{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T16:11:19Z","timestamp":1790093479235,"version":"4.0.1"},"reference-count":26,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004192","name":"National Science and Technology Development Agency","doi-asserted-by":"publisher","award":["B13F690027"],"award-info":[{"award-number":["B13F690027"]}],"id":[{"id":"10.13039\/501100004192","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002873","name":"Chulalongkorn University","doi-asserted-by":"publisher","award":["HEA_FF_69_190_6300_005"],"award-info":[{"award-number":["HEA_FF_69_190_6300_005"]}],"id":[{"id":"10.13039\/501100002873","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,22]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>This work reports the development of photocurable hybrid resins based on methacrylated vanillin (MV) and glycidyl methacrylate-functionalized poly(\u03b5-caprolactone) (PCL-GMA) for high-resolution light-assisted 3D printing. FTIR and 1H NMR analyses confirmed successful methacrylation of vanillin and methacrylate end-group incorporation into PCL\u2013GMA, ensuring efficient photopolymerization. Systematic variation of MV\/PCL ratios enabled precise control over resin behavior. Cure-depth studies showed that increasing MV content somewhat enhanced photoreactivity. Notably, rheological measurements revealed low viscosities suitable for light-assisted 3D printing, decreasing from 1.55 Pa\u00b7s at low MV to 0.10 Pa\u00b7s in the MV: PEG system. The 3D-printed specimens exhibited excellent dimensional fidelity, with dimensional errors of 2\u20133% for cylindrical parts and only 1.17% in height and 1.21% in width for porous diamond lattices. TGA indicated increased thermal stability with higher MV incorporation, while mechanical testing showed significant improvements in modulus and compressive strength across the MV-rich formulations. Taken together, MV\/PCL hybrid resins constitute a versatile, low-error, and biocompatible platform for precision liquid crystal display (LCD) based fabrication.<\/jats:p>","DOI":"10.1021\/acsomega.6c05571","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T06:01:57Z","timestamp":1788760917000},"page":"55878-55887","source":"Crossref","is-referenced-by-count":0,"title":["Photocurable Vanillin-Derived\nHybrid Methacrylate\nResins with Tunable Properties for High-Resolution Light-Assisted\n3D Printing"],"prefix":"10.1021","volume":"11","author":[{"given":"Nuttapol","family":"Risangud","sequence":"first","affiliation":[{"name":"Chulalongkorn University , , ,","place":["Bangkok, Thailand, 10330"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jittima","family":"Mama","sequence":"additional","affiliation":[{"name":"National Nanotechnology Center (NANOTEC) , , 111 Thailand Science Park, Phahonyothin Road, Klong Luang , ,","place":["Pathum Thani, Thailand, 12120"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Phichanat","family":"Iumsriwan","sequence":"additional","affiliation":[{"name":"National Nanotechnology Center (NANOTEC) , , 111 Thailand Science Park, Phahonyothin Road, Klong Luang , ,","place":["Pathum Thani, Thailand, 12120"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rattanawadee","family":"Srioanchan","sequence":"additional","affiliation":[{"name":"National Nanotechnology Center (NANOTEC) , , 111 Thailand Science Park, Phahonyothin Road, Klong Luang , ,","place":["Pathum Thani, Thailand, 12120"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chutidech","family":"Thongdeelerd","sequence":"additional","affiliation":[{"name":"National Nanotechnology Center (NANOTEC) , , 111 Thailand Science Park, Phahonyothin Road, Klong Luang , ,","place":["Pathum Thani, Thailand, 12120"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tule","family":"Sirikitputtisak","sequence":"additional","affiliation":[{"name":"Prince of Songkla University , , Surat Thani Campus , ,","place":["Surat Thani, Thailand, 84000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9938-6788","authenticated-orcid":true,"given":"Somprasong","family":"Thongkham","sequence":"additional","affiliation":[{"name":"National Nanotechnology Center (NANOTEC) , , 111 Thailand Science Park, Phahonyothin Road, Klong Luang , ,","place":["Pathum Thani, Thailand, 12120"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"2026092210564460700_cit1","doi-asserted-by":"publisher","first-page":"1234340","DOI":"10.3389\/fbioe.2023.1234340","article-title":"Biomaterials-based\nadditive manufacturing for customized bioengineering in management\nof otolaryngology: a comprehensive review","volume":"11","author":"Vyas","year":"2023","journal-title":"Front.\nBioeng. 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Manuf."},{"key":"2026092210564460700_cit4","doi-asserted-by":"publisher","first-page":"36398","DOI":"10.1039\/D1RA04060J","article-title":"Additive manufacturing\ntechnology\nof polymeric materials for customized products: recent developments\nand future prospective","volume":"11","author":"Pal","year":"2021","journal-title":"RSC Adv."},{"key":"2026092210564460700_cit5","doi-asserted-by":"publisher","first-page":"119508","DOI":"10.1016\/j.carbpol.2022.119508","article-title":"Digital light processing-based 3D\nbioprinting of \u03ba-carrageenan hydrogels for engineering cell-loaded\ntissue scaffolds","volume":"290","author":"Kumari","year":"2022","journal-title":"Carbohydr. Polym."},{"key":"2026092210564460700_cit6","doi-asserted-by":"publisher","first-page":"100171","DOI":"10.1016\/j.jcomc.2021.100171","article-title":"Reinforcement\nability of lignocellulosic components in biocomposites and their 3D\nprinted applications \u2013 A review","volume":"6","author":"Zarna","year":"2021","journal-title":"Compos.,\nPart C: Open Access"},{"key":"2026092210564460700_cit7","doi-asserted-by":"publisher","first-page":"115970","DOI":"10.1016\/j.carbpol.2020.115970","article-title":"DLP printing photocurable\nchitosan to build bio-constructs for tissue engineering","volume":"235","author":"Shen","year":"2020","journal-title":"Carbohydr. Polym."},{"key":"2026092210564460700_cit8","doi-asserted-by":"publisher","first-page":"6863","DOI":"10.1039\/D1GC01489G","article-title":"Sustainable advances\nin SLA\/DLP 3D printing materials and processes","volume":"23","author":"Maines","year":"2021","journal-title":"Green Chem."},{"key":"2026092210564460700_cit9","doi-asserted-by":"publisher","first-page":"284","DOI":"10.1039\/D3LP00207A","article-title":"Synthesis of bio-sourced\nliquid resins and their photopolymerization with poly(ethylene glycol)\ndiacrylate in the roadmap to more sustainable digital light processing\ntechnologies","volume":"2","author":"Hoda\u0301sova\u0301","year":"2024","journal-title":"RSC Appl. 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Sci."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c05571","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/37\/55878\/68398558\/acsomega.6c05571.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/37\/55878\/68398558\/acsomega.6c05571.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T15:44:14Z","timestamp":1790091854000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/37\/55878\/5422056\/Photocurable-Vanillin-Derived-Hybrid-Methacrylate"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,7]]},"references-count":26,"journal-issue":{"issue":"37","published-online":{"date-parts":[[2026,9,7]]},"published-print":{"date-parts":[[2026,9,22]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c05571","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,7]]}}}