":"4770","DOI":"10.1016\/j.jnoncrysol.2008.04.023","article-title":"Mechanisms\nof non-radiative energy transfer involving lanthanide ions revisited","volume":"354","author":"Malta","year":"2008","journal-title":"Non. Cryst. Solids"},{"key":"2026072810110429800_cit23","doi-asserted-by":"publisher","DOI":"10.3390\/photonics10101171","article-title":"Bimetallic Eu\/Tb\nComplexes for Ratiometric Temperature\nSensing with Unusual Enhancement of Eu Luminescence with","volume":"10","author":"Kharcheva","year":"2023","journal-title":"Temperature. Photonics"},{"key":"2026072810110429800_cit24","doi-asserted-by":"publisher","first-page":"1833","DOI":"10.1021\/acs.inorgchem.4c04488","article-title":"Multi-Emitting\nRatiometric Temperature\nSensing and Tunable White Light Emitting Based on Effective Energy\nTransfer in a Lanthanide-Br\u00f8nsted Acidic Ionic Liquid Coordination\nPolymer","volume":"64","author":"Yang","year":"2025","journal-title":"Inorg. Chem."},{"key":"2026072810110429800_cit25","doi-asserted-by":"publisher","first-page":"405","DOI":"10.1016\/j.dyepig.2018.10.055","article-title":"Eu(III)- and Tb(III)-coordination\npolymer luminescent thermometers constructed from a \u03c0-rich aromatic\nligand exhibiting a high sensitivity","volume":"162","author":"Peng","year":"2019","journal-title":"Dyes Pigm."},{"key":"2026072810110429800_cit26","doi-asserted-by":"publisher","first-page":"719","DOI":"10.1039\/C3CC47225F","article-title":"A ratiometric and colorimetric\nluminescent thermometer over a wide\ntemperature range based on a lanthanide coordination polymer","volume":"50","author":"Cui","year":"2014","journal-title":"Chem. Commun."},{"key":"2026072810110429800_cit27","doi-asserted-by":"publisher","DOI":"10.3390\/ma14216445","article-title":"1D-Zigzag\nEu3+\/Tb3+ Coordination Chains as Luminescent\nRatiometric Thermometers Endowed with Multicolor Emission","volume":"14","author":"Bellucci","year":"2021","journal-title":"Materials"},{"key":"2026072810110429800_cit28","doi-asserted-by":"publisher","first-page":"423","DOI":"10.1039\/C6SC03006H","article-title":"Organic linkers control\nthe thermosensitivity\nof the emission intensities from Tb(III) and Eu(III) in a chameleon\npolymer","volume":"8","author":"Hatanaka","year":"2017","journal-title":"Chem. Sci."},{"key":"2026072810110429800_cit29","doi-asserted-by":"publisher","first-page":"12059","DOI":"10.1002\/anie.201606371","article-title":"Luminescent Europium(III) Coordination Zippers Linked\nwith Thiophene-Based Bridges","volume":"55","author":"Hirai","year":"2016","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026072810110429800_cit30","doi-asserted-by":"publisher","first-page":"6413","DOI":"10.1002\/anie.201301448","article-title":"hameleon Luminophore\nfor Sensing Temperatures: Control of Metal-to-Metal and Energy Back\nTransfer in Lanthanide Coordination Polymers","volume":"52","author":"Miyata","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810110429800_cit31","doi-asserted-by":"publisher","first-page":"264","DOI":"10.1002\/chem.202002628","article-title":"Long-Range\nLMCT Coupling in EuIII Coordination Polymers for an Effective\nMolecular Luminescent Thermometer","volume":"27","author":"Kitagawa","year":"2021","journal-title":"Chem. - Eur.\nJ."},{"key":"2026072810110429800_cit32","doi-asserted-by":"publisher","first-page":"6808","DOI":"10.1021\/acs.inorgchem.3c00555","article-title":"Tuning the thermometric features in 1D luminescent\nEuIII and TbIII coordination polymers through\ndifferent bridge phosphine oxide ligands","volume":"62","author":"A Lima","year":"2023","journal-title":"Inorg.\nChem."},{"key":"2026072810110429800_cit33","doi-asserted-by":"publisher","first-page":"3320","DOI":"10.1039\/D4TC04537H","article-title":"Lanthanide coordination\npolymers as luminescent thermometers:\nintegrating theoretical modeling with experimental analysis to tune\nthe thermal response","volume":"13","author":"Bispo-Jr","year":"2025","journal-title":"J. Mater. Chem. C"},{"key":"2026072810110429800_cit34","doi-asserted-by":"publisher","first-page":"22616","DOI":"10.1039\/D5TC02967H","article-title":"Insights\ninto quantum cutting and downshifting contributions to near-infrared\nYbIII luminescence in 1D coordination polymers","volume":"13","author":"Bispo","year":"2025","journal-title":"J. Mater. Chem. C"},{"key":"2026072810110429800_cit35","doi-asserted-by":"publisher","first-page":"1207","DOI":"10.1039\/D4TC03823A","article-title":"The role of terminal\nand bridge ligands in the molecular upconversion of lanthanide(III)\n1D coordination polymers","volume":"13","author":"de Andrade","year":"2025","journal-title":"J. Mater. Chem. C"},{"key":"2026072810110429800_cit36","doi-asserted-by":"publisher","first-page":"9881","DOI":"10.1039\/D1DT01550H","article-title":"Luminescence thermometry based on one-dimensional benzoato-bridged\ncoordination polymers containing lanthanide ions","volume":"50","author":"Topor","year":"2021","journal-title":"Dalton Trans."},{"key":"2026072810110429800_cit37","doi-asserted-by":"publisher","first-page":"493","DOI":"10.1039\/a808692c","article-title":"Non-radiative\ndeactivation of the excited states of europium, terbium and ytterbium\ncomplexes by proximate energy-matched OH, NH and CH oscillators: an\nimproved luminescence method for establishing solution hydration states","volume":"2","author":"Beeby","year":"1999","journal-title":"J. Chem. Soc., Perkin Trans."},{"key":"2026072810110429800_cit38","doi-asserted-by":"publisher","first-page":"3742","DOI":"10.1039\/C8SC00259B","article-title":"Highly luminescent,\nbiocompatible ytterbium(III) complexes\nas nearinfrared fluorophores for living cell imaging","volume":"9","author":"Ning","year":"2018","journal-title":"Chem. Sci."},{"key":"2026072810110429800_cit39","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1039\/B905604C","article-title":"Lanthanide luminescence for functional materials and\nbio-sciences","volume":"39","author":"Eliseeva","year":"2010","journal-title":"Chem. Soc. Rev."},{"key":"2026072810110429800_cit40","doi-asserted-by":"publisher","first-page":"505","DOI":"10.1039\/a706152h","article-title":"Complexes\nof p-tert-butylcalix[5]arene with lanthanides: synthesis, structure\nand photophysical properties","volume":"3","author":"Charbonnie\u0300re","year":"1998","journal-title":"J. Chem. Soc.,\nDalton Trans."},{"key":"2026072810110429800_cit41","doi-asserted-by":"publisher","first-page":"18156","DOI":"10.1021\/acs.inorgchem.0c02611","article-title":"Composition-Thermometric\nProperties Correlations in Homodinuclear Eu3+ Luminescent Complexes","volume":"59","author":"Bellucci","year":"2020","journal-title":"Inorg. Chem."},{"key":"2026072810110429800_cit42","doi-asserted-by":"crossref","unstructured":"Canisares, F. S. M.; Laurindo, M. G.; Saraiva, L. F.; Araujo-Neto, J. H.; Ellena, J.; Brito, H. F.; Bispo-Jr, A. G.\n          Elucidating\nthermally activated luminescence quenching in EuIII \u03b2-diketonate\ncomplexes as crystals or polymeric films for application in thermometry\n          J. Mater. Chem. 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