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In this study, ELO was synthesized via the Shi epoxidation approach and subsequently cured with either methyltetrahydrophthalic anhydride (ELO-AD) or a fatty amine agent (ELO-AM). Although epoxy\u2013amine reactions exhibit lower activation energies (19\u201326 kJ\u00b7mol\u20131) than the epoxy\u2013anhydride system (40\u201345 kJ\u00b7mol\u20131), the overall curing efficiency is governed by vitrification and diffusion constraints rather than intrinsic chemical reactivity. The anhydride-cured system forms a dense network with higher glass transition temperature (Tg = 46\u201394 \u00b0C), higher cross-link density (\u03c5 = 1.19 \u00d7 103 mol\u00b7m\u20133), and gel content (97.95 \u00b1 0.16%) together with rapid viscosity growth (k\u03b7 up to 0.83 min\u20131 at 140 \u00b0C), resulting in shorter characteristic times in time\u2013temperature\u2013transformation (TTT) diagrams. The amine-cured system forms a more flexible, lower Tg (\u221210 to 19 \u00b0C) network with lower \u03c5 (4.77 \u00d7 102 mol\u00b7m\u20133), and gel content (79.87 \u00b1 4.45%), consistent with a less interconnected netword and greater diffusion limitations at advanced conversion. These structural and kinetic differences translate directly into macroscopic performance. ELO-AD exhibits superior Young\u2019s modulus and strength (2.0 GPa and \u2248 46 MPa, respectively), whereas ELO-AM shows enhanced ductility (strain at break \u2248 26%) and higher thermal stability (DTG peak \u2248 485 \u00b0C). Overall, this study establishes quantitative structure\u2013process\u2013property relationships for ELO-based epoxy systems, with practical guidelines for selecting curing agents and processing windows for sustainable thermoset resins.<\/jats:p>","DOI":"10.1021\/acsomega.6c05665","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T04:02:07Z","timestamp":1790049727000},"page":"59463-59479","source":"Crossref","is-referenced-by-count":0,"title":["Vitrification-Controlled\nCuring of Epoxidized Linseed\nOil Resins: Kinetics, TTT Analysis, and Thermomechanical Performance\nwith Anhydride and Amine Curing Agents"],"prefix":"10.1021","volume":"11","author":[{"given":"Cristiane da Silva","family":"Fonseca","sequence":"first","affiliation":[{"name":"Federal University of Rio Grande do Sul , , Avenida Bento Gonc\u0327alves 9500 , ,","place":["Porto Alegre, Brazil, 91501-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mauri\u0301cio Carpe Diem Ferreira","family":"Xavier","sequence":"additional","affiliation":[{"name":"Federal University of Rio Grande do Sul , , Avenida Bento Gonc\u0327alves 9500 , ,","place":["Porto Alegre, Brazil, 91501-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7493-8163","authenticated-orcid":true,"given":"Ota\u0301vio","family":"Bianchi","sequence":"additional","affiliation":[{"name":"Federal University of Rio Grande do Sul , , Avenida Bento Gonc\u0327alves 9500 , ,","place":["Porto Alegre, Brazil, 91501-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandro Campos","family":"Amico","sequence":"additional","affiliation":[{"name":"Federal University of Rio Grande do Sul , , Avenida Bento Gonc\u0327alves 9500 , ,","place":["Porto Alegre, Brazil, 91501-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cesar","family":"Liberato Petzhold","sequence":"additional","affiliation":[{"name":"Federal University of Rio Grande do Sul , , Avenida Bento Gonc\u0327alves 9500 , ,","place":["Porto Alegre, Brazil, 91501-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,21]]},"reference":[{"issue":"3","key":"2026100610475944500_cit1","doi-asserted-by":"publisher","first-page":"133","DOI":"10.1080\/03602559.2016.1253742","article-title":"Recent Development\nof Biobased Epoxy Resins: A Review","volume":"57","author":"Kumar","year":"2018","journal-title":"Polym. -\nPlast. 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