{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T15:53:15Z","timestamp":1789487595281,"version":"build-2803163510"},"reference-count":46,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004809","name":"Financiadora de Estudos e Projetos","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003401","name":"Funda??o de Amparo ? Pesquisa do Estado de Alagoas","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003401","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The influence of temperature on the product distribution during fructose conversion was systematically investigated using Ce(P), Nb(P), CeNb5(P), CeNb15(P), and CeNb25(P) materials prepared by the Pechini method. Reactions were performed in aqueous medium for 2 h at temperatures ranging from 130 to 160 \u00b0C. Increasing temperature enhanced fructose conversion but also modified the relative contributions of dehydration, fragmentation, and consecutive degradation pathways. Nb(P) reached the highest fructose conversion, increasing from 17.6% at 130 \u00b0C to 67.9% at 160 \u00b0C, but also exhibited a greater contribution from unidentified and degradation products under the most severe conditions. In contrast, the Ce\u2013Nb mixed oxides, particularly CeNb15(P) and CeNb25(P), more effectively directed the identified soluble products toward 5-hydroxymethylfurfural (5-HMF), while limiting some competing pathways. The formation of C3 compounds, including dihydroxyacetone and pyruvaldehyde, indicates the occurrence of C\u2013C bond cleavage reactions, whose contribution increased with temperature and depended on material composition. The observed product distributions result from the combined influence of temperature, acid-site nature, concentration, strength, and accessibility, together with the redox properties of the Ce containing materials. These findings demonstrate that the principal contribution of the studied oxides lies in their catalyst dependent modulation of the fructose reaction network rather than in the effect of temperature alone.<\/jats:p>","DOI":"10.1021\/acsomega.6c06462","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:48:18Z","timestamp":1788396498000},"page":"54492-54500","source":"Crossref","is-referenced-by-count":0,"title":["Influence of Temperature\non Reaction Pathways in Fructose\nConversion over Mixed Oxide Catalysts Based on Ce and Nb"],"prefix":"10.1021","volume":"11","author":[{"given":"Dhara Beatriz de Amorim","family":"Pryston","sequence":"first","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thatiane Veri\u0301ssimo dos Santos","family":"Martins","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jailma Barros","family":"dos Santos","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel Santos Vilela","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wemerson do Nascimento","family":"Silva","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Renato da Silva","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2033-318X","authenticated-orcid":true,"given":"Maria do Carmo M.","family":"Alves","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio Grande do Sul , , CP 15003 , , ,","place":["Porto Alegre, RS, Brazil, 91501-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4143-1208","authenticated-orcid":true,"given":"Jonder","family":"Morais","sequence":"additional","affiliation":[{"name":"Universidade Federal do Rio Grande do Sul , , CP 15051 , , ,","place":["Porto Alegre, RS, Brazil, 91501- 970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Janai\u0301na Heberle","family":"Bortoluzzi","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0722-8599","authenticated-orcid":true,"given":"Mario Roberto","family":"Meneghetti","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3073-5406","authenticated-orcid":true,"given":"Simoni Margareti Plentz","family":"Meneghetti","sequence":"additional","affiliation":[{"name":"Federal University of Alagoas , , Av. Lourival de Melo Mota, s\/n\u00b0 , , ,","place":["Maceio\u0301, AL, Brazil, 57072-970"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,31]]},"reference":[{"key":"2026091510075742800_cit1","doi-asserted-by":"publisher","DOI":"10.1007\/s13399-025-07035-0","article-title":"Hydrothermal liquefaction and gasification of industrial\nwaste algae: experimental and AI-assisted optimization for biofuel\nand hydrogen production","volume":"16","author":"Deepankumar","year":"2026","journal-title":"Biomass Convers. Biorefin."},{"key":"2026091510075742800_cit2","doi-asserted-by":"publisher","first-page":"183","DOI":"10.1016\/j.apcatb.2017.09.049","article-title":"Tin phosphate as a\nheterogeneous catalyst for efficient dehydration of glucose into 5-hydroxymethylfurfural\nin ionic liquid","volume":"224","author":"Hou","year":"2018","journal-title":"Appl. Catal., B"},{"key":"2026091510075742800_cit3","doi-asserted-by":"publisher","first-page":"2879","DOI":"10.1039\/D3EE00478C","article-title":"From fossil\nto green chemicals: sustainable pathways and new carbon feedstocks\nfor the global chemical industry","volume":"16","author":"Lopez","year":"2023","journal-title":"Energy Environ.\nSci."},{"issue":"4","key":"2026091510075742800_cit4","doi-asserted-by":"publisher","DOI":"10.1002\/smo.20240019","article-title":"A review on renewable\nenergy: conversion and utilization of biomass","volume":"2","author":"Yang","year":"2024","journal-title":"SmartMat"},{"key":"2026091510075742800_cit5","doi-asserted-by":"publisher","first-page":"1679","DOI":"10.1039\/D2GC04046H","article-title":"High-yield synthesis of 5-hydroxymethylfurfural\nfrom glucose and fructose by selective catalysis with water-tolerant\nrare earth metal triflates assisted by choline chloride","volume":"25","author":"Olivito","year":"2023","journal-title":"Green Chem."},{"key":"2026091510075742800_cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.126610","article-title":"The influence\nof the surface chemistry of phosphorylated carbon xerogel catalysts\non the production of 5-hydroxymethylfurfural from fructose in water","volume":"334","author":"Eblagon","year":"2023","journal-title":"Fuel"},{"key":"2026091510075742800_cit7","doi-asserted-by":"publisher","first-page":"754","DOI":"10.1039\/c0gc00401d","article-title":"5-Hydroxymethylfurfural\n(HMF) as a Building Block Platform: Biological Properties, Synthesis\nand Synthetic Applications","volume":"13","author":"Rosatella","year":"2011","journal-title":"Green Chem."},{"key":"2026091510075742800_cit8","doi-asserted-by":"publisher","first-page":"15994","DOI":"10.1021\/acsomega.5c10095","article-title":"Production\nof 5-hydroxymethylfurfural from glucose\nunder hydrothermal conditions","volume":"11","author":"Tian","year":"2026","journal-title":"ACS Omega"},{"key":"2026091510075742800_cit9","doi-asserted-by":"publisher","first-page":"14007","DOI":"10.1039\/D5TA07323E","article-title":"A comprehensive\nreview on the chemical processes and catalytic mechanisms\ninvolved in the conversion of biomass to carbon materials","volume":"14","author":"Tayyab","year":"2026","journal-title":"J. Mater. Chem. A"},{"key":"2026091510075742800_cit10","doi-asserted-by":"publisher","first-page":"389","DOI":"10.1016\/j.biombioe.2012.01.036","article-title":"Microwave-assisted hydrothermal degradation\nof fructose and glucose in subcritical water","volume":"39","author":"Mo\u0308ller","year":"2012","journal-title":"Biomass Bioenergy"},{"key":"2026091510075742800_cit11","doi-asserted-by":"publisher","first-page":"5481","DOI":"10.1039\/D1GC01429C","article-title":"Catalytic Approach\nvia Retro-Aldol\nCondensation of Glucose to Furanic Compounds","volume":"23","author":"Zhang","year":"2021","journal-title":"Green Chem."},{"key":"2026091510075742800_cit12","doi-asserted-by":"publisher","first-page":"23692","DOI":"10.1021\/acs.energyfuels.5c05071","article-title":"Hydrothermal\nReactions of Biomass-Derived Platform\nMolecules: Catalytic Decomposition Mechanisms of Glucose and Fructose\nover a Solid Acid Catalyst","volume":"39","author":"Wu","year":"2025","journal-title":"Energy Fuels"},{"key":"2026091510075742800_cit13","doi-asserted-by":"publisher","first-page":"2115","DOI":"10.1021\/acs.energyfuels.2c03462","article-title":"Hydrothermal\nreactions of biomass-derived platform\nmolecules: mechanistic insights into 5-hydroxymethylfurfural (5-HMF)\nformation during glucose and fructose decomposition","volume":"37","author":"Wu","year":"2023","journal-title":"Energy Fuels"},{"issue":"10","key":"2026091510075742800_cit14","doi-asserted-by":"publisher","first-page":"2211","DOI":"10.1002\/cssc.201803013","article-title":"Examining\nacid formation during the selective dehydration of fructose to 5-hydroxymethylfurfural\nin dimethyl sulfoxide and water","volume":"12","author":"Whitaker","year":"2019","journal-title":"ChemSusChem"},{"issue":"8","key":"2026091510075742800_cit15","doi-asserted-by":"publisher","first-page":"1248","DOI":"10.1016\/S1872-2067(19)63519-9","article-title":"Dehydration of sugars to 5-hydroxymethylfurfural\nand non-stoichiometric formic and levulinic acids over mesoporous\nTa and Ta-W oxide solid acid catalysts","volume":"41","author":"Guo","year":"2020","journal-title":"Chin.\nJ. Catal."},{"key":"2026091510075742800_cit16","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmf.2025.100009","article-title":"A review of\n5-hydroxymethylfurfural production from fructose using heterogeneous\ncatalysts","volume":"1","author":"Arabi","year":"2026","journal-title":"Biomass Futures"},{"key":"2026091510075742800_cit17","doi-asserted-by":"publisher","first-page":"4812","DOI":"10.1002\/cssc.202001341","article-title":"Controlling the reaction networks\nfor efficient conversion of glucose into 5-hydroxymethylfurfural","volume":"13","author":"Zhu","year":"2020","journal-title":"ChemSusChem"},{"key":"2026091510075742800_cit18","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2026.122935","article-title":"Room-Temperature Isomerization of Glucose into Fructose over CaO\u2013MgO\nCatalysts in Water Based on Response Surface Methodology Optimization","volume":"242","author":"Long","year":"2026","journal-title":"Ind. Crops Prod."},{"issue":"8","key":"2026091510075742800_cit19","doi-asserted-by":"publisher","first-page":"1586","DOI":"10.1021\/acssusresmgt.4c00190","article-title":"Sustainable\nporous heterogeneous catalysts for the conversion of biomass into\nrenewable energy products","volume":"1","author":"Mondal","year":"2024","journal-title":"ACS Sustainable Resour.\nManage."},{"key":"2026091510075742800_cit20","doi-asserted-by":"publisher","first-page":"11270","DOI":"10.1039\/D1CS00039J","article-title":"Emerging Heterogeneous Catalysts\nfor Biomass Conversion: Studies of the Reaction Mechanism","volume":"50","author":"Lin","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"2026091510075742800_cit21","doi-asserted-by":"publisher","DOI":"10.1002\/aesr.202500402","article-title":"Emerging heterogeneous catalysis for valorization of biomass-derived\nplatform molecules: The systematic review toward sustainable biorefinery\napplications","volume":"7","author":"Lakhani","year":"2026","journal-title":"Adv. Energy Sustainability Res."},{"key":"2026091510075742800_cit22","doi-asserted-by":"publisher","DOI":"10.3390\/catal13020285","article-title":"Influence of synthesis methodology\non the properties and catalytic performance of tin, niobium, and tin\u2013niobium\noxides in fructose conversion","volume":"13","author":"dos Santos Martins","year":"2023","journal-title":"Catalysts"},{"key":"2026091510075742800_cit23","doi-asserted-by":"publisher","first-page":"160","DOI":"10.1016\/j.cattod.2011.10.040","article-title":"CeO2\u2013Nb2O5 mixed\noxide catalysts: preparation, characterization\nand catalytic activity in fructose dehydration reaction","volume":"192","author":"Stos\u030cic\u0301","year":"2012","journal-title":"Catal. Today"},{"key":"2026091510075742800_cit24","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2025.131025","article-title":"Pristine\nand mixed cerium and niobium oxides synthesized via Pechini and chitosan\nmethods: effect of properties on methylene blue (MB) photodegradation","volume":"344","author":"de Amorim Pryston","year":"2025","journal-title":"Mater. Chem. Phys."},{"key":"2026091510075742800_cit25","doi-asserted-by":"publisher","first-page":"5987","DOI":"10.1021\/acs.chemrev.5b00603","article-title":"Fundamentals\nand catalytic applications of cerium oxide-based materials","volume":"116","author":"Montini","year":"2016","journal-title":"Chem. Rev."},{"key":"2026091510075742800_cit26","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2021.112083","article-title":"Ceria-supported\nniobium oxide catalyst for low-temperature oxidation of 1,3-butadiene","volume":"518","author":"Razmgar","year":"2022","journal-title":"Mol. Catal."},{"key":"2026091510075742800_cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2021.10.018","article-title":"Tin, molybdenum and tin\u2013molybdenum oxides: influence\nof Lewis and Br\u00f8nsted acid sites on xylose conversion","volume":"394\u2013396","author":"dos Santos","year":"2022","journal-title":"Catal. Today"},{"key":"2026091510075742800_cit28","unstructured":"Pryston, D. B. A.\n          \n          Synthesis-dependent\nelectronic structure and acidity of Ce-Nb oxides: implications for\nfructose conversion in aqueous media\n          Universidade\nFederal de Alagoas: Alagoas; 2026."},{"key":"2026091510075742800_cit29","doi-asserted-by":"publisher","first-page":"62","DOI":"10.1016\/j.cattod.2020.07.002","article-title":"Tin, niobium and tin\u2013niobium oxides obtained\nby the Pechini method using glycerol as a polyol: synthesis, characterization\nand use as a catalyst in fructose conversion","volume":"379","author":"dos Santos","year":"2021","journal-title":"Catal. Today"},{"issue":"3","key":"2026091510075742800_cit30","doi-asserted-by":"publisher","first-page":"5839","DOI":"10.15376\/biores.11.3.5839-5853","article-title":"Catalytic conversion of biomass-derived\ncarbohydrates into 5-hydroxymethylfurfural\nusing a strong solid acid catalyst in aqueous \u03b3-valerolactone","volume":"11","author":"Li","year":"2016","journal-title":"BioResources"},{"key":"2026091510075742800_cit31","doi-asserted-by":"publisher","DOI":"10.1007\/s11243-026-00721-6","article-title":"Niobium-catalyzed\nreactions to add value to renewable\nraw material: a review of unsupported and supported catalysts","volume":"51","author":"Batalha","year":"2026","journal-title":"Transit. Met. Chem."},{"issue":"11","key":"2026091510075742800_cit32","doi-asserted-by":"publisher","DOI":"10.3390\/catal9110907","article-title":"Rational design\nof metal oxide solid acids for sugar conversion","volume":"9","author":"Takagaki","year":"2019","journal-title":"Catalysts"},{"issue":"17","key":"2026091510075742800_cit33","doi-asserted-by":"publisher","first-page":"15670","DOI":"10.1021\/acscatal.5c03817","article-title":"NbOx-based\ncatalysts for biomass conversion: progress in the past 20 years","volume":"15","author":"Jing","year":"2025","journal-title":"ACS Catal."},{"key":"2026091510075742800_cit34","doi-asserted-by":"publisher","first-page":"329","DOI":"10.1016\/j.jcat.2016.03.007","article-title":"Niobium oxides:\ncorrelation of acidity with structure\nand catalytic performance in sucrose conversion to 5-hydroxymethylfurfural","volume":"338","author":"Kreissl","year":"2016","journal-title":"J. Catal."},{"key":"2026091510075742800_cit35","doi-asserted-by":"publisher","first-page":"8523","DOI":"10.1039\/D2GC02736D","article-title":"Aqueous Conversion\nof Monosaccharides\nto Furans: Were We Wrong All Along to Use Catalysts?","volume":"24","author":"Jakob","year":"2022","journal-title":"Green Chem."},{"key":"2026091510075742800_cit36","doi-asserted-by":"publisher","first-page":"259","DOI":"10.1021\/cs4009495","article-title":"Kinetics of Homogeneous Br\u00f8nsted Acid-Catalyzed\nFructose Dehydration and 5-Hydroxymethylfurfural Rehydration: A Combined\nExperimental and Computational Study","volume":"4","author":"Swift","year":"2014","journal-title":"ACS Catal."},{"key":"2026091510075742800_cit37","doi-asserted-by":"publisher","first-page":"3024","DOI":"10.1021\/acssuschemeng.5b00023","article-title":"Experimental and\nKinetic Modeling Studies on the Sulfuric\nAcid-Catalyzed Conversion of d-Fructose to 5-Hydroxymethylfurfural\nand Levulinic Acid in Water","volume":"3","author":"Fachri","year":"2015","journal-title":"ACS Sustainable\nChem. Eng."},{"key":"2026091510075742800_cit38","doi-asserted-by":"publisher","first-page":"35578","DOI":"10.1039\/D4RA06038E","article-title":"Statistically driven\nautomated method for catalytic glucose conversion optimization","volume":"14","author":"Install","year":"2024","journal-title":"RSC Adv."},{"key":"2026091510075742800_cit39","doi-asserted-by":"publisher","first-page":"6463","DOI":"10.1021\/acs.iecr.5c05048","article-title":"Synergistic catalysis\nat engineered Ru\u2013Fe2O3 interfaces on\niron silicate for selective conversion of sucrose to diols and lower\nalcohols","volume":"65","author":"Luo","year":"2026","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026091510075742800_cit40","doi-asserted-by":"publisher","first-page":"5704","DOI":"10.1039\/D0CS00177E","article-title":"Advances in\ncatalytic routes for the production of carboxylic acids from biomass:\na step forward for sustainable polymers","volume":"49","author":"Iglesias","year":"2020","journal-title":"Chem.\nSoc. Rev."},{"key":"2026091510075742800_cit41","doi-asserted-by":"publisher","first-page":"23121","DOI":"10.1021\/acsomega.3c10015","article-title":"Homogeneous and heterogeneous catalysis of glucose\nto lactic acid and lactates: a review","volume":"9","author":"Saulnier-Bellemare","year":"2024","journal-title":"ACS Omega"},{"key":"2026091510075742800_cit42","doi-asserted-by":"publisher","first-page":"44786","DOI":"10.1021\/acsomega.2c04783","article-title":"Mechanistic investigation into the\nformation of humins in acid-catalyzed biomass reactions","volume":"7","author":"Caldero\u0301n","year":"2022","journal-title":"ACS Omega"},{"key":"2026091510075742800_cit43","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202400761","article-title":"Controlling Chelation\nand Esterification in Pechini Synthesis for Enhancing Chemical Looping\nSteam Methane Reforming Using LaFeO3 Perovskite","volume":"18","author":"Kim","year":"2025","journal-title":"ChemSusChem"},{"key":"2026091510075742800_cit44","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsadv.2021.100112","article-title":"Systematic\nand Collaborative Approach to Problem Solving Using X-ray Photoelectron\nSpectroscopy","volume":"5","author":"Fairley","year":"2021","journal-title":"Appl. Surf. Sci. Adv."},{"key":"2026091510075742800_cit45","volume-title":"Handbook of X-ray Photoelectron Spectroscopy: A\nReference Book of\nStandard Spectra for Identification and Interpretation of XPS Data","author":"Moulder","year":"1992"},{"key":"2026091510075742800_cit46","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.5.4709","article-title":"High-Resolution\nX-Ray Photoemission Spectrum of the Valence Bands of Gold","volume":"5","author":"Shirley","year":"1972","journal-title":"Phys. Rev. B"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c06462","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/36\/54492\/67959299\/acsomega.6c06462.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/36\/54492\/67959299\/acsomega.6c06462.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T14:50:17Z","timestamp":1789483817000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/36\/54492\/5380942\/Influence-of-Temperature-on-Reaction-Pathways-in"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,31]]},"references-count":46,"journal-issue":{"issue":"36","published-online":{"date-parts":[[2026,8,31]]},"published-print":{"date-parts":[[2026,9,15]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c06462","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,31]]}}}