{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T16:10:20Z","timestamp":1790698220944,"version":"4.1.0"},"reference-count":41,"publisher":"American Chemical Society (ACS)","issue":"38","license":[{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico","doi-asserted-by":"publisher","award":["303359\/2023-4"],"award-info":[{"award-number":["303359\/2023-4"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico","doi-asserted-by":"publisher","award":["407581\/2021-9"],"award-info":[{"award-number":["407581\/2021-9"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005672","name":"Funda??o de Apoio ao Desenvolvimento do Ensino, Ci?ncia e Tecnologia do Estado de Mato Grosso do Sul","doi-asserted-by":"publisher","award":["71\/032.955\/2022"],"award-info":[{"award-number":["71\/032.955\/2022"]}],"id":[{"id":"10.13039\/501100005672","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005672","name":"Funda??o de Apoio ao Desenvolvimento do Ensino, Ci?ncia e Tecnologia do Estado de Mato Grosso do Sul","doi-asserted-by":"publisher","award":["83\/022.625\/2023"],"award-info":[{"award-number":["83\/022.625\/2023"]}],"id":[{"id":"10.13039\/501100005672","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior","doi-asserted-by":"publisher","award":["001"],"award-info":[{"award-number":["001"]}],"id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The widespread use of pesticides in agricultural activities has increased concerns regarding environmental contamination and occupational exposure, particularly through dermal contact. In this work, we report a portable and low-cost electrochemical sensing platform for on-site monitoring of sulfentrazone (SFT), a herbicide extensively used in eucalyptus cultivation. The proposed device consists of a fully 3D-printed miniaturized electrochemical system fabricated by multi-material printing using conductive and non-conductive filaments, enabling accessible and decentralized analysis. SFT detection was performed by square-wave voltammetry (SWV), exhibiting a single irreversible oxidation peak at +0.86 V (pH 6.5). Under optimized conditions, the platform showed a linear response from 1.1 to 101.1 \u03bcmol L\u20131, with a limit of detection of 0.50 \u03bcmol L\u20131 (obtained through IUPAC recommendations). The proposed approach demonstrated satisfactory accuracy and precision in spiked tap water samples, with recoveries ranging from 100 to 103% and RSD values \u2264 2.9% (n = 3). Additionally, the platform was successfully applied to porcine skin samples as a model for detecting dermal contamination, yielding recoveries between 81 and 111%. The combination of additive manufacturing and electrochemical sensing provides a simple, reliable, and field-deployable strategy for SFT monitoring in environmental and biological matrices, highlighting the potential of fully 3D-printed analytical platforms for occupational and environmental applications.<\/jats:p>","DOI":"10.1021\/acsomega.6c05449","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T03:02:07Z","timestamp":1789527727000},"page":"57259-57268","source":"Crossref","is-referenced-by-count":0,"title":["On-Site Electrochemical\nDetection of Sulfentrazone\nUsing a Fully 3D-Printed Portable Sensing Platform"],"prefix":"10.1021","volume":"11","author":[{"given":"Jacqueline Marques","family":"Petroni","sequence":"first","affiliation":[{"name":"Federal University of Mato Grosso do Sul , , , ,","place":["Campo Grande, Mato Grosso do Sul, Brazil, 79074-460"]},{"name":"Industry Social Service Innovation Center , , , ,","place":["Campo Grande, Mato Grosso do Sul, Brazil, 79002-072"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonas Raul","family":"Balbinoti","sequence":"additional","affiliation":[{"name":"Industry Social Service Innovation Center , , , ,","place":["Campo Grande, Mato Grosso do Sul, Brazil, 79002-072"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elias","family":"Jorge","sequence":"additional","affiliation":[{"name":"Eldorado Brasil , , , ,","place":["Tre\u0302s Lagoas, Mato Grosso do Sul, Brazil, 79641-300"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Osvaldo Cavalcante da Costa","family":"Neto","sequence":"additional","affiliation":[{"name":"Eldorado Brasil , , , ,","place":["Tre\u0302s Lagoas, Mato Grosso do Sul, Brazil, 79641-300"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0210-5311","authenticated-orcid":true,"given":"Rodrigo","family":"Amorim Bezerra da Silva","sequence":"additional","affiliation":[{"name":"Federal University of Uberlandia , , , ,","place":["Uberlandia, Minas Gerais, Brazil, 38400-902"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4674-4809","authenticated-orcid":true,"given":"Magno Aparecido Gonc\u0327alves","family":"Trindade","sequence":"additional","affiliation":[{"name":"Federal University of Grande Dourados , , , ,","place":["Dourados, Mato Grosso do Sul, Brazil, 79804-970"]},{"name":"Universidade de Sa\u0303o Paulo , , , ,","place":["Sa\u0303o Paulo, Sa\u0303o Paulo, Brazil, 05508-900"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5782-6845","authenticated-orcid":true,"given":"Bruno Gabriel","family":"Lucca","sequence":"additional","affiliation":[{"name":"Federal University of Mato Grosso do Sul , , , ,","place":["Campo Grande, Mato Grosso do Sul, Brazil, 79074-460"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,15]]},"reference":[{"key":"2026092911084978500_cit1","doi-asserted-by":"publisher","first-page":"57","DOI":"10.1016\/S0065-2113(08)60253-9","article-title":"Herbicide resistance:\nimpact and management","volume":"58","author":"Powles","year":"1996","journal-title":"Adv. Agron."},{"key":"2026092911084978500_cit2","doi-asserted-by":"publisher","first-page":"108010","DOI":"10.1016\/j.plaphy.2023.108010","article-title":"Unveiling the efficacy\nof pre-emergent application\nof young Eucalyptus globulus leaves as a weed control strategy: Bridging\nmacroscopic effects and cellular responses","volume":"203","author":"Pinto","year":"2023","journal-title":"Plant Physiol. Biochem."},{"key":"2026092911084978500_cit3","doi-asserted-by":"publisher","first-page":"1751","DOI":"10.5935\/0103-5053.20150150","article-title":"New and\nsensitive electroquantification of sulfentrazone in soil by differential-pulse\nvoltammetry","volume":"26","author":"Catrinck","year":"2015","journal-title":"J. Braz. Chem. Soc."},{"key":"2026092911084978500_cit4","doi-asserted-by":"publisher","first-page":"884","DOI":"10.1016\/j.chemosphere.2010.08.003","article-title":"Electroanalytical studies of sulfentrazone in protic\nmedium, its degradation by the electro-Fenton process, and toxicity\nassessment using ss-DNA","volume":"81","author":"de A. Lima","year":"2010","journal-title":"Chemosphere"},{"key":"2026092911084978500_cit5","doi-asserted-by":"publisher","first-page":"56","DOI":"10.1016\/j.geoderma.2008.07.005","article-title":"The effects of moisture and temperature on the degradation\nof sulfentrazone","volume":"147","author":"Martinez","year":"2008","journal-title":"Geoderma"},{"key":"2026092911084978500_cit6","doi-asserted-by":"publisher","first-page":"879","DOI":"10.1016\/j.soilbio.2007.10.016","article-title":"Degradation\nof the herbicide sulfentrazone\nin a Brazilian Typic Hapludox soil","volume":"40","author":"Martinez","year":"2008","journal-title":"Soil Biol.\nBioche.m"},{"key":"2026092911084978500_cit7","doi-asserted-by":"publisher","DOI":"10.1590\/s0100-83582020380100032","article-title":"Sulfentrazone:\nEnvironmental dynamics\nand selectivity","volume":"38","author":"Gehrke","year":"2020","journal-title":"Planta Daninha"},{"key":"2026092911084978500_cit8","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1590\/S0100-83582014000200016","article-title":"Sorc\u0327a\u0303o\ndo sulfentrazone em diferentes tipos de solo determinada por bioensaios","volume":"32","author":"Freitas","year":"2014","journal-title":"Planta Daninha"},{"key":"2026092911084978500_cit9","doi-asserted-by":"publisher","first-page":"132632","DOI":"10.1016\/j.chemosphere.2021.132632","article-title":"Health risks of sulfentrazone\nexposure during zebrafish embryo-larvae development at environmental\nconcentration","volume":"288","author":"Jiang","year":"2022","journal-title":"Chemosphere"},{"key":"2026092911084978500_cit10","doi-asserted-by":"publisher","first-page":"1211","DOI":"10.1007\/s12665-015-4110-7","article-title":"Leaching of sulfentrazone in soils\nof reforestation in Brazil, Environ","volume":"74","author":"Passos","year":"2015","journal-title":"Earth Sci."},{"key":"2026092911084978500_cit11","doi-asserted-by":"publisher","first-page":"335","DOI":"10.3390\/toxics10060335","article-title":"Exposure\nroutes and health risks associated with pesticide application","volume":"10","author":"Tudi","year":"2022","journal-title":"Toxics"},{"key":"2026092911084978500_cit12","doi-asserted-by":"publisher","first-page":"801","DOI":"10.1289\/ehp.97105s4801","article-title":"Biomarkers\nof human exposure to pesticides","volume":"105","author":"Anwar","year":"1997","journal-title":"Environ. 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Silva","year":"2019","journal-title":"J. Electroanal. Chem. Interfacial Electrochem."},{"key":"2026092911084978500_cit27","doi-asserted-by":"publisher","first-page":"137215","DOI":"10.1016\/j.snb.2024.137215","article-title":"Sensitive,\nintegrated, mass-produced, portable and low-cost electrochemical 3D-printed\nsensing set (SIMPLE-3D-SenS): A promising analytical tool for forensic\napplications, Sens","volume":"427","author":"Conrado","year":"2025","journal-title":"Actuators B Chem."},{"key":"2026092911084978500_cit28","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1016\/j.aca.2020.03.028","article-title":"Additive-manufactured\n(3D-printed)\nelectrochemical sensors: A critical review, Anal","volume":"1118","author":"Cardoso","year":"2020","journal-title":"Chim. 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