{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T12:13:20Z","timestamp":1788437600540,"version":"build-2803163510"},"reference-count":53,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001509","name":"Royal Society Te Aparangi","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100001509","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2021QB096"],"award-info":[{"award-number":["ZR2021QB096"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013266","name":"MacDiarmid Institute for Advanced Materials and Nanotechnology","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100013266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Shandong provincial ?Double-hundred talents? program","doi-asserted-by":"publisher","award":["WSR2023071"],"award-info":[{"award-number":["WSR2023071"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Electrocatalytic nitrite reduction for ammonia synthesis offers a novel green pathway to overcome limitations of the Haber\u2013Bosch process, though it remains constrained by issues such as sluggish adsorption\/desorption kinetics of reaction intermediates. This study employs waste peanut shells as feedstock to synthesize FeP2\/PS nanocatalysts in situ via single-step high-temperature calcination. This catalyst enhances the active surface area through the incorporation of a biochar support and phosphorus (P) elements. Simultaneously, the introduction of phosphorus atoms and their electronegativity induces a directed electron transfer from iron to phosphorus within FeP2. The resulting FeP2\/PS exhibits a Faradaic efficiency of 98.94% in the nitrite reduction reaction (NO2\u2013RR), with an ammonia yield of 308.459 \u03bcmol h\u20131 cm\u20132. Performance remained stable after 15 cycles. Based on density functional theory (DFT) calculations, the P sites in FeP2\/PS act as bridges for electron and proton transport, effectively mediating electron transfer and charge supply to the Fe active sites, and optimizing the electronic structure of the Fe sites, thereby greatly enhancing the catalyst\u2019s adsorption of nitrite (NO2\u2013) and key reaction intermediates, lowering the reaction energy barrier, and accelerating the NO2\u2013 reduction kinetics, which significantly improves the yield of electrocatalytic ammonia synthesis.<\/jats:p>","DOI":"10.1021\/acsomega.6c03443","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T13:03:35Z","timestamp":1786539815000},"page":"51106-51118","source":"Crossref","is-referenced-by-count":0,"title":["Peanut Shell-Derived\nBiochar Loaded with Iron Phosphide\nas a Catalyst for Effective Electrocatalytic Ammonia Synthesis from\nNitrite"],"prefix":"10.1021","volume":"11","author":[{"given":"Jing","family":"Dong","sequence":"first","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Zhao","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Lei","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjun","family":"Lin","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengru","family":"Lang","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixuan","family":"Zhao","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8257-0781","authenticated-orcid":true,"given":"Chuanjun","family":"Wang","sequence":"additional","affiliation":[{"name":"Shandong Agricultural University , , , ,","place":["Tai\u2019an, Shandong, China, 271018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoqiang","family":"Wang","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, PR China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3296-3093","authenticated-orcid":true,"given":"Geoffrey","family":"Waterhouse","sequence":"additional","affiliation":[{"name":"The University of Auckland , , ,","place":["Auckland, New Zealand, 1142"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,12]]},"reference":[{"key":"2026090307190349700_cit1","doi-asserted-by":"publisher","first-page":"119621","DOI":"10.1016\/j.jelechem.2025.119621","article-title":"Engineering the surface\nchemical microenvironment over CuO porous nano-olives by proline for\nefficient ammonia electrosynthesis from nitrite","volume":"1000","author":"Li","year":"2026","journal-title":"J. Electroanal. Chem."},{"issue":"4","key":"2026090307190349700_cit2","doi-asserted-by":"publisher","first-page":"1528","DOI":"10.1039\/D4SC05936K","article-title":"Valorization systems\nbased on electrocatalytic nitrate\/nitrite conversion for energy supply\nand valuable product synthesis","volume":"16","author":"Feng","year":"2025","journal-title":"Chem. Sci."},{"issue":"26","key":"2026090307190349700_cit3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402841","article-title":"Controlled\nsynthesis of unconventional phase alloy\nnanobranches for highly selective electrocatalytic nitrite reduction\nto ammonia","volume":"63","author":"Wang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"issue":"11","key":"2026090307190349700_cit4","doi-asserted-by":"publisher","first-page":"755","DOI":"10.1038\/s44359-025-00102-9","article-title":"Ammonia as a renewable energy carrier from synthesis\nto utilization","volume":"1","author":"Wen","year":"2025","journal-title":"Nat. Rev. Clean Technol."},{"key":"2026090307190349700_cit5","doi-asserted-by":"publisher","first-page":"112988","DOI":"10.1016\/j.envres.2022.112988","article-title":"Nitrate and nitrite\ncontamination in drinking water and cancer risk: A systematic review\nwith meta-analysis","volume":"210","author":"Picetti","year":"2022","journal-title":"Environ. Res."},{"key":"2026090307190349700_cit6","doi-asserted-by":"publisher","first-page":"101858","DOI":"10.1016\/j.mtphys.2025.101858","article-title":"Self-powered energy-efficient\nammonia electrosynthesis via zinc-nitrite\nbattery with bifunctional Pd-Co(OH)2 electrocatalyst","volume":"58","author":"Xiao","year":"2025","journal-title":"Mater. Today Phys."},{"key":"2026090307190349700_cit7","doi-asserted-by":"publisher","first-page":"148952","DOI":"10.1016\/j.cej.2024.148952","article-title":"Critical review in electrocatalytic nitrate reduction\nto ammonia towards a sustainable nitrogen utilization","volume":"483","author":"Zhang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026090307190349700_cit8","doi-asserted-by":"publisher","first-page":"459","DOI":"10.1016\/j.jechem.2023.12.024","article-title":"Comprehensive understanding of the\nthriving electrocatalytic nitrate\/nitrite reduction to ammonia under\nambient conditions","volume":"92","author":"Zhao","year":"2024","journal-title":"J. Energy Chem."},{"key":"2026090307190349700_cit9","doi-asserted-by":"publisher","first-page":"294","DOI":"10.1016\/j.electacta.2012.06.014","article-title":"Cobalt\nnanoflowers: Synthesis, characterization and derivatization to cobalt\nhexacyanoferrate\u2500Electrocatalytic oxidation and determination\nof sulfite and nitrite","volume":"77","author":"Heli","year":"2012","journal-title":"Electrochim. Acta"},{"key":"2026090307190349700_cit10","doi-asserted-by":"publisher","first-page":"151835","DOI":"10.1016\/j.ijhydene.2025.151835","article-title":"Phosphate-functionalized copper oxide promotes the\nammonia electrosynthesis from nitrite waste","volume":"184","author":"Wang","year":"2025","journal-title":"Int. J. Hydrogen Energy"},{"issue":"7","key":"2026090307190349700_cit11","doi-asserted-by":"publisher","first-page":"107100","DOI":"10.1016\/j.isci.2023.107100","article-title":"High-efficiency\nelectrocatalytic nitrite reduction toward ammonia synthesis on CoP@TiO2 nanoribbon array","volume":"26","author":"He","year":"2023","journal-title":"iScience"},{"issue":"33","key":"2026090307190349700_cit12","doi-asserted-by":"publisher","first-page":"5160","DOI":"10.1039\/D2CC00611A","article-title":"A 3D FeOOH nanotube\narray: an efficient catalyst for ammonia electrosynthesis by nitrite\nreduction\u2020\u2020Electronic supplementary information (ESI)\navailable: Experimental section and supplementary figures","volume":"58","author":"Liu","year":"2022","journal-title":"Chem. Commun."},{"issue":"24","key":"2026090307190349700_cit13","doi-asserted-by":"publisher","first-page":"14242","DOI":"10.1021\/acsomega.9b03829","article-title":"Ultrasonic assisted\nsynthesis of size-controlled Cu-metal\u2013organic framework decorated\ngraphene oxide composite: sustainable electrocatalyst for the trace-level\ndetermination of nitrite in environmental water samples","volume":"5","author":"Arul","year":"2020","journal-title":"ACS Omega"},{"issue":"1","key":"2026090307190349700_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202512473","article-title":"CO2-mediated\ndynamic site modulation in copper catalysts for selective electrocatalytic\nnitrite-to-ammonia conversion","volume":"36","author":"Gao","year":"2026","journal-title":"Adv. Funct. Mater."},{"issue":"40","key":"2026090307190349700_cit15","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509944","article-title":"Architecture engineering\nand phase engineering of rhodium metallene\nCo-boost nitrite-to-ammonia electroconversion","volume":"64","author":"Yuan","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090307190349700_cit16","doi-asserted-by":"publisher","first-page":"119988","DOI":"10.1016\/j.jelechem.2026.119988","article-title":"Metastable\nFe-Co\/NC electrocatalysts engineered by ultrafast 500 \u00b0C Joule-heating:\na break from the high-temperature paradigm for superior ORR","volume":"1009","author":"Wang","year":"2026","journal-title":"J. Electroanal. Chem."},{"issue":"26","key":"2026090307190349700_cit17","doi-asserted-by":"publisher","first-page":"22785","DOI":"10.1021\/jacs.5c04950","article-title":"Tiara Ni clusters\nfor electrocatalytic nitrate reduction\nto ammonia with 97% faradaic efficiency","volume":"147","author":"Gu","year":"2025","journal-title":"J.\nAm. Chem. Soc."},{"issue":"47","key":"2026090307190349700_cit18","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75535","article-title":"Universal\ninterface metal imprinting for surface-selective synthesis of mesoporous\nnitrogen-doped carbon supported single-atom catalysts","volume":"36","author":"Hu","year":"2026","journal-title":"Adv. Funct. Mater."},{"issue":"11","key":"2026090307190349700_cit19","doi-asserted-by":"publisher","first-page":"2400523","DOI":"10.1002\/adsu.202400523","article-title":"Electrocatalytic\nreduction of nitrate\/nitrite to ammonia on CuCo nanoparticles decorated\nN-doped carbon","volume":"9","author":"Cang","year":"2025","journal-title":"Adv. Sustainable Syst."},{"issue":"18","key":"2026090307190349700_cit20","doi-asserted-by":"publisher","first-page":"18693","DOI":"10.1021\/jacs.5c21242","article-title":"Highly efficient\nalkene radical difunctionalization toward alkyl azide and nitrile\nachieved by copper single-atom catalysts","volume":"148","author":"Ge","year":"2026","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026090307190349700_cit21","doi-asserted-by":"publisher","first-page":"159082","DOI":"10.1016\/j.apsusc.2023.159082","article-title":"Interface coupling of Ni2P@Cu3P catalyst to\nfacilitate highly-efficient electrochemical reduction of nitrate to\nammonia","volume":"648","author":"Lv","year":"2024","journal-title":"Appl. Surf. Sci."},{"issue":"2","key":"2026090307190349700_cit22","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202501193","article-title":"Recent advances in electrocatalytic nitrate reduction to ammonia","volume":"19","author":"Lin","year":"2026","journal-title":"ChemSusChem"},{"key":"2026090307190349700_cit23","doi-asserted-by":"publisher","first-page":"116171","DOI":"10.1016\/j.jelechem.2022.116171","article-title":"CoP nanowires\non carbon cloth for electrocatalytic NOx\u2013 reduction to ammonia","volume":"910","author":"Zhang","year":"2022","journal-title":"J. Electroanal. Chem."},{"key":"2026090307190349700_cit24","doi-asserted-by":"publisher","first-page":"164265","DOI":"10.1016\/j.apsusc.2025.164265","article-title":"One-step in situ construction of\nsub-nanometer FeP anchored to biomass-based\ncarbon defects for electrochemical nitrite reduction to ammonia over\na wide concentration range with long duration","volume":"713","author":"Zhou","year":"2025","journal-title":"Appl. Surf. Sci."},{"key":"2026090307190349700_cit25","doi-asserted-by":"publisher","first-page":"171632","DOI":"10.1016\/j.cej.2025.171632","article-title":"Metal complex-derived\ncarbon-coated cobalt phosphide nanoparticles supported on C3N4 for efficient electrocatalytic nitrite reduction to\nammonia","volume":"527","author":"Liu","year":"2026","journal-title":"Chem. Eng. J."},{"issue":"24","key":"2026090307190349700_cit26","doi-asserted-by":"publisher","first-page":"2311439","DOI":"10.1002\/smll.202311439","article-title":"Facile construction of CuFe-based metal phosphides for synergistic\nNOx\u2013 reduction to NH3 and\nZn-nitrite batteries in electrochemical cell","volume":"20","author":"Wang","year":"2024","journal-title":"Small"},{"issue":"1","key":"2026090307190349700_cit27","doi-asserted-by":"publisher","first-page":"558","DOI":"10.1103\/PhysRevB.47.558","article-title":"Ab initio molecular\ndynamics for liquid metals","volume":"47","author":"Kresse","year":"1993","journal-title":"Phys. Rev. B: Condens.\nMatter"},{"issue":"20","key":"2026090307190349700_cit28","doi-asserted-by":"publisher","first-page":"14251","DOI":"10.1103\/PhysRevB.49.14251","article-title":"Ab initio molecular-dynamics simulation of the liquid-metal-amorphous-semiconductor\ntransition in germanium","volume":"49","author":"Kresse","year":"1994","journal-title":"Phys. Rev. B: Condens.\nMatter"},{"issue":"18","key":"2026090307190349700_cit29","doi-asserted-by":"publisher","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","article-title":"Generalized\ngradient approximation\nmade simple","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"2026090307190349700_cit30","doi-asserted-by":"publisher","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","article-title":"From ultrasoft pseudopotentials to the projector augmented-wave\nmethod","volume":"59","author":"Kresse","year":"1999","journal-title":"Phys. Rev. B"},{"issue":"15","key":"2026090307190349700_cit31","doi-asserted-by":"publisher","first-page":"154104","DOI":"10.1063\/1.3382344","article-title":"A consistent\nand accurate\nab initio parametrization of density functional dispersion correction\n(DFT-D) for the 94 elements H-Pu","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"issue":"1","key":"2026090307190349700_cit32","doi-asserted-by":"publisher","first-page":"7958","DOI":"10.1038\/s41467-022-35664-w","article-title":"Active hydrogen boosts electrochemical nitrate reduction\nto ammonia","volume":"13","author":"Fan","year":"2022","journal-title":"Nat. Commun."},{"key":"2026090307190349700_cit33","doi-asserted-by":"publisher","first-page":"874","DOI":"10.3390\/su15010874","article-title":"The removal of tetracycline\nfrom aqueous solutions\nusing peanut shell biochars prepared at different pyrolysis temperatures","volume":"15","author":"Shi","year":"2023","journal-title":"Sustainability"},{"issue":"6","key":"2026090307190349700_cit34","doi-asserted-by":"publisher","first-page":"1066","DOI":"10.1007\/s11783-015-0769-y","article-title":"Removing phosphorus\nfrom aqueous solutions by using iron-modified corn straw biochar","volume":"9","author":"Liu","year":"2015","journal-title":"Front. Environ. Sci. Eng."},{"key":"2026090307190349700_cit35","doi-asserted-by":"publisher","first-page":"143371","DOI":"10.1016\/j.cej.2023.143371","article-title":"Elucidation\nof the\nelectrocatalytic activity origin of Fe3C species and application\nin the NOx full conversion to valuable ammonia","volume":"467","author":"Hao","year":"2023","journal-title":"Chem. Eng. J."},{"issue":"5","key":"2026090307190349700_cit36","doi-asserted-by":"publisher","first-page":"681","DOI":"10.1007\/s00374-024-01805-0","article-title":"Pyrolysis temperature affects biochar\nsuitability as an alternative rhizobial carrier","volume":"60","author":"Shabir","year":"2024","journal-title":"Biol. Fertil. Soils"},{"key":"2026090307190349700_cit37","doi-asserted-by":"publisher","first-page":"129673","DOI":"10.1016\/j.colsurfa.2022.129673","article-title":"PANI-coated porous FeP sheets as bifunctional electrocatalyst\nfor\nwater splitting","volume":"651","author":"Gao","year":"2022","journal-title":"Colloids Surf., A"},{"key":"2026090307190349700_cit38","doi-asserted-by":"publisher","first-page":"2528","DOI":"10.1039\/d3cc04897g","article-title":"FeP-Fe3O4 nanospheres for electrocatalytic\nN2 reduction to NH3 under ambient conditions","volume":"60","author":"Zhang","year":"2024","journal-title":"Chem. Commun."},{"issue":"3","key":"2026090307190349700_cit39","doi-asserted-by":"publisher","first-page":"94","DOI":"10.1007\/s00604-023-05672-8","article-title":"Magnetic Fe3O4 nanoparticles decorated phosphorus-doped\nbiochar-attapulgite\/bismuth\nfilm electrode for smartphone-operated wireless portable sensing of\nultra-trace multiple heavy metal ions","volume":"190","author":"Huang","year":"2023","journal-title":"Microchim.\nActa"},{"key":"2026090307190349700_cit40","doi-asserted-by":"publisher","first-page":"149666","DOI":"10.1016\/j.cej.2024.149666","article-title":"Vacancy engineering\nof FeP dispersed N, P-doped porous carbon for\nhigh-performance capacitive deionization","volume":"484","author":"Wang","year":"2024","journal-title":"Chem.\nEng. J."},{"key":"2026090307190349700_cit41","doi-asserted-by":"publisher","first-page":"125947","DOI":"10.1016\/j.seppur.2023.125947","article-title":"Pomelo peel\nderived phosphorus-doped biochar for efficient\ndisposal of uranium-containing nuclear wastewater: Experimental and\ntheoretical perspectives","volume":"333","author":"Li","year":"2024","journal-title":"Sep. Purif. Technol."},{"issue":"1","key":"2026090307190349700_cit42","doi-asserted-by":"publisher","first-page":"1267","DOI":"10.1021\/acsami.8b17612","article-title":"Multishelled FeCo@FeCoP@C hollow\nspheres as highly efficient hydrogen evolution catalysts","volume":"11","author":"Zhang","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"9","key":"2026090307190349700_cit43","doi-asserted-by":"publisher","first-page":"818","DOI":"10.1038\/s41929-023-01005-3","article-title":"Strain\nenhances the activity of molecular electrocatalysts via carbon\nnanotube supports","volume":"6","author":"Su","year":"2023","journal-title":"Nat. Catal."},{"key":"2026090307190349700_cit44","doi-asserted-by":"publisher","first-page":"108840","DOI":"10.1016\/j.nanoen.2023.108840","article-title":"Highly dispersed copper-iron\nnanoalloy enhanced electrocatalytic reduction coupled with plasma\noxidation for ammonia synthesis from ubiquitous air and water","volume":"117","author":"Liu","year":"2023","journal-title":"Nano Energy"},{"key":"2026090307190349700_cit45","doi-asserted-by":"publisher","first-page":"112624","DOI":"10.1016\/j.jpcs.2025.112624","article-title":"Ginkgo leaf nanoarchitectonics-derived carbon materials\ncontaining ultrathin carbon nanosheets for high-performance symmetric\nsupercapacitors","volume":"200","author":"Zhang","year":"2025","journal-title":"J. Phys. Chem. Solids"},{"key":"2026090307190349700_cit46","doi-asserted-by":"publisher","first-page":"129074","DOI":"10.1016\/j.seppur.2024.129074","article-title":"Co, and N-doped titanium mesh-based carbon nanosheet\narrays for enhanced nitrite reduction reaction and ammonia generation","volume":"354","author":"Zhao","year":"2025","journal-title":"Sep. Purif. Technol."},{"issue":"1","key":"2026090307190349700_cit47","doi-asserted-by":"publisher","first-page":"78","DOI":"10.1021\/acs.inorgchem.3c04194","article-title":"Promoting Nitrite-to-Ammonia Electroreduction over\nAmorphous CoS2 Nanorods","volume":"63","author":"Qu","year":"2024","journal-title":"Inorg. Chem."},{"issue":"3","key":"2026090307190349700_cit48","doi-asserted-by":"publisher","first-page":"109718","DOI":"10.1016\/j.jece.2023.109718","article-title":"Co-N bond promotes the H* pathway for the electrocatalytic reduction\nof nitrate (NO3RR) to ammonia","volume":"11","author":"Liu","year":"2023","journal-title":"J.\nEnviron. Chem. Eng."},{"issue":"2","key":"2026090307190349700_cit49","doi-asserted-by":"publisher","first-page":"972","DOI":"10.1007\/s12274-021-3583-9","article-title":"Ambient ammonia production via electrocatalytic\nnitrite reduction catalyzed by a CoP nanoarray","volume":"15","author":"Wen","year":"2022","journal-title":"Nano Res."},{"key":"2026090307190349700_cit50","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.apcatb.2018.10.019","article-title":"Direct Z-scheme\nZnO\/CdS hierarchical photocatalyst for enhanced photocatalytic H2-production activity","volume":"243","author":"Wang","year":"2019","journal-title":"Appl. Catal.,\nB"},{"key":"2026090307190349700_cit51","doi-asserted-by":"publisher","first-page":"1055","DOI":"10.1016\/j.jcis.2021.08.050","article-title":"Ni2P nanosheet array for high-efficiency\nelectrohydrogenation\nof nitrite to ammonia at ambient conditions","volume":"606","author":"Wen","year":"2022","journal-title":"J. Colloid Interface Sci."},{"issue":"14","key":"2026090307190349700_cit52","doi-asserted-by":"publisher","first-page":"9665","DOI":"10.1021\/jacs.3c13288","article-title":"Electrocatalytic nitrate\nand nitrite reduction toward ammonia using Cu2O nanocubes:\nactive species and reaction mechanisms","volume":"146","author":"Bai","year":"2024","journal-title":"J. Am.\nChem. Soc."},{"issue":"52","key":"2026090307190349700_cit53","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202509113","article-title":"Single-site polyoxometalate complexes with engineered electron channels\nfor efficient electrocatalytic ammonia synthesis from nitrate","volume":"21","author":"Jiang","year":"2025","journal-title":"Small"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c03443","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/34\/51106\/66510842\/acsomega.6c03443.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/34\/51106\/66510842\/acsomega.6c03443.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T11:19:10Z","timestamp":1788434350000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/34\/51106\/5253402\/Peanut-Shell-Derived-Biochar-Loaded-with-Iron"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,12]]},"references-count":53,"journal-issue":{"issue":"34","published-online":{"date-parts":[[2026,8,12]]},"published-print":{"date-parts":[[2026,9,1]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c03443","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,12]]}}}