{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T15:58:32Z","timestamp":1791302312993,"version":"4.1.0"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior","doi-asserted-by":"publisher","award":["001"],"award-info":[{"award-number":["001"]}],"id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Lignocellulosic biomass is considered a promising alternative to fossil fuels. Due to its complex composition, understanding its thermal behavior is essential for improving the energy efficiency of thermochemical conversion processes. Thermogravimetric analysis has been widely used to investigate biomass thermal behavior; however, available studies are generally fragmented across different materials and experimental conditions, limiting direct comparisons. Therefore, this study provides a systematic comparison of eucalyptus wood and sugarcane bagasse, together with their structural fractions, under identical thermogravimetric conditions. This study investigates the thermal decomposition behavior of eucalyptus wood chips and sugarcane bagasse, as well as their structural components\u2500cellulose, hemicellulose, and lignin\u2500to better understand biomass pyrolysis processes. Proximate and chemical analyses were conducted to characterize the biomass and isolate its structural fractions, followed by thermogravimetric (TG\/DTG) analysis. In addition, DTG curve deconvolution was performed to quantitatively evaluate overlapping degradation events. In general, eucalyptus and sugarcane bagasse exhibited similar TG and DTG profiles under equivalent conditions, including the in natura biomass and samples after sequential removal of extractives, hemicellulose (holocellulose), and \u03b1-cellulose. However, a gradual disappearance of the shoulder peak (Tsh) preceding the maximum decomposition temperature, together with a narrowing of the main DTG peak, was observed after the sequential removal of structural components, indicating the influence of extractives and hemicellulose on thermal decomposition. Deconvolution analysis quantitatively confirmed the contribution of these overlapping thermal events. These results establish a direct relationship between chemical composition and thermal behavior under standardized conditions. The comparative evaluation of biomass and its structural fractions, complemented by DTG curve deconvolution, provides quantitative information that improves the interpretation of thermal degradation events and supports the development of thermochemical conversion technologies for bioenergy applications.<\/jats:p>","DOI":"10.1021\/acsomega.6c04390","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T14:01:31Z","timestamp":1790517691000},"page":"59064-59077","source":"Crossref","is-referenced-by-count":0,"title":["Linking Chemical\nComposition to Thermal Decomposition\nof Lignocellulosic Biomass and Its Structural Fractions: Insights\nfrom Eucalyptus and Sugarcane Bagasse"],"prefix":"10.1021","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2739-2596","authenticated-orcid":true,"given":"Nata\u0301lia","family":"R. de Carvalho","sequence":"first","affiliation":[{"name":"Federal University of Sa\u0303o Carlos , , Joa\u0303o Leme dos Santos Highway, Km 110 - SP-264, Itinga Neighborhood , , ,","place":["Sorocaba, Sa\u0303o Paulo, Brazil, 18052-780"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anna J. B.","family":"Correia","sequence":"additional","affiliation":[{"name":"Federal University of Sa\u0303o Carlos , , Joa\u0303o Leme dos Santos Highway, Km 110 - SP-264, Itinga Neighborhood , , ,","place":["Sorocaba, Sa\u0303o Paulo, Brazil, 18052-780"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gabriela T.","family":"Nakashima","sequence":"additional","affiliation":[{"name":"Brazilian Aluminium Company , , ,","place":["Alumi\u0301nio, Sa\u0303o Paulo, Brazil, 18125-000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ana Larissa S.","family":"Hansted","sequence":"additional","affiliation":[{"name":"Government of Newfoundland and Labrador , , , ,","place":["St. John\u2019s, NL, Canada, A1B 4J6"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ariane A. F.","family":"Pires","sequence":"additional","affiliation":[{"name":"Federal University of Sa\u0303o Carlos , , Joa\u0303o Leme dos Santos Highway, Km 110 - SP-264, Itinga Neighborhood , , ,","place":["Sorocaba, Sa\u0303o Paulo, Brazil, 18052-780"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tamaki","family":"Kugimiya","sequence":"additional","affiliation":[{"name":"Nagoya University , , Chikusa , ,","place":["Nagoya, Japan, 464-8601"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroyuki","family":"Yamamoto","sequence":"additional","affiliation":[{"name":"Nagoya University , , Chikusa , ,","place":["Nagoya, Japan, 464-8601"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0908-8163","authenticated-orcid":true,"given":"Fa\u0301bio M.","family":"Yamaji","sequence":"additional","affiliation":[{"name":"Federal University of Sa\u0303o Carlos , , Joa\u0303o Leme dos Santos Highway, Km 110 - SP-264, Itinga Neighborhood , , ,","place":["Sorocaba, Sa\u0303o Paulo, Brazil, 18052-780"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,27]]},"reference":[{"key":"2026100610484928200_cit1","doi-asserted-by":"publisher","first-page":"121086","DOI":"10.1016\/j.fuel.2021.121086","article-title":"Lignocellulosic biomass based biorefinery:\nA successful platform towards circular bioeconomy","volume":"302","author":"Rajesh Banu","year":"2021","journal-title":"Fuel"},{"key":"2026100610484928200_cit2","doi-asserted-by":"publisher","first-page":"114116","DOI":"10.1016\/j.enconman.2021.114116","article-title":"Two-step thermodegradation\nkinetics of cellulose, hemicelluloses,\nand lignin under isothermal torrefaction analyzed by particle swarm\noptimization","volume":"238","author":"Chen","year":"2021","journal-title":"Energy Conversion and Management"},{"key":"2026100610484928200_cit3","doi-asserted-by":"publisher","first-page":"117147","DOI":"10.1016\/j.energy.2020.117147","article-title":"Thermogravimetric analysis\non the co-combustion of biomass pellets with lignite and bituminous\ncoal","volume":"197","author":"Guo","year":"2020","journal-title":"Energy"},{"key":"2026100610484928200_cit4","doi-asserted-by":"publisher","first-page":"100538","DOI":"10.1016\/j.ecmx.2024.100538","article-title":"Lignocellulosic\nbiofuel properties and reactivity analyzed by thermogravimetric analysis\n(TGA) toward zero carbon scheme: A critical review","volume":"22","author":"Aniza","year":"2024","journal-title":"Energy Conversion and Management: X"},{"issue":"49","key":"2026100610484928200_cit5","doi-asserted-by":"publisher","first-page":"17216","DOI":"10.1021\/acssuschemeng.3c03769","article-title":"Thermogravimetric\nanalysis as a high-throughput lignocellulosic biomass characterization\nmethod","volume":"11","author":"Shapiro","year":"2023","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026100610484928200_cit6","doi-asserted-by":"publisher","first-page":"6524","DOI":"10.3390\/en15186524","article-title":"Analysis of\nPyrolysis Kinetic Parameters Based on Various Mathematical Models\nfor More than Twenty Different Biomasses: A Review","volume":"15","author":"Alvarado Flores","year":"2022","journal-title":"Energies"},{"key":"2026100610484928200_cit7","doi-asserted-by":"publisher","first-page":"5341","DOI":"10.3390\/en16145341","article-title":"Development of a Biomass\nComponent Prediction Model Based on Elemental\nand ProximatebAnalyses","volume":"16","author":"Park","year":"2023","journal-title":"Energies"},{"key":"2026100610484928200_cit8","doi-asserted-by":"publisher","first-page":"3674","DOI":"10.3390\/en16093674","article-title":"TGA-FTIR Analysis of Biomass Samples\nBased on the Thermal Decomposition Behavior of Hemicellulose, Cellulose,\nand Lignin","volume":"16","author":"Apayd\u0131n Varol","year":"2023","journal-title":"Energies"},{"key":"2026100610484928200_cit9","doi-asserted-by":"publisher","first-page":"247","DOI":"10.1016\/j.jechem.2020.08.060","article-title":"Lignocellulosic biomass as sustainable feedstock and materials for\npower generation and energy storage","volume":"57","author":"Wang","year":"2021","journal-title":"Journal\nof Energy Chemistry"},{"key":"2026100610484928200_cit10","doi-asserted-by":"publisher","first-page":"110305","DOI":"10.1016\/j.rser.2020.110305","article-title":"Catalytic pyrolysis of lignocellulosic biomass: A review of variations\nin process factors and system structure","volume":"134","author":"Kan","year":"2020","journal-title":"Renewable\nand Sustainable Energy Reviews"},{"key":"2026100610484928200_cit11","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1016\/S0960-8524(01)00118-3","article-title":"Energy production\nfrom biomass (part 1): overview of biomass","volume":"83","author":"Mckendry","year":"2002","journal-title":"Bioresour. Technol."},{"key":"2026100610484928200_cit12","doi-asserted-by":"publisher","first-page":"105106","DOI":"10.1016\/j.jaap.2021.105106","article-title":"Selective\nsequential fractionation of biomass for quantitatively elucidating\nthe compositional factors affecting biomass fast pyrolysis","volume":"156","author":"Zheng","year":"2021","journal-title":"Journal of Analytical and Applied Pyrolysis"},{"issue":"1","key":"2026100610484928200_cit13","doi-asserted-by":"publisher","first-page":"35","DOI":"10.21577\/0100-4042.20170663","article-title":"Caracterizac\u0327a\u0303o Fi\u0301sica\nE Qui\u0301mica\nDa Biomassa Usada Como Combusti\u0301vel So\u0301lido Em Uma Caldeira","volume":"44","author":"Carvalho","year":"2021","journal-title":"Quim. Nova"},{"key":"2026100610484928200_cit14","doi-asserted-by":"publisher","first-page":"100344","DOI":"10.1016\/j.carpta.2023.100344","article-title":"Thermochemical isolation\nand characterization of nanofibrillated cellulose from Stipa obtusa\nfibers","volume":"6","author":"Chavez","year":"2023","journal-title":"Carbohydrate Polymer Technologies and\nApplications"},{"key":"2026100610484928200_cit15","volume-title":"ASTM D1106-96(2013):\nStandard Test Method for Acid-Insoluble Lignin in Wood","author":"American Society for Testing and Materials.","year":"2013"},{"key":"2026100610484928200_cit16","volume-title":"D1104-56(1978): Standard\nTest Method of Test for Holocellulose in Wood","author":"American Society for Testing and Materials.","year":"1978"},{"key":"2026100610484928200_cit17","volume-title":"D1103-60(1977): Standard\nTest Method of test for alpha-cellulose in wood","author":"American Society for Testing and Materials.","year":"1977"},{"key":"2026100610484928200_cit18","doi-asserted-by":"publisher","first-page":"437","DOI":"10.1007\/s10973-016-5378-x","article-title":"Kinetic\nstudies of termal decomposition of sugarcane bagasse and cassava bagasse","volume":"125","author":"Zanatta","year":"2016","journal-title":"J. Therm Anal Calorim"},{"key":"2026100610484928200_cit19","doi-asserted-by":"publisher","first-page":"1754","DOI":"10.3390\/nano14211754","article-title":"Estabilidade\nte\u0301rmica e pureza do grafeno e dos nanotubos de carbono: para\u0302metros-chave\npara sua ana\u0301lise termogravime\u0301trica (TGA)","volume":"14","author":"Martincic","year":"2024","journal-title":"Nanomaterials"},{"issue":"4","key":"2026100610484928200_cit20","doi-asserted-by":"publisher","first-page":"867","DOI":"10.21577\/1984-6835.20200069","article-title":"Isolamento e Caracterizac\u0327a\u0303o de Lignina\nAcetossolve Extrai\u0301da do Bagac\u0327o de Cana-de-Ac\u0327u\u0301car","volume":"12","author":"Rodrigues","year":"2020","journal-title":"Rev. Virtual Quim."},{"key":"2026100610484928200_cit21","doi-asserted-by":"publisher","first-page":"1048","DOI":"10.3390\/pr8091048","article-title":"Determination\nof Hemicellulose, Cellulose, and Lignin Content in Different Types\nof Biomasses by Thermogravimetric Analysis and Pseudocomponent Kinetic\nModel (TGA-PKM Method)","volume":"8","author":"Di\u0301ez","year":"2020","journal-title":"Processes"},{"key":"2026100610484928200_cit22","volume-title":"Utilizac\u0327a\u0303o\nda Biomassa do Eucalipto para Produc\u0327a\u0303o de Calor, Vapor\ne Eletricidad: Parte 1: Biomassa Florestal & Florestas Energe\u0301ticas","author":"Foelkel","year":"2016"},{"key":"2026100610484928200_cit23","first-page":"54","article-title":"The University of Idaho wood-fired\nboiler: A case study","volume":"41","author":"Kirkland","year":"1991","journal-title":"Forest Products Journal"},{"issue":"6","key":"2026100610484928200_cit24","doi-asserted-by":"publisher","first-page":"403","DOI":"10.31413\/nativa.v4i6.3730","article-title":"Avaliac\u0327a\u0303o das propriedades\nfi\u0301sicas e qui\u0301micas da madeira de Corymbia citriodorae\nEucalyptus urophylla x Eucalyptus grandis cultivadas no Piaui\u0301","volume":"4","author":"Medeiros","year":"2016","journal-title":"NATIVA"},{"issue":"1","key":"2026100610484928200_cit25","doi-asserted-by":"publisher","first-page":"46","DOI":"10.21577\/1984-6835.20210097","article-title":"Avaliac\u0327a\u0303o do Potencial Energe\u0301tico\nde Resi\u0301duos Agroindustriais","volume":"14","author":"Fernanda Felippe Silva","year":"2022","journal-title":"Rev. Virtual\nQuim."},{"key":"2026100610484928200_cit26","doi-asserted-by":"publisher","first-page":"104079","DOI":"10.1016\/j.firesaf.2023.104079","article-title":"The influence of experimental conditions\non the mass loss for TGA in fire safety science","volume":"144","author":"De Lannoye","year":"2024","journal-title":"Fire Safety Journal"},{"key":"2026100610484928200_cit27","doi-asserted-by":"publisher","first-page":"2552","DOI":"10.3390\/agronomy13102552","article-title":"Evaluation of the Intermediate Values of the TGA Curves\nas Indicators of the Proximal Analysis of Biomass","volume":"13","author":"Vela\u0301zquez Marti\u0301","year":"2023","journal-title":"Agronomy"},{"key":"2026100610484928200_cit28","volume-title":"Theories of the combustion\nof wood and its control","author":"Browne","year":"1958"},{"key":"2026100610484928200_cit29","doi-asserted-by":"publisher","first-page":"862","DOI":"10.5902\/2179460X18332","article-title":"Estudo\nde ana\u0301lise termogravime\u0301trica de diferentes biomassas\nlignocelulo\u0301sicas utilizando a ana\u0301lise por componentes\nprincipais","volume":"37","author":"Rambo","year":"2015","journal-title":"CeN"},{"key":"2026100610484928200_cit30","doi-asserted-by":"publisher","first-page":"126181","DOI":"10.1016\/j.biortech.2021.126181","article-title":"Analyzing\nthe kinetics of waste plant biomass pyrolysis via thermogravimetry\nmodeling and semi-statistical methods","volume":"344","author":"Postawa","year":"2022","journal-title":"Bioresour.\nTechnol."},{"key":"2026100610484928200_cit31","doi-asserted-by":"publisher","first-page":"100344","DOI":"10.1016\/j.carpta.2023.100344","article-title":"Thermochemical isolation\nand characterization of nanofibrillated cellulose from Stipa obtusa\nfibers","volume":"6","author":"Chavez","year":"2023","journal-title":"Carbohydrate Polymer Technologies and\nApplications"},{"issue":"2026","key":"2026100610484928200_cit32","doi-asserted-by":"publisher","first-page":"100496","DOI":"10.1016\/j.jaecs.2026.100496","article-title":"Mechanistic insights\ninto thermal degradation of lignocellulosic biomass components for\nbioenergy and biofuel: A review","volume":"26","author":"Chen","year":"2026","journal-title":"Applications\nin Energy and Combustion Science"},{"key":"2026100610484928200_cit33","doi-asserted-by":"publisher","first-page":"118002","DOI":"10.1016\/j.fuel.2020.118002","article-title":"Biomass pyrolysis TGA assessment with an international\nround robin","volume":"276","author":"Anca-Couce","year":"2020","journal-title":"Fuel"},{"key":"2026100610484928200_cit34","doi-asserted-by":"publisher","first-page":"105427","DOI":"10.1016\/j.jaap.2021.105427","article-title":"Comprehensive thermokinetic\nmodelling and predictions of cellulose decomposition in isothermal,\nnon-isothermal, and stepwise heating modes","volume":"161","author":"Osman","year":"2022","journal-title":"Journal of Analytical and Applied Pyrolysis"},{"key":"2026100610484928200_cit35","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2021.e07669","article-title":"Multi-distribution\nactivation energy\nmodel on slow pyrolysis of celulose and lignin in TGA\/DSC","volume":"7","author":"Kristanto","year":"2021","journal-title":"Heliyon"},{"key":"2026100610484928200_cit36","doi-asserted-by":"publisher","first-page":"165","DOI":"10.1016\/j.enconman.2014.05.068","article-title":"Pyrolysis characteristics and kinetic\nparameters determination\nof biomass fuel powders by differential thermal gravimetric analysis\n(TGA\/DTG)","volume":"85","author":"EL-SAYED","year":"2014","journal-title":"Energy Conversion and Management"},{"key":"2026100610484928200_cit37","doi-asserted-by":"publisher","first-page":"106233","DOI":"10.1016\/j.jaap.2023.106233","article-title":"TG-FTIR-MS and Py-GC\/MS\nstudy on the pyrolysis characteristics and\ngas evolution behavior of forest duff","volume":"176","author":"Yang","year":"2023","journal-title":"Journal\nof Analytical and Applied Pyrolysis"},{"issue":"5","key":"2026100610484928200_cit38","doi-asserted-by":"publisher","first-page":"462","DOI":"10.13543\/j.cnki.bhxbzr.2007.05.019","article-title":"Comparison\nof the Pyrolysis and Kinetics\nof Three Components of Biomass","volume":"34","author":"Huang","year":"2007","journal-title":"J. Beijing Univ.\nChem. Technol."},{"key":"2026100610484928200_cit39","doi-asserted-by":"publisher","first-page":"103247","DOI":"10.1016\/j.cis.2024.103247","article-title":"Lignin\nself-assembly phenomena and valorization strategies for pulping, biorefining,\nand materials development: Part 1. The physical chemistry of lignin\nself-assembly","volume":"332","author":"Trovagunta","year":"2024","journal-title":"Adv. Colloid Interface Sci."},{"key":"2026100610484928200_cit40","doi-asserted-by":"publisher","first-page":"125215","DOI":"10.1016\/j.fuel.2022.125215","article-title":"Investigation\ninto the correlation between the chemical structure\nof lignin and its temperature-dependent pyrolytic product evolution","volume":"329","author":"Wang","year":"2022","journal-title":"SSRN Electronic Journal"},{"key":"2026100610484928200_cit41","doi-asserted-by":"publisher","first-page":"130518","DOI":"10.1016\/j.ijbiomac.2024.130518","article-title":"Exploring chemical reactions to enhance\nthermal and dispersion stability of kraft and organosolv lignin","volume":"264","author":"Izaguirre","year":"2024","journal-title":"Int. J. Biol. Macromol."},{"key":"2026100610484928200_cit42","doi-asserted-by":"publisher","first-page":"116","DOI":"10.1016\/j.jaap.2004.12.009","article-title":"Chemical characterization of residual lignins from eucalypt paper\npulps","volume":"74","author":"Ibarra","year":"2005","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"2026100610484928200_cit43","unstructured":"Felsner, M. L.\n          \n          Caracterizac\u0327a\u0303o\nde me\u0301is monoflorais de eucalipto e laranja do estado de Sa\u0303o\nPaulo por te\u0301cnicas termoanali\u0301ticas.\nPh.D. Thesis, Instituto de Qui\u0301mica de Universidade\nde Sa\u0303o Paulo, Sa\u0303o Paulo, 2001."},{"issue":"1","key":"2026100610484928200_cit44","doi-asserted-by":"publisher","first-page":"27","DOI":"10.1016\/j.joei.2017.12.003","article-title":"Comparative studies\non the pyrolysis of cellulose, hemicellulose, and lignin based on\ncombined kinetics","volume":"92","author":"Yeo","year":"2019","journal-title":"Journal of the Energy Institute"},{"issue":"4","key":"2026100610484928200_cit45","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1520\/JAI12795","article-title":"Separation\nof Overlapping Processes\nfrom TGA Data and Verification by EGA","volume":"2","author":"Artiaga","year":"2005","journal-title":"ASTM\nInt."},{"key":"2026100610484928200_cit46","doi-asserted-by":"crossref","unstructured":"Dodampola, R.; Perera, T.; Egodage, D.; Amarasinghe, S.; Attygalle, D.; Weragoda, S.\n          Identifying Better\nFitting Function for Asymmetric Differential Thermo Gravimetric Signal\nAnalysis.  2019 Moratuwa Engineering Research\nConference (MERCon); IEEE, Moratuwa, Sri Lanka, 2019; pp 84\u201389. 10.1109\/MERCon.2019.8818876.","DOI":"10.1109\/MERCon.2019.8818876"},{"issue":"2","key":"2026100610484928200_cit47","doi-asserted-by":"publisher","first-page":"3604","DOI":"10.15376\/biores.15.2.3604-3620","article-title":"Chemical and thermal characterizations\nof Pinus sylvestris and Pinus pinaster","volume":"15","author":"Mertoglu Elmas","year":"2020","journal-title":"Bio\nResources"},{"key":"2026100610484928200_cit48","doi-asserted-by":"publisher","first-page":"1333","DOI":"10.3390\/polym14071333","article-title":"Optimization of demineralization\nand pyrolysis performance of eucalyptus hydrothermal pretreatment","volume":"14","author":"Zhu","year":"2022","journal-title":"Polymers"},{"key":"2026100610484928200_cit49","doi-asserted-by":"publisher","first-page":"4289","DOI":"10.3390\/en18164289","article-title":"Impact of demineralization\non various types of biomass pyrolysis: behavior, kinetics, and thermodynamics","volume":"18","author":"Shen","year":"2025","journal-title":"Energies"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c04390","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/39\/59064\/68668709\/acsomega.6c04390.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/39\/59064\/68668709\/acsomega.6c04390.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T15:30:29Z","timestamp":1791300629000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/39\/59064\/5439479\/Linking-Chemical-Composition-to-Thermal"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,27]]},"references-count":49,"journal-issue":{"issue":"39","published-online":{"date-parts":[[2026,9,27]]},"published-print":{"date-parts":[[2026,10,6]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c04390","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,27]]}}}