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We investigate MoS2 grown on three technologically relevant substrates, namely SrTiO3(111), c-axis Al2O3(0001) and 6H-SiC(0001). Experimental investigations by temperature dependent resistivity, photoemission spectroscopy and scanning transmission electron microscopy with coupled energy dispersive spectroscopy, with the support of theoretical calculation by Density Functional Theory, allow the identification of the substrate induced specific defects and their correlation with the electronic properties. Ti interdiffusion in SrTiO3\/MoS2 generates p-type states near the Fermi level, leading to metallic transport. Al2O3\/MoS2 exhibits a high density of sulfur-related defects that introduce localized states and yield nearly temperature independent conductivity. SiC\/MoS2 exhibits significant interface disorder resulting in a semiconducting temperature dependent resistivity, yet deviating from the ideal bulk-like behavior. These results demonstrate how substrate choice governs defect formation and ultimately dominates the electronic behavior of MoS2 thin films, making the control of film\/substrate interactions essential for the engineering of new functional devices.<\/jats:p>","DOI":"10.1021\/acsomega.6c03932","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T15:01:37Z","timestamp":1788793297000},"page":"55454-55464","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial Properties\nof MoS2 Thin Films\nGrown on Functional Substrates"],"prefix":"10.1021","volume":"11","author":[{"given":"Hafiz","family":"Sami Ur Rehman","sequence":"first","affiliation":[{"name":"Universita\u0300 Degli Studi di Salerno , , , ,","place":["Fisciano, Salerno, Italy, 84084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3650-1395","authenticated-orcid":true,"given":"Nunzia","family":"Coppola","sequence":"additional","affiliation":[{"name":"Universita\u0300 Degli Studi di Salerno , , , ,","place":["Fisciano, Salerno, Italy, 84084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2863-5393","authenticated-orcid":true,"given":"Alice","family":"Galdi","sequence":"additional","affiliation":[{"name":"Universita\u0300 Degli Studi di Salerno , , , ,","place":["Fisciano, Salerno, Italy, 84084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3689-3336","authenticated-orcid":true,"given":"Sandeep Kumar","family":"Chaluvadi","sequence":"additional","affiliation":[{"name":"CNR-IOM , Strada Statale 14 Km 163.5 , , ,","place":["Basovizza, Trieste, Italy, 34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3329-2735","authenticated-orcid":true,"given":"Shyni","family":"Punathum Chalil","sequence":"additional","affiliation":[{"name":"CNR-IOM , Strada Statale 14 Km 163.5 , , ,","place":["Basovizza, Trieste, Italy, 34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1082-9651","authenticated-orcid":true,"given":"Pasquale","family":"Orgiani","sequence":"additional","affiliation":[{"name":"CNR-IOM , Strada Statale 14 Km 163.5 , , ,","place":["Basovizza, Trieste, Italy, 34149"]},{"name":"Area Science Park , Padriciano 99 , ,","place":["Trieste, Italy, 34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sara","family":"Passuti","sequence":"additional","affiliation":[{"name":"Area Science Park , Padriciano 99 , ,","place":["Trieste, Italy, 34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Regina","family":"Ciancio","sequence":"additional","affiliation":[{"name":"Area Science Park , Padriciano 99 , ,","place":["Trieste, Italy, 34149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7222-8627","authenticated-orcid":true,"given":"Paolo","family":"Barone","sequence":"additional","affiliation":[{"name":"CNR-SPIN , via del Fosso del Cavaliere 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luigi","family":"Maritato","sequence":"additional","affiliation":[{"name":"Universita\u0300 Degli Studi di Salerno , , , ,","place":["Fisciano, Salerno, Italy, 84084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6917-6667","authenticated-orcid":true,"given":"Carmela","family":"Aruta","sequence":"additional","affiliation":[{"name":"CNR-SPIN , via del Fosso del Cavaliere 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"2026092210571862700_cit1","doi-asserted-by":"publisher","first-page":"100","DOI":"10.1126\/science.1141483","article-title":"Identification of Active Edge Sites for Electrochemical\nH2 Evolution from MoS2 Nanocatalysts","volume":"317","author":"Jaramillo","year":"2007","journal-title":"Science"},{"key":"2026092210571862700_cit2","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1039\/C7NH00137A","article-title":"Group 6 Transition Metal Dichalcogenide Nanomaterials:\nSynthesis, Applications and Future Perspectives","volume":"3","author":"Samadi","year":"2018","journal-title":"Nanoscale Horiz."},{"key":"2026092210571862700_cit3","doi-asserted-by":"publisher","first-page":"263","DOI":"10.1038\/nchem.1589","article-title":"The Chemistry of Two-Dimensional Layered Transition Metal Dichalcogenide\nNanosheets","volume":"5","author":"Chhowalla","year":"2013","journal-title":"Nat. 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