{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T00:13:04Z","timestamp":1788221584801,"version":"build-2803163510"},"reference-count":46,"publisher":"American Chemical Society (ACS)","issue":"33","license":[{"start":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T00:00:00Z","timestamp":1786320000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100020950","name":"National Science and Technology Council","doi-asserted-by":"publisher","award":["111-2221-E-027-071-MY3"],"award-info":[{"award-number":["111-2221-E-027-071-MY3"]}],"id":[{"id":"10.13039\/501100020950","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100020950","name":"National Science and Technology Council","doi-asserted-by":"publisher","award":["113-2221-E-027-010-MY3"],"award-info":[{"award-number":["113-2221-E-027-010-MY3"]}],"id":[{"id":"10.13039\/501100020950","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,25]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The development of electrode materials with efficient charge transfer and abundant active sites remains crucial for high-performance supercapacitors. In this work, cobalt\u2013manganese glycerates with tunable cobalt-to-manganese ratios are synthesized to systematically investigate the relationship between composition, structure, and electrochemical behavior. The incorporation of manganese disrupts the regular growth of cobalt-based glycerates, resulting in amorphous, rough, and defect-rich structures with enhanced surface area and improved electrolyte accessibility. Among all compositions, the optimized bimetallic sample with the highest manganese content exhibits the highest specific capacitance of 1333.6 F\/g at 20 mV\/s, demonstrating a balanced combination of electrical conductivity and redox activity. Compared with monometallic counterparts, the bimetallic system shows improved charge storage capability due to synergistic electronic interaction and more efficient ion and electron transport. The assembled two-electrode device achieves a potential window of 1.3 V and a maximum energy density of 83 Wh\/kg at 325 W\/kg. In addition, the device retains 90% of its initial capacitance with nearly 100% Coulombic efficiency after 7500 cycles. These results highlight the importance of composition regulation in glycerate-derived materials, and further improvements may be achieved by optimizing composition and enhancing structural stability.<\/jats:p>","DOI":"10.1021\/acsomega.6c07626","type":"journal-article","created":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T18:02:04Z","timestamp":1786384924000},"page":"50570-50584","source":"Crossref","is-referenced-by-count":0,"title":["Composition-Driven\nStructural Evolution in Cobalt\u2013Manganese\nGlycerates toward Defect-Rich Amorphous Electrodes for High-Performance\nBattery\u2013Supercapacitor Hybrids"],"prefix":"10.1021","volume":"11","author":[{"given":"Tsai-Mu","family":"Cheng","sequence":"first","affiliation":[{"name":"Taipei Medical University , , ,","place":["Taipei, Taiwan, 11031"]},{"name":"Taipei Medical University , , ,","place":["Taipei, Taiwan, 11031"]},{"name":"Taipei Medical University Hospital , , ,","place":["Taipei, Taiwan, 11031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chih-Yu","family":"Chang","sequence":"additional","affiliation":[{"name":"National Taipei University of Technology , , ,","place":["Taipei, Taiwan, 106344"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zher-Yu","family":"You","sequence":"additional","affiliation":[{"name":"National Taipei University of Technology , , ,","place":["Taipei, Taiwan, 106344"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1274-0597","authenticated-orcid":true,"given":"Chutima","family":"Kongvarhodom","sequence":"additional","affiliation":[{"name":"King Mongkut\u2019s University of Technology Thonburi , , 126 Pracha-u-thit , Toong-kru, ,","place":["Bangkok, Thailand, 10140"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sadang","family":"Husain","sequence":"additional","affiliation":[{"name":"Lambung Mangkurat University , , ,","place":["Banjarmasin, Indonesia, 70124"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sibidou","family":"Yougbare\u0301","sequence":"additional","affiliation":[{"name":"Institut de Recherche en Sciences de la Sante\u0301 (IRSS-DRCO)\/Nanoro , ,","place":["Ouagadougou 03, Burkina Faso, 03 B.P 7192"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hung-Ming","family":"Chen","sequence":"additional","affiliation":[{"name":"Gingen Technology Co., LTD. , Rm. 7, 10F., No.189, Sec. 2, Keelung Rd. , Xinyi Dist., ,","place":["Taipei, Taiwan, 11054"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2326-292X","authenticated-orcid":true,"given":"Lu-Yin","family":"Lin","sequence":"additional","affiliation":[{"name":"National Taipei University of Technology , , ,","place":["Taipei, Taiwan, 106344"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,10]]},"reference":[{"key":"2026083119141394000_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2025.115530","article-title":"Investigating energy storage ability of cobalt molybdenum\nhydroxide, sulfide and boride as active materials of battery supercapacitor\nhybrids","volume":"112","author":"Chen","year":"2025","journal-title":"J. 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Energy Mater."},{"key":"2026083119141394000_cit40","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2024.115135","article-title":"Synthesis\nof electroactive nickel\nhydroxide using nickel tetrafluoroborate as novel metal precursor\nand structure directing agent in different solvents for energy storage\napplication","volume":"109","author":"You","year":"2025","journal-title":"J. Energy Storage"},{"key":"2026083119141394000_cit41","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2023.110316","article-title":"Metal ratio\nand bimetal nanoarchitectonics of ammonia-based fluoride complex induced\nnickel hydroxide and manganese oxide composites as active materials\nof an energy storage device","volume":"80","author":"Hsu","year":"2024","journal-title":"J. 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Energy\nMater."},{"issue":"21","key":"2026083119141394000_cit46","doi-asserted-by":"publisher","first-page":"21498","DOI":"10.1021\/acs.energyfuels.4c03384","article-title":"Advanced Supercapacitor Electrodes:\nTrimetallic Co\u2013Mn\u2013Fe Selenide Nanoflowers Encased in\nReduced Graphene Oxide","volume":"38","author":"Zardkhoshoui","year":"2024","journal-title":"Energy Fuels"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c07626","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/33\/50570\/66478469\/acsomega.6c07626.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/33\/50570\/66478469\/acsomega.6c07626.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T23:14:19Z","timestamp":1788218059000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/33\/50570\/5251528\/Composition-Driven-Structural-Evolution-in-Cobalt"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,10]]},"references-count":46,"journal-issue":{"issue":"33","published-online":{"date-parts":[[2026,8,10]]},"published-print":{"date-parts":[[2026,8,25]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c07626","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,10]]}}}