{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T12:12:59Z","timestamp":1788437579719,"version":"build-2803163510"},"reference-count":79,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient??fico e Tecnol??gico","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004586","name":"Funda????o Carlos Chagas Filho de Amparo ls Pesquisa do Estado do Rio de Janeiro","doi-asserted-by":"publisher","award":["APQ1 SEI-260003\/006121\/2024 - E-26\/210.784\/2024"],"award-info":[{"award-number":["APQ1 SEI-260003\/006121\/2024 - E-26\/210.784\/2024"]}],"id":[{"id":"10.13039\/501100004586","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004586","name":"Funda????o Carlos Chagas Filho de Amparo ls Pesquisa do Estado do Rio de Janeiro","doi-asserted-by":"publisher","award":["E-26\/201.814\/2025"],"award-info":[{"award-number":["E-26\/201.814\/2025"]}],"id":[{"id":"10.13039\/501100004586","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Corrosive processes are responsible for direct and indirect costs in industrial systems, which can be mitigated by corrosion inhibitors. The awareness of environmental risks has motivated sustainable approaches, such as naturally derived biopolymers, due to low toxicity and inhibition potential. \u03bb-carrageenan, a sulfated biopolymer obtained from red algae, is explored in this work as an environmentally benign corrosion inhibitor. Gravimetric analyses indicate that the addition of 1500 ppm of \u03bb-carrageenan markedly decreases the corrosion rate of mild steel, yielding inhibition efficiencies of 87.1% at 303 K and 72.0% at 333 K. Electrochemical techniques were employed under static conditions (0 rpm) and under hydrodynamic conditions at 500 and 1500 rpm to mimic flowing conditions expected in transport pipelines, achieving 89.8% at 500 rpm. Density functional theory calculations demonstrated that both the neutral and protonated forms of \u03bb-carrageenan exhibit favorable electronic properties, with electron density distributed across hydroxyl and sulfate functionalities that promote interaction with the steel surface. Molecular dynamics simulations further confirmed the spontaneous adsorption onto the iron substrate at 1500 ppm, with interaction energies ranging from \u2212158 to \u2212179 kcal\/mol across the investigated temperature interval. The protective layer, enabled by multiple adsorption sites involving SO3H and OH groups, accounts for the high inhibition performance. Overall, the results support \u03bb-carrageenan as a viable green inhibitor capable of providing effective protection in industrial environments.<\/jats:p>","DOI":"10.1021\/acsomega.6c05701","type":"journal-article","created":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T06:02:12Z","timestamp":1786946532000},"page":"51589-51606","source":"Crossref","is-referenced-by-count":0,"title":["From Seaweed to Corrosion Inhibitor: A Multi-Method\nValidation of \u03bb-Carrageenan as a Non-Toxic Inhibitor\nunder Acidic Hydrodynamic Conditions"],"prefix":"10.1021","volume":"11","author":[{"given":"Ana Fla\u0301via Martins","family":"Rodrigues","sequence":"first","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Athos da Silveira Ramos, 149, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-909"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Larissa Caruso da","family":"Eira","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Athos da Silveira Ramos, 149, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-909"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5958-3552","authenticated-orcid":true,"given":"Fa\u0301bio","family":"Jr Ferreira da Silva Henrique","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro , , Av. Athos da Silveira Ramos, 149, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-909"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eduardo Alencar de","family":"Souza","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Hora\u0301cio Macedo, 2030, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-914"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rodrigo da","family":"Silva","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Hora\u0301cio Macedo, 2030, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-914"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juliana Oliveira","family":"Pereira","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Hora\u0301cio Macedo, 2030, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-914"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria Jose\u0301 O. C.","family":"Guimara\u0303es","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Athos da Silveira Ramos, 149, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-909"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jose\u0301 Anto\u0302nio da Cunha","family":"Ponciano Gomes","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Hora\u0301cio Macedo, 2030, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-914"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9882-3037","authenticated-orcid":true,"given":"Luana Barros","family":"Furtado","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio de Janeiro (UFRJ) , , Av. Athos da Silveira Ramos, 149, Cidade Universita\u0301ria , , ,","place":["Rio de Janeiro, RJ, Brasil, 21941-909"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,17]]},"reference":[{"key":"2026090307172380500_cit1","doi-asserted-by":"publisher","first-page":"867","DOI":"10.1016\/j.molliq.2018.11.095","article-title":"Biopolymer dextrin\nand poly (vinyl acetate) based graft copolymer as an efficient corrosion\ninhibitor for mild steel in hydrochloric acid: Electrochemical, surface\nmorphological and theoretical studies","volume":"275","author":"Biswas","year":"2019","journal-title":"J. Mol.\nLiq."},{"key":"2026090307172380500_cit2","doi-asserted-by":"publisher","first-page":"661","DOI":"10.1016\/j.corsci.2009.10.026","article-title":"The effects of Aloe vera extract on corrosion and kinetics\nof corrosion process of zinc in HCl solution","volume":"52","author":"Abiola","year":"2010","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit3","doi-asserted-by":"publisher","first-page":"113","DOI":"10.1016\/j.matlet.2007.04.079","article-title":"Natural\nproducts as corrosion inhibitor for metals\nin corrosive media - A review","volume":"62","author":"Raja","year":"2008","journal-title":"Mater. Lett."},{"key":"2026090307172380500_cit4","unstructured":"El-Enin, S. A. A.; Amin, A.\n          Review of Corrosion\nInhibitors for Industrial Applications. www.researchpublish.com."},{"key":"2026090307172380500_cit5","doi-asserted-by":"publisher","first-page":"1746","DOI":"10.1021\/acssuschemeng.5b01725","article-title":"Synergistic\nCorrosion Inhibition of Mild Steel in Aqueous Chloride Solutions by\nan Imidazolinium Carboxylate Salt","volume":"4","author":"Chong","year":"2016","journal-title":"ACS Sustainable\nChem. Eng."},{"key":"2026090307172380500_cit6","doi-asserted-by":"publisher","first-page":"407","DOI":"10.1016\/j.aiepr.2023.04.005","article-title":"Biodegradable synthetic\npolymers in sustainable corrosion protection: Present and future scenarios","volume":"6","author":"Verma","year":"2023","journal-title":"Adv. Ind. Eng. Polym. Res."},{"key":"2026090307172380500_cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2024.137461","article-title":"Development of pH-sensitive chitosan\/plant extract\nmicrocapsules: Enhanced corrosion protection for carbon steel in HCl\nsolution","volume":"282","author":"Wang","year":"2024","journal-title":"Int. J. Biol. Macromol."},{"key":"2026090307172380500_cit8","doi-asserted-by":"publisher","first-page":"1013","DOI":"10.48317\/IMIST.PRSM\/morjchem-v11i04.41618","article-title":"Alocasia Odora Extract\nas Environmentally Benign Corrosion\nInhibitor for Aluminum in HCl","volume":"11","author":"Haque","year":"2023","journal-title":"Moroccan J. Chem."},{"key":"2026090307172380500_cit9","doi-asserted-by":"publisher","first-page":"11954","DOI":"10.1021\/ie201450d","article-title":"Inhibitive\nEffect of Argemone mexicana Plant Extract on Acid Corrosion of Mild\nSteel","volume":"50","author":"Ji","year":"2011","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026090307172380500_cit10","doi-asserted-by":"publisher","first-page":"2848","DOI":"10.1016\/j.corsci.2009.08.016","article-title":"Corrosion\ninhibition by Justicia gendarussa plant extract in hydrochloric acid\nsolution","volume":"51","author":"Satapathy","year":"2009","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit11","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2024.112751","article-title":"Adsorption\nand corrosion inhibition ability of avocado seed (Persea americana)\nextract for copper corrosion in 0.5 M H2SO4 solution","volume":"167","author":"S\u0327ahin","year":"2024","journal-title":"Inorg. Chem. Commun."},{"key":"2026090307172380500_cit12","doi-asserted-by":"publisher","first-page":"1143","DOI":"10.1016\/S1005-0302(12)60010-3","article-title":"Seed Extract\nof Psidium guajava as\nEcofriendly Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid\nMedium","volume":"27","author":"Kumar","year":"2011","journal-title":"J. Mater. Sci. Technol."},{"key":"2026090307172380500_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2024.129220","article-title":"Corrosion inhibition\nactivity of a natural polysaccharide from Dysosma versipellis using\ntailor-made deep eutectic solvents","volume":"268","author":"Luo","year":"2024","journal-title":"Int. J.\nBiol. Macromol."},{"key":"2026090307172380500_cit14","doi-asserted-by":"publisher","first-page":"173","DOI":"10.1016\/j.apsusc.2015.06.128","article-title":"Experimental\nand theoretical studies of xanthan gum\nand its graft co-polymer as corrosion inhibitor for mild steel in\n15% HCl","volume":"353","author":"Biswas","year":"2015","journal-title":"Appl. Surf. Sci."},{"key":"2026090307172380500_cit15","doi-asserted-by":"publisher","first-page":"35","DOI":"10.1016\/j.corsci.2012.02.009","article-title":"Chemically modified natural polysaccharide\nas green corrosion inhibitor for mild steel in acidic medium","volume":"59","author":"Banerjee","year":"2012","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit16","doi-asserted-by":"publisher","first-page":"223","DOI":"10.1016\/j.corsci.2012.08.018","article-title":"Corrosion\ninhibition of iota-carrageenan\nnatural polymer on aluminum in presence of zwitterion mediator in\nHCl media","volume":"65","author":"Fares","year":"2012","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2025.142750","article-title":"Synthesis and evaluation\nof anionic guar gum derivatives\nas dual-function inhibitors for methane hydrate formation and metal\ncorrosion in oil and gas pipelines","volume":"309","author":"Wan","year":"2025","journal-title":"Int. J.\nBiol. Macromol."},{"key":"2026090307172380500_cit18","doi-asserted-by":"publisher","first-page":"246","DOI":"10.1016\/j.corsci.2014.07.039","article-title":"Corrosion inhibition\nof mild steel in acidic medium by polyacrylamide grafted Guar gum\nwith various grafting percentage: Effect of intramolecular synergism","volume":"88","author":"Roy","year":"2014","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2019.108346","article-title":"Two novel chitosan derivatives as\nhigh efficient eco-friendly\ninhibitors for the corrosion of mild steel in acidic solution","volume":"164","author":"Zhang","year":"2020","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit20","doi-asserted-by":"publisher","first-page":"192","DOI":"10.1016\/j.corsci.2014.12.002","article-title":"Corrosion\ninhibition\nof mild steel in HCL solution by pectin","volume":"92","author":"Fiori-Bimbi","year":"2015","journal-title":"Corros.\nSci."},{"key":"2026090307172380500_cit21","doi-asserted-by":"publisher","first-page":"104535","DOI":"10.1039\/C5RA20340F","article-title":"Alginate\nsurfactant derivatives as an ecofriendly corrosion inhibitor for carbon\nsteel in acidic environments","volume":"5","author":"Tawfik","year":"2015","journal-title":"RSC Adv."},{"key":"2026090307172380500_cit22","doi-asserted-by":"publisher","first-page":"303","DOI":"10.1016\/j.jiec.2023.02.031","article-title":"Biopolymer sodium alginate\nbased titania and magnetite nanocomposites as natural corrosion inhibitors\nfor mild steel in acidic medium","volume":"122","author":"Kesari","year":"2023","journal-title":"J. Ind. Eng.\nChem."},{"key":"2026090307172380500_cit23","first-page":"245","article-title":"Carrageenan","volume-title":"Biopolymers","author":"van de Velde","year":"2002"},{"key":"2026090307172380500_cit24","doi-asserted-by":"publisher","first-page":"167","DOI":"10.1016\/j.carbpol.2009.01.020","article-title":"Carrageenans: Biological\nproperties, chemical modifications and structural analysis - A review","volume":"77","author":"Campo","year":"2009","journal-title":"Carbohydr. Polym."},{"key":"2026090307172380500_cit25","doi-asserted-by":"publisher","first-page":"389","DOI":"10.1016\/S0924-2244(97)01091-1","article-title":"Carrageenan biotechnology","volume":"8","author":"De Ruiter","year":"1997","journal-title":"Trends Food Sci. Technol."},{"key":"2026090307172380500_cit26","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2025.120587","article-title":"Mittal, Synthesis and characterization\nof \u03ba-carrageenan and guar gum-based hydrogels for controlled\nrelease fertilizers: Optimization, release kinetics, and agricultural\nimpact","volume":"225","author":"Nandal","year":"2025","journal-title":"Ind. Crops Prod."},{"key":"2026090307172380500_cit27","doi-asserted-by":"publisher","first-page":"269","DOI":"10.1016\/s0144-8617(96)00031-8","article-title":"Composition\nof carrageenan\nblends inferred from 13C-NMR and infrared spectroscopic analysis","volume":"31","author":"Turquois","year":"1996","journal-title":"Carbohydr. Polym."},{"key":"2026090307172380500_cit28","doi-asserted-by":"publisher","first-page":"8631","DOI":"10.1021\/acssuschemeng.2c02374","article-title":"Carrageenan-Based\nHybrid Materials\nwith Ionic Liquids for Sustainable and Recyclable Printable Pressure\nSensors","volume":"10","author":"Serra","year":"2022","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026090307172380500_cit29","doi-asserted-by":"publisher","first-page":"280","DOI":"10.1016\/j.carbpol.2015.02.036","article-title":"Performance evaluation\nof pectin as ecofriendly corrosion inhibitor for X60 pipeline steel\nin acid medium: Experimental and theoretical approaches","volume":"124","author":"Umoren","year":"2015","journal-title":"Carbohydr. Polym."},{"key":"2026090307172380500_cit30","doi-asserted-by":"publisher","first-page":"901","DOI":"10.1016\/j.carbpol.2012.06.018","article-title":"Synthesis\nof graft copolymer (CgOH-g-AGA): Physicochemical properties, characterization\nand application","volume":"90","author":"Sand","year":"2012","journal-title":"Carbohydr. Polym."},{"key":"2026090307172380500_cit31","doi-asserted-by":"publisher","first-page":"524","DOI":"10.1016\/j.carbpol.2007.06.021","article-title":"Synthesis\nof graft copolymer (k-carrageenan-g-N,N-dimethylacrylamide)\nand studies of metal ion uptake, swelling capacity and flocculation\nproperties","volume":"71","author":"Mishra","year":"2008","journal-title":"Carbohydr. Polym."},{"key":"2026090307172380500_cit32","doi-asserted-by":"publisher","DOI":"10.3390\/gels8110752","article-title":"Gelling Power Alteration on Kappa-Carrageenan\nDispersion\nthrough Esterification Method with Different Fatty Acid Saturation","volume":"8","author":"Wardhana","year":"2022","journal-title":"Gels"},{"key":"2026090307172380500_cit33","doi-asserted-by":"publisher","first-page":"340","DOI":"10.1016\/j.molstruc.2018.12.030","article-title":"Experimental, DFT and molecular dynamics\nsimulation on the inhibition performance of the DGDCBA epoxy polymer\nagainst the corrosion of the E24 carbon steel in 1.0\u202fM HCl\nsolution","volume":"1182","author":"Hsissou","year":"2019","journal-title":"J. Mol. Struct."},{"key":"2026090307172380500_cit34","doi-asserted-by":"publisher","first-page":"393","DOI":"10.1016\/j.molliq.2019.02.083","article-title":"Eco-friendly\ncorrosion inhibitors based on Cashew nut shell liquid (CNSL) for acidizing\nfluids","volume":"284","author":"Furtado","year":"2019","journal-title":"J. Mol. Liq."},{"key":"2026090307172380500_cit35","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2024.125132","article-title":"Cashew\nnut shell liquid (CNSL) residue\nas a greener corrosion inhibitor: Experimental and DFT studies of\nintensifier effect","volume":"406","author":"Furtado","year":"2024","journal-title":"J. Mol. Liq."},{"key":"2026090307172380500_cit36","doi-asserted-by":"publisher","first-page":"S3358","DOI":"10.1016\/J.ARABJC.2014.01.016","article-title":"Corrosion\ninhibition, adsorption\nand thermodynamic properties of poly(vinyl alcohol-cysteine) in molar\nHCl","volume":"10","author":"Rahiman","year":"2017","journal-title":"Arabian J. Chem."},{"key":"2026090307172380500_cit37","doi-asserted-by":"publisher","DOI":"10.3390\/polym15040891","article-title":"Experimental\nand\nComputational Exploration of Chitin, Pectin, and Amylopectin Polymers\nas Efficient Eco-Friendly Corrosion Inhibitors for Mild Steel in an\nAcidic Environment. Kinetic, Thermodynamic, and Mechanistic Aspects","volume":"15","author":"Fawzy","year":"2023","journal-title":"Polymers"},{"key":"2026090307172380500_cit38","doi-asserted-by":"publisher","DOI":"10.3390\/polym15143144","article-title":"Unraveling the Adsorption Mechanism and Anti-Corrosion Functionality\nof Dextrin and Inulin as Eco-Friendly Biopolymers for the Corrosion\nof Reinforced Steel in 1.0 M HCl: A Thermodynamic and Kinetic Approach","volume":"15","author":"Toghan","year":"2023","journal-title":"Polymers"},{"key":"2026090307172380500_cit39","doi-asserted-by":"publisher","first-page":"121","DOI":"10.1007\/s00289-020-03491-y","article-title":"An eco-friendly\ngreen biopolymer blend for copper corrosion inhibition","volume":"79","author":"Nair","year":"2022","journal-title":"Polym. Bull."},{"key":"2026090307172380500_cit40","doi-asserted-by":"publisher","DOI":"10.3390\/met12101598","article-title":"Adsorption Mechanism\nof Eco-Friendly Corrosion Inhibitors for Exceptional Corrosion Protection\nof Carbon Steel: Electrochemical and First-Principles DFT Evaluations","volume":"12","author":"Chaouiki","year":"2022","journal-title":"Metals"},{"key":"2026090307172380500_cit41","doi-asserted-by":"publisher","first-page":"182","DOI":"10.1016\/j.corsci.2019.04.040","article-title":"Determining Gibbs energies of adsorption\nfrom corrosion inhibition efficiencies: Is it a reliable approach?","volume":"155","author":"Walczak","year":"2019","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit42","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2021.109939","article-title":"Corrosion\ninhibitors: physisorbed or chemisorbed?","volume":"196","author":"Kokalj","year":"2022","journal-title":"Corros.\nSci."},{"key":"2026090307172380500_cit43","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2023.111139","article-title":"On the estimation\nof standard adsorption free energy from corrosion inhibition efficiencies","volume":"217","author":"Kokalj","year":"2023","journal-title":"Corros. Sci."},{"key":"2026090307172380500_cit44","doi-asserted-by":"publisher","first-page":"27057","DOI":"10.1021\/acsomega.0c02345","article-title":"Comparative\nstudies\nof the corrosion inhibition efficacy of a dicationic monomer and its\npolymer against API X60 steel corrosion in simulated acidizing fluid\nunder static and hydrodynamic conditions","volume":"5","author":"Odewunmi","year":"2020","journal-title":"ACS\nOmega"},{"key":"2026090307172380500_cit45","doi-asserted-by":"publisher","first-page":"162","DOI":"10.1016\/j.electacta.2008.08.024","article-title":"Effect of hydrodynamic conditions on the inhibition\nperformance of l-methionine as a \u201cgreen\u201d inhibitor","volume":"54","author":"Ashassi-Sorkhabi","year":"2008","journal-title":"Electrochim. Acta"},{"key":"2026090307172380500_cit46","doi-asserted-by":"publisher","DOI":"10.1016\/j.petrol.2019.106801","article-title":"Effect\nof akyl chain length, flow, and temperature on the corrosion inhibition\nof carbon steel in a simulated acidizing environment by an imidazoline-based\ninhibitor","volume":"187","author":"Solomon","year":"2020","journal-title":"J. Pet. Sci. Eng."},{"key":"2026090307172380500_cit47","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2023.128798","article-title":"Long chain imidazole\nderivative as a novel corrosion inhibitor for\nQ235 steel in 15% HCl medium under hydrodynamic condition: Experimental\nand theoretical examinations","volume":"313","author":"Singh","year":"2024","journal-title":"Mater. Chem. Phys."},{"key":"2026090307172380500_cit48","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcomm.2022.104110","article-title":"Inhibitive\nperformance of novel\/eco-friendly pyrimidine\nderivative for Q235 steel protection in 15% HCl under hydrodynamic\ncondition: Combination of experimental, surface and computational\napproach","volume":"32","author":"Singh","year":"2022","journal-title":"Mater. Today Commun."},{"key":"2026090307172380500_cit49","doi-asserted-by":"publisher","first-page":"232","DOI":"10.1016\/j.sajce.2022.10.006","article-title":"Inhibition\nof low carbon steel corrosion by a cationic gemini surfactant in 10wt.%\nH2SO4 and 15wt.% HCl under static condition and hydrodynamic flow","volume":"43","author":"Mu\u2019azu","year":"2023","journal-title":"S. Afr. J. Chem. Eng."},{"key":"2026090307172380500_cit50","doi-asserted-by":"publisher","first-page":"175","DOI":"10.1016\/j.jiec.2025.04.049","article-title":"Biomolecules-modified\ncarbon dots\nfor enhanced surface and interface properties and sustainable corrosion\nprotection: Experimental and computational studies","volume":"152","author":"Aslam","year":"2025","journal-title":"J. Ind. Eng. Chem."},{"key":"2026090307172380500_cit51","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2022.116183","article-title":"Rosemary extract inhibitive behavior\nagainst mild steel\ncorrosion in tempered 1 M HCl media","volume":"193","author":"Dehghani","year":"2023","journal-title":"Ind. Crops\nProd."},{"key":"2026090307172380500_cit52","doi-asserted-by":"publisher","first-page":"27799","DOI":"10.1007\/s13399-022-03581-z","article-title":"Apple pomace\nextract: a potent renewable source of active biomolecules for suppressing\nmild steel aggression in aquatic solution","volume":"14","author":"Ghahremani","year":"2024","journal-title":"Biomass\nConvers. Biorefin."},{"key":"2026090307172380500_cit53","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2023.116952","article-title":"Nigella sativa\nextract phytochemicals: Effective green\/bio-active anti-corrosion\nagent for steel protection in saline media","volume":"202","author":"Hosseini","year":"2023","journal-title":"Ind. Crops Prod."},{"key":"2026090307172380500_cit54","doi-asserted-by":"publisher","DOI":"10.1016\/j.petrol.2022.110401","article-title":"Effects of temperature,\nconcentration and synergism on green Schiff bases synthesized from\nvanillin in applications as corrosion inhibitors for carbon steel\nin well stimulation","volume":"213","author":"Furtado","year":"2022","journal-title":"J. Pet. Sci. Eng."},{"key":"2026090307172380500_cit55","doi-asserted-by":"publisher","DOI":"10.1016\/j.scp.2020.100353","article-title":"Cleaner corrosion\ninhibitors using Peumus boldus Molina formulations in oil well acidizing\nfluids: gravimetric, electrochemical and DFT studies","volume":"19","author":"Furtado","year":"2021","journal-title":"Sustainable Chem. Pharm."},{"key":"2026090307172380500_cit56","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2021.115782","article-title":"Corrosion\ninhibition properties of small peptides:\nDFT and Monte Carlo simulation studies","volume":"331","author":"Kasprzhitskii","year":"2021","journal-title":"J. Mol.\nLiq."},{"key":"2026090307172380500_cit57","doi-asserted-by":"publisher","first-page":"9978","DOI":"10.1021\/acsomega.2c07185","article-title":"DFT Study on Corrosion Inhibition\nby Tetrazole Derivatives: Investigation of the Substitution Effect","volume":"8","author":"Esmaeilzadeh Khabazi","year":"2023","journal-title":"ACS Omega"},{"key":"2026090307172380500_cit58","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2025.128773","article-title":"Hybrid TiO2\u2013polymer composites for corrosion\nprotection: a combined gravimetric, DFT, and molecular docking approach","volume":"438","author":"Masroor","year":"2025","journal-title":"J. Mol. Liq."},{"key":"2026090307172380500_cit59","doi-asserted-by":"publisher","first-page":"3997","DOI":"10.1021\/acsomega.7b00436","article-title":"Biopolymer from\nTragacanth Gum as a Green Corrosion Inhibitor for Carbon Steel in\n1 M HCl Solution","volume":"2","author":"Mobin","year":"2017","journal-title":"ACS Omega"},{"key":"2026090307172380500_cit60","doi-asserted-by":"publisher","first-page":"1052","DOI":"10.1016\/j.jcis.2023.02.141","article-title":"Chitosan derivatives\nas promising green corrosion inhibitors for carbon steel in acidic\nenvironment: Inhibition performance and interfacial adsorption mechanism","volume":"640","author":"Zhang","year":"2023","journal-title":"J. Colloid Interface Sci."},{"key":"2026090307172380500_cit61","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbpol.2025.124022","article-title":"Innovative\ndual-functional, green\nand biodegradable dicarboxylated inulin as scale and corrosion inhibitors\nfor sustainable oil and gas operations","volume":"367","author":"Ganie","year":"2025","journal-title":"Carbohydr.\nPolym."},{"key":"2026090307172380500_cit62","doi-asserted-by":"publisher","DOI":"10.1016\/j.jtice.2025.106225","article-title":"Biopolymer Xylan as a novel green corrosion inhibitor\nfor AISI 5140 steel and copper in H2SO4 medium","volume":"174","author":"Jomy","year":"2025","journal-title":"J. Taiwan Inst. Chem. Eng."},{"key":"2026090307172380500_cit63","unstructured":"ASTM.\n          . ASTM G31: Guide for Laboratory Immersion\nCorrosion Testing of Metals. 202110.1520\/G0031-21."},{"key":"2026090307172380500_cit64","doi-asserted-by":"publisher","DOI":"10.1016\/j.nexres.2025.100702","article-title":"Sulfamezarine\nderivatives as potential\ncorrosion inhibitors for zinc metal in 1 M sulfuric acid solution:\nSynthesis, experimental, and DFT studies","volume":"2","author":"Leboho","year":"2025","journal-title":"Next\nRes."},{"key":"2026090307172380500_cit65","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcomm.2025.111661","article-title":"Two nicotinic acid\n-amino acid derivatives as green corrosion inhibitors\nfor Q235 steel in 1\u202fM HCl solution","volume":"43","author":"Guo","year":"2025","journal-title":"Mater.\nToday Commun."},{"key":"2026090307172380500_cit66","doi-asserted-by":"publisher","DOI":"10.1016\/j.scowo.2025.100163","article-title":"Jasminum officinale\nplant leaves extract as sustainable and green corrosion inhibitor\nfor mild steel in acidic medium: Chemical, electrochemical, surface\ncharacterisation and computational approaches","volume":"9","author":"Pai","year":"2026","journal-title":"Sustainable Chem. One World"},{"key":"2026090307172380500_cit67","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2025.107999","article-title":"Polypodium\nleucotomos\nextract as a promising corrosion inhibitor for mild steel in 5% HCl:\nInsights from gravimetric, electrochemical and surface and studies","volume":"77","author":"Khan","year":"2025","journal-title":"Surf. Interfaces"},{"key":"2026090307172380500_cit68","unstructured":"American Society for Testing and Materials.\n          . ASTM D7042\u201316E1: Standard Test Method for Dynamic Viscosity\nand Density of Liquids by Stabinger Viscometer. 2016."},{"key":"2026090307172380500_cit69","unstructured":"Caricato, M.; Frisch, A.; Hiscocks, J.; Frisch, M. J.\n          Gaussian 09\nIOps Reference, 2003."},{"key":"2026090307172380500_cit70","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.softx.2015.06.001","article-title":"Gromacs: High performance\nmolecular simulations through multi-level parallelism from laptops\nto supercomputers","volume":"1-2","author":"Abraham","year":"2015","journal-title":"SoftwareX"},{"key":"2026090307172380500_cit71","doi-asserted-by":"publisher","first-page":"11225","DOI":"10.1021\/ja9621760","article-title":"Development\nand Testing of the OPLS\nAll-Atom Force Field on Conformational Energetics and Properties of\nOrganic Liquids","volume":"118","author":"Jorgensen","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"2026090307172380500_cit72","doi-asserted-by":"publisher","DOI":"10.3390\/buildings14082558","article-title":"Protective Effects\nof Small Molecular Inhibitors on Steel Corrosion:\nThe Generation of a Multi-Electric Layer on Passivation Films","volume":"14","author":"Wu","year":"2024","journal-title":"Buildings"},{"key":"2026090307172380500_cit73","doi-asserted-by":"publisher","first-page":"49432","DOI":"10.1021\/acsomega.3c08211","article-title":"Corrosion Prevention of Copper in\n2.0 M Sulfamic Acid\nUsing Novel Plant Extract: Chemical, Electrochemical, and Theoretical\nStudies","volume":"8","author":"Salem","year":"2023","journal-title":"ACS Omega"},{"key":"2026090307172380500_cit74","doi-asserted-by":"publisher","first-page":"301","DOI":"10.1021\/acs.energyfuels.2c03337","article-title":"Molecular\nDynamics Simulation of Methane Hydrate Formation\non Pipeline Surface in the Presence of Corrosion Inhibitors","volume":"37","author":"Hu","year":"2023","journal-title":"Energy Fuels"},{"key":"2026090307172380500_cit75","doi-asserted-by":"publisher","first-page":"926","DOI":"10.1063\/1.445869","article-title":"Comparison\nof simple potential functions for simulating liquid water","volume":"79","author":"Jorgensen","year":"1983","journal-title":"J. Chem. Phys."},{"key":"2026090307172380500_cit76","doi-asserted-by":"publisher","first-page":"7618","DOI":"10.1016\/j.apsusc.2008.01.123","article-title":"Development of a new\nmolecular dynamics method for tribochemical reaction and its application\nto formation dynamics of MoS2 tribofilm","volume":"254","author":"Morita","year":"2008","journal-title":"Appl.\nSurf. Sci."},{"key":"2026090307172380500_cit77","doi-asserted-by":"publisher","first-page":"10089","DOI":"10.1063\/1.464397","article-title":"Particle mesh Ewald: An N\u00b7log(N)\nmethod for Ewald sums in large systems","volume":"98","author":"Darden","year":"1993","journal-title":"J. Chem.\nPhys."},{"key":"2026090307172380500_cit78","volume-title":"LINCS: A Linear\nConstraint Solver for Molecular Simulations","author":"Hess","year":"1997"},{"key":"2026090307172380500_cit79","doi-asserted-by":"publisher","DOI":"10.1063\/1.2408420","article-title":"Canonical\nsampling through velocity\nrescaling","volume":"126","author":"Bussi","year":"2007","journal-title":"J. Chem. Phys."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c05701","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/34\/51589\/66608249\/acsomega.6c05701.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/34\/51589\/66608249\/acsomega.6c05701.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T11:17:30Z","timestamp":1788434250000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/34\/51589\/5259540\/From-Seaweed-to-Corrosion-Inhibitor-A-Multi-Method"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,17]]},"references-count":79,"journal-issue":{"issue":"34","published-online":{"date-parts":[[2026,8,17]]},"published-print":{"date-parts":[[2026,9,1]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c05701","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,17]]}}}