{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T15:58:44Z","timestamp":1791302324654,"version":"4.1.0"},"reference-count":55,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T00:00:00Z","timestamp":1790121600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"name":"Scientific and Technological Project of Yunnan Precious Metals Laboratory","award":["YPML-2023050213"],"award-info":[{"award-number":["YPML-2023050213"]}]},{"name":"Scientific and Technological Project of Yunnan Precious Metals Laboratory","award":["YPML-20240502044"],"award-info":[{"award-number":["YPML-20240502044"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Diatom frustules offer hierarchically porous biosilica templates for sustainable electrode design; however, their low electrical conductivity and limited electrochemically accessible sites constrain lithium-storage performance. In this study, a two-stage cultivation strategy was used to introduce Ce-related species into Cyclotella cryptica frustules, followed by purification and pyrolysis to obtain Ce-functionalized biosilica\/carbon anodes. Ce-200 provided the best balance among biological tolerance, cerium enrichment, structural retention, pore evolution, and electrochemical performance. SEM, ICP-MS, XPS, Raman, and nitrogen sorption analyses confirmed cerium enrichment, preservation of the frustule morphology, formation of defect-containing carbon, and an approximately 3-fold increase in specific surface area. In half-cells, DBS\/C@Ce200 delivered 932.8 mAh g\u20131 after 200 cycles at 0.1 A g\u20131 and retained 527.0 mAh g\u20131 at 2 A g\u20131. CV, EIS, and postcycling SEM results were consistent with improved charge-transfer behavior and structural stability. This work demonstrates bioassisted cerium modification as a promising route for diatom-derived lithium-ion battery anodes.<\/jats:p>","DOI":"10.1021\/acsomega.6c03561","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T16:01:53Z","timestamp":1790179313000},"page":"58884-58895","source":"Crossref","is-referenced-by-count":0,"title":["Cerium-Modified\nDiatom Biosilica for Lithium-Ion Anodes"],"prefix":"10.1021","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6048-9122","authenticated-orcid":true,"given":"Hongwei","family":"Liu","sequence":"first","affiliation":[{"name":"Key Laboratory of Biometallurgy of Ministry of Education , ,","place":["Changsha, Hunan, China, 410083"]},{"name":"Central South University , , , ,","place":["Changsha, Hunan, China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-0448-5383","authenticated-orcid":true,"given":"Can","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biometallurgy of Ministry of Education , ,","place":["Changsha, Hunan, China, 410083"]},{"name":"Central South University , , , ,","place":["Changsha, Hunan, China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Huang","sequence":"additional","affiliation":[{"name":"Hunan Juwei Carbon Technology Co. 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