{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T16:09:34Z","timestamp":1790698174524,"version":"4.1.0"},"reference-count":83,"publisher":"American Chemical Society (ACS)","issue":"38","license":[{"start":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T00:00:00Z","timestamp":1789171200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100011789","name":"Department of Science and Technology of Jilin Province","doi-asserted-by":"publisher","award":["YDZJ202501ZYTS348"],"award-info":[{"award-number":["YDZJ202501ZYTS348"]}],"id":[{"id":"10.13039\/501100011789","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["61705079"],"award-info":[{"award-number":["61705079"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010211","name":"Education Department of Jilin Province","doi-asserted-by":"publisher","award":["JJKH20250941KJ"],"award-info":[{"award-number":["JJKH20250941KJ"]}],"id":[{"id":"10.13039\/501100010211","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Doping with transition metals and constructing S-scheme heterojunctions are well-recognized strategies for boosting photocatalytic CO2 reduction. Herein, we adopt a cascade design approach to fabricate a Ni-doped CsPbBr3\/ZnO S-scheme heterojunction, aiming to further improve the material\u2019s photocatalytic activity. First, Ni-doped CsPbBr3 nanocrystals were prepared by a hot-injection method. Subsequently, they were loaded onto ZnO nanosheets through a simple electrostatic self-assembly approach, successfully yielding a 0D\/2D Ni-CsPbBr3\/ZnO S-scheme heterojunction photocatalyst. In this system, the introduction of transition metal Ni, which possesses a relatively high d-band center position, into CsPbBr3 effectively extends the light response region and enhances the light-harvesting capacity. Meanwhile, the dimensional effects of the 0D\/2D heterostructure shorten the transport path of photogenerated carriers, while the internal electric field formed at the Ni-CsPbBr3\/ZnO heterojunction interface further promotes carrier separation and transport, resulting in an increased local electron density. Under UV-Vis illumination for 4 h, the CO and CH4 yields over 4CsPbBr3-3Ni\/ZnO reached 155.06 and 125.87 \u03bcmol\/g, respectively, which are 4.38-fold and 5.43-fold those of CsPbBr3-3Ni, 4.33-fold and 60.22-fold those of pure ZnO, and 1.40-fold and 4.32-fold those of 4CsPbBr3\/ZnO. The excellent photocatalytic CO2 reduction performance is attributed to the synergistic interplay between d-band center engineering and S-scheme heterojunction formation. This synergy concurrently strengthens light harvesting, facilitates directional charge migration, maintains a high redox potential, and optimizes the CO2 adsorption and activation. This study offers meaningful guidance for the rational design of high-efficiency photocatalysts.<\/jats:p>","DOI":"10.1021\/acsomega.6c07948","type":"journal-article","created":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T16:01:57Z","timestamp":1789228917000},"page":"58112-58125","source":"Crossref","is-referenced-by-count":0,"title":["Construction of\na 0D\/2D S-Scheme Heterojunction\nBased on Ni-Doped CsPbBr3 and ZnO for Enhanced Photocatalytic\nCO2 Reduction"],"prefix":"10.1021","volume":"11","author":[{"given":"Tongbin","family":"Zhang","sequence":"first","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Wang","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0095-5694","authenticated-orcid":true,"given":"Xiaoyan","family":"Liu","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hougang","family":"Fan","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Cao","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0333-1684","authenticated-orcid":true,"given":"Lili","family":"Yang","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-6109-3334","authenticated-orcid":true,"given":"Qiong","family":"Wu","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5477-7550","authenticated-orcid":true,"given":"Yanli","family":"Chen","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2735-5421","authenticated-orcid":true,"given":"Xin","family":"Li","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maobin","family":"Wei","sequence":"additional","affiliation":[{"name":"Jilin Normal University , , ,","place":["Changchun, PR China, 130103"]},{"name":"Jilin Normal University , , ,","place":["Siping, PR China, 136000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,12]]},"reference":[{"key":"2026092911083519500_cit1","doi-asserted-by":"publisher","first-page":"952","DOI":"10.1038\/s41929-021-00699-7","article-title":"Coupling electrochemical CO2 conversion with CO2 capture","volume":"4","author":"Sullivan","year":"2021","journal-title":"Nature\nCatalysis"},{"key":"2026092911083519500_cit2","doi-asserted-by":"publisher","first-page":"5563","DOI":"10.1021\/acsomega.4c08249","article-title":"Enhancing\nCO2 Capture and Conversion to Formic Acid via a Membrane-Photocatalytic\nHybrid System with ZnO-ZnS Heterojunction Catalyst","volume":"10","author":"Astuti","year":"2025","journal-title":"ACS Omega"},{"key":"2026092911083519500_cit3","doi-asserted-by":"publisher","first-page":"112101","DOI":"10.1016\/j.cclet.2025.112101","article-title":"Recent\nresearch progress on metal-organic frameworks and their derivatives\nheterostructure for photocatalytic CO2 reduction","volume":"37","author":"Li","year":"2026","journal-title":"Chinese Chemical Letters"},{"key":"2026092911083519500_cit4","doi-asserted-by":"publisher","first-page":"6551","DOI":"10.1021\/jacs.1c01109","article-title":"Interfacial Engineering of Bi19Br3S27 Nanowires Promotes Metallic\nPhotocatalytic CO2 Reduction Activity under Near-Infrared\nLight Irradiation","volume":"143","author":"Li","year":"2021","journal-title":"Journal Of The American Chemical\nSociety"},{"key":"2026092911083519500_cit5","doi-asserted-by":"publisher","first-page":"75","DOI":"10.1016\/j.jmst.2025.08.025","article-title":"Construction of a sea-urchin liked\nS-Scheme heterojunction: A case study using 3D CoNiO2\/W18O49 composite for efficient CO2 photoreduction","volume":"255","author":"Qin","year":"2026","journal-title":"Journal of Materials Science & Technology"},{"key":"2026092911083519500_cit6","doi-asserted-by":"publisher","first-page":"24495","DOI":"10.1021\/acsomega.0c02960","article-title":"Incorporation\nof Cesium Lead Halide Perovskites into g-C3N4 for Photocatalytic CO2 Reduction","volume":"5","author":"Cheng","year":"2020","journal-title":"ACS Omega"},{"key":"2026092911083519500_cit7","doi-asserted-by":"publisher","first-page":"120411","DOI":"10.1016\/j.apcatb.2021.120411","article-title":"Aspect ratio dependent\nphotocatalytic enhancement of CsPbBr3 in CO2 reduction with two-dimensional metal organic framework as a cocatalyst","volume":"297","author":"Xi","year":"2021","journal-title":"Applied Catalysis B: Environmental"},{"key":"2026092911083519500_cit8","doi-asserted-by":"publisher","first-page":"6911","DOI":"10.1039\/C9TA00550A","article-title":"Design of\ndoped cesium\nlead halide perovskite as a photo-catalytic CO2 reduction\ncatalyst","volume":"7","author":"Tang","year":"2019","journal-title":"Journal of Materials Chemistry A"},{"key":"2026092911083519500_cit9","doi-asserted-by":"publisher","first-page":"3437","DOI":"10.1002\/cjoc.70257","article-title":"Photochemical\nNickel-Catalyzed Hydrocyanation of Unactivated Alkenes Using Isonitriles","volume":"43","author":"Lu","year":"2025","journal-title":"Chinese Journal of Chemistry"},{"key":"2026092911083519500_cit10","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116725","article-title":"Selective Fluoromethyl\nCouplings of Alkynes via Nickel Catalysis","volume":"61","author":"Li","year":"2022","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026092911083519500_cit11","doi-asserted-by":"publisher","first-page":"169994","DOI":"10.1016\/j.cej.2025.169994","article-title":"Ni-doped\nCdS modulated d-band center for enhanced S-scheme graphdiyne\/NiCdS\nheterojunction photocatalytic hydrogen production","volume":"525","author":"Xiang","year":"2025","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit12","doi-asserted-by":"publisher","first-page":"107266","DOI":"10.1016\/j.nanoen.2022.107266","article-title":"Modulating\nthe d-band\ncenters by coordination environment regulation of single-atom Ni on\nporous carbon fibers for overall water splitting","volume":"98","author":"Yu","year":"2022","journal-title":"Nano Energy"},{"key":"2026092911083519500_cit13","doi-asserted-by":"publisher","first-page":"16294","DOI":"10.1039\/C9TA04477A","article-title":"Two-dimensional\nZnO for the selective photoreduction of CO2","volume":"7","author":"Zhao","year":"2019","journal-title":"Journal of Materials Chemistry A"},{"key":"2026092911083519500_cit14","doi-asserted-by":"publisher","first-page":"1543","DOI":"10.1016\/j.chempr.2020.06.010","article-title":"S-Scheme\nHeterojunction Photocatalyst","volume":"6","author":"Xu","year":"2020","journal-title":"Chem."},{"key":"2026092911083519500_cit15","doi-asserted-by":"publisher","first-page":"38524","DOI":"10.1021\/acsomega.3c05357","article-title":"Facile\nSynthesis of gC3N4-Exfoliated BiFeO3 Nanocomposite: A Versatile and Efficient S-Scheme Photocatalyst\nfor the Degradation of Various Textile Dyes and Antibiotics in Water","volume":"8","author":"Upar","year":"2023","journal-title":"ACS Omega"},{"key":"2026092911083519500_cit16","doi-asserted-by":"publisher","first-page":"169197","DOI":"10.1016\/j.jallcom.2023.169197","article-title":"3D ZnO\nhollow spheres-dispersed CsPbBr3 quantum dots S-scheme\nheterojunctions for high-efficient\nCO2 photoreduction","volume":"945","author":"Wang","year":"2023","journal-title":"Journal of Alloys\nand Compounds"},{"key":"2026092911083519500_cit17","doi-asserted-by":"publisher","first-page":"15330","DOI":"10.1039\/D4DT02322F","article-title":"Enhanced photocatalytic CO2 conversion over 0D\/2D CsPbBr3\/BiOCl S-scheme heterojunction\nvia boosting charge separation","volume":"53","author":"Qi","year":"2024","journal-title":"Dalton Transactions"},{"key":"2026092911083519500_cit18","doi-asserted-by":"publisher","first-page":"3351","DOI":"10.1021\/acs.inorgchem.2c00012","article-title":"Step-Scheme Photocatalyst of CsPbBr3 Quantum Dots\/BiOBr\nNanosheets for Efficient CO2 Photoreduction","volume":"61","author":"Zhang","year":"2022","journal-title":"Inorg. Chem."},{"key":"2026092911083519500_cit19","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202102295","article-title":"In-Situ Generated\nCsPbBr3 Nanocrystals on\nO-Defective WO3 for Photocatalytic CO2 Reduction","volume":"15","author":"Jiang","year":"2022","journal-title":"ChemSusChem"},{"key":"2026092911083519500_cit20","doi-asserted-by":"publisher","first-page":"116112","DOI":"10.1016\/j.jcat.2025.116112","article-title":"Dual-S-scheme 0D\/2D heterojunction\nof CsPbBr3\/Agi-TiO2 for improved\nphotocatalytic CO2 reduction: Enabling ultrafast interfacial\ncharge transfer and product selective regulation","volume":"447","author":"Wang","year":"2025","journal-title":"Journal of Catalysis"},{"key":"2026092911083519500_cit21","doi-asserted-by":"publisher","first-page":"135071","DOI":"10.1016\/j.cej.2022.135071","article-title":"Unveiling the\neffect of interstitial dopants on CO2 activation over CsPbBr3 catalyst for efficient photothermal CO2 reduction","volume":"435","author":"Bian","year":"2022","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit22","doi-asserted-by":"publisher","first-page":"2001344","DOI":"10.1002\/adma.202001344","article-title":"Lead-Free Halide Perovskite Cs3Bi2xSb2-2xI9 (x \u2248 0.3) Possessing\nthe Photocatalytic Activity for Hydrogen Evolution Comparable to that\nof (CH3NH3)PbI3","volume":"32","author":"Chen","year":"2020","journal-title":"Advanced Materials"},{"key":"2026092911083519500_cit23","doi-asserted-by":"publisher","first-page":"9942","DOI":"10.1021\/jacs.8b04763","article-title":"Doping-Enhanced\nShort-Range Order of Perovskite Nanocrystals for Near-Unity Violet\nLuminescence Quantum Yield","volume":"140","author":"Yong","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"2026092911083519500_cit24","doi-asserted-by":"publisher","first-page":"227195","DOI":"10.1016\/j.jpowsour.2019.227195","article-title":"The effects\nof alkali metal ions with different ionic radii substituting in Li\nsites on the electrochemical properties of Ni-Rich cathode materials","volume":"441","author":"He","year":"2019","journal-title":"J. Power Sources"},{"key":"2026092911083519500_cit25","doi-asserted-by":"publisher","first-page":"121895","DOI":"10.1016\/j.apcatb.2022.121895","article-title":"Efficient\nphotocatalytic CO2 conversion over 2D\/2D Ni-doped CsPbBr3\/Bi3O4Br Z-scheme heterojunction: Critical\nrole of Ni doping, boosted charge separation and mechanism study","volume":"319","author":"Wang","year":"2022","journal-title":"Applied Catalysis B: Environmental"},{"key":"2026092911083519500_cit26","doi-asserted-by":"publisher","first-page":"133762","DOI":"10.1016\/j.cej.2021.133762","article-title":"Embedding\nCsPbBr3 perovskite quantum dots into mesoporous TiO2 beads as an S-scheme heterojunction for CO2 photoreduction","volume":"433","author":"Dong","year":"2022","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit27","doi-asserted-by":"publisher","first-page":"109990","DOI":"10.1016\/j.mssp.2025.109990","article-title":"S-scheme heterojunction of 0D p-type Cu2O and 3D n-type\nFe3O4@SiO2@ZnO for efficiently boosting\nCO2 photoreduction","volume":"200","author":"Wang","year":"2025","journal-title":"Materials Science\nin Semiconductor Processing"},{"key":"2026092911083519500_cit28","doi-asserted-by":"publisher","first-page":"148656","DOI":"10.1016\/j.cej.2024.148656","article-title":"Reasonable\ndesign pentamerous artificial photosynthesis system for efficient\noverall CO2 reduction","volume":"481","author":"Chen","year":"2024","journal-title":"Chemical Engineering\nJournal"},{"key":"2026092911083519500_cit29","doi-asserted-by":"publisher","first-page":"8733","DOI":"10.1039\/D6CC00135A","article-title":"Nitrogen-doped carbon\nlayer thickness modulates the Cu0\/Cu+ interface\nfor selective and stable CO2 electroreduction to ethylene","volume":"62","author":"Liu","year":"2026","journal-title":"Chem. Commun."},{"key":"2026092911083519500_cit30","doi-asserted-by":"publisher","first-page":"26882","DOI":"10.1021\/acsomega.3c01591","article-title":"2D\/2D Biochar\/Bi2WO6 Hybrid Nanosheets with Enhanced Visible Light-Driven\nPhotocatalytic\nActivities for Organic Pollutants Degradation","volume":"8","author":"Li","year":"2023","journal-title":"ACS Omega"},{"key":"2026092911083519500_cit31","doi-asserted-by":"publisher","first-page":"106007","DOI":"10.1016\/j.surfin.2025.106007","article-title":"Construction of\nCsPbBr3\/P25 S-scheme heterostructure for photocatalytic\nselective aerobic oxidation of aromatic alcohols","volume":"60","author":"Liao","year":"2025","journal-title":"Surfaces and Interfaces"},{"key":"2026092911083519500_cit32","doi-asserted-by":"publisher","first-page":"2102770","DOI":"10.1002\/adfm.202102770","article-title":"Enhanced Optical\nProperties and Stability of CsPbBr3 Nanocrystals Through\nNickel Doping","volume":"31","author":"Kim","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"2026092911083519500_cit33","doi-asserted-by":"publisher","first-page":"299","DOI":"10.1016\/j.ijhydene.2024.02.046","article-title":"Cd1-xNixS nanocrystals decorated flower-like Mn doped In2O3 microspheres with enhanced reduction activity\nof CO2","volume":"59","author":"Xu","year":"2024","journal-title":"International Journal of\nHydrogen Energy"},{"key":"2026092911083519500_cit34","doi-asserted-by":"publisher","first-page":"103988","DOI":"10.1016\/j.surfin.2024.103988","article-title":"Construction\nof self-lapping three-dimensional thermal conduction\nnetwork in epoxy resin thermosets by incorporating \u2033dendritic\u2033\nzinc oxide derived from metal-organic framework","volume":"46","author":"Leng","year":"2024","journal-title":"Surfaces and Interfaces"},{"key":"2026092911083519500_cit35","doi-asserted-by":"publisher","first-page":"70","DOI":"10.1016\/j.jpowsour.2018.04.007","article-title":"Oxidation\ndriven ZnS Core-ZnO shell photocatalysts\nunder controlled oxygen atmosphere for improved photocatalytic solar\nwater splitting","volume":"389","author":"Bak","year":"2018","journal-title":"J. Power Sources"},{"key":"2026092911083519500_cit36","doi-asserted-by":"publisher","first-page":"180","DOI":"10.1016\/S1872-2067(19)63484-4","article-title":"MoSe2\/ZnO\/ZnSe hybrids\nfor efficient Cr(VI) reduction under visible\nlight irradiation","volume":"41","author":"Ren","year":"2020","journal-title":"Chinese Journal of Catalysis"},{"key":"2026092911083519500_cit37","doi-asserted-by":"publisher","first-page":"135014","DOI":"10.1016\/j.cej.2022.135014","article-title":"A novel\nS-scheme heterojunction of CsPbBr3 nanocrystals\/AgBr nanorods\nfor artificial photosynthesis","volume":"435","author":"Zhang","year":"2022","journal-title":"Chemical Engineering\nJournal"},{"key":"2026092911083519500_cit38","doi-asserted-by":"publisher","first-page":"13570","DOI":"10.1002\/anie.201808930","article-title":"Amino-assisted\nanchoring of CsPbBr3 perovskite quantum dots on porous\ng-C3N4 for enhanced photocatalytic CO2 reduction","volume":"57","author":"Ou","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026092911083519500_cit39","doi-asserted-by":"publisher","first-page":"4613","DOI":"10.1038\/s41467-020-18350-7","article-title":"Unique S-scheme\nheterojunctions in selfassembled TiO2\/CsPbBr3 hybrids for CO2 photoreduction","volume":"11","author":"Xu","year":"2020","journal-title":"Nat. Commun."},{"key":"2026092911083519500_cit40","doi-asserted-by":"publisher","first-page":"129543","DOI":"10.1016\/j.cej.2021.129543","article-title":"Boosting charge\nseparation and photocatalytic CO2 reduction of CsPbBr3 perovskite quantum dots by hybridizing with P3HT","volume":"419","author":"Li","year":"2021","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit41","doi-asserted-by":"publisher","first-page":"120979","DOI":"10.1016\/j.apcatb.2021.120979","article-title":"2D\/2D BiVO4\/CsPbBr3 S-scheme\nheterojunction for photocatalytic CO2 reduction: Insights\ninto structure regulation and Fermi level\nmodulation","volume":"304","author":"Yue","year":"2022","journal-title":"Applied Catalysis B: Environmental"},{"key":"2026092911083519500_cit42","doi-asserted-by":"publisher","first-page":"116857","DOI":"10.1016\/j.jphotochem.2025.116857","article-title":"A DFT study\non CO2 photoreduction\ncatalyzed by Ni single atoms anchored on COF-1","volume":"472","author":"Xie","year":"2026","journal-title":"Journal of Photochemistry & Photobiology A: Chemistry"},{"key":"2026092911083519500_cit43","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202501541","article-title":"Boosting CH4 Selectivity\nin CO2 Photoreduction over a CdS QDs\/MXene-Derived TiO2 S-Scheme Heterojunction via Interlayer Confinement Engineering","volume":"10","author":"Li","year":"2026","journal-title":"Advanced Sustainable Systems"},{"key":"2026092911083519500_cit44","doi-asserted-by":"publisher","DOI":"10.1016\/j.jes.2026.06.001","article-title":"Time-controlled\nrapid crystallization for defect engineering of Pb-MOF\/aerogel composites\ntowards enhanced visible-light photocatalytic removal of Cr(VI) and\norganic pollutants","author":"Zhang","year":"2026","journal-title":"Journal of Environmental\nSciences"},{"key":"2026092911083519500_cit45","doi-asserted-by":"publisher","first-page":"124014","DOI":"10.1016\/j.cej.2020.124014","article-title":"Z-scheme heterojunction\ng-C3N4@PDA\/BiOBr with biomimetic polydopamine\nas electron\ntransfer mediators for enhanced visible-light driven degradation of\nsulfamethoxazole","volume":"386","author":"Guo","year":"2020","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit46","doi-asserted-by":"publisher","first-page":"171520","DOI":"10.1016\/j.jallcom.2023.171520","article-title":"Withered\nmagnolia-derived BCDs onto 3D flower-like Bi2WO6 for efficient photocatalytic TC degradation and CO2 reduction","volume":"965","author":"Li","year":"2023","journal-title":"Journal of Alloys and Compounds"},{"key":"2026092911083519500_cit47","doi-asserted-by":"publisher","first-page":"200","DOI":"10.1016\/j.apcatb.2016.05.056","article-title":"Enhancement of g-C3N4 nanosheets photocatalysis\nby synergistic interaction of ZnS microsphere and RGO inducing multistep\ncharge transfer","volume":"198","author":"Shao","year":"2016","journal-title":"Applied Catalysis B: Environmental"},{"key":"2026092911083519500_cit48","doi-asserted-by":"publisher","first-page":"81","DOI":"10.1007\/s12274-020-3045-9","article-title":"A hierarchical heterostructure\nof CdS QDs confined on 3D ZnIn2S4 with boosted\ncharge transfer for photocatalytic CO2 reduction","volume":"14","author":"Zhu","year":"2021","journal-title":"Nano Research"},{"key":"2026092911083519500_cit49","doi-asserted-by":"publisher","first-page":"58","DOI":"10.1016\/j.jcis.2020.09.018","article-title":"Ultrathin Z-scheme 2D\/2D N-doped\nHTiNbO5 nanosheets\/g-C3N4 porous\ncomposites for efficient photocatalytic degradation and H2 generation under visible light","volume":"583","author":"Liu","year":"2021","journal-title":"J. Colloid\nInterface Sci."},{"key":"2026092911083519500_cit50","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202512107","article-title":"Au LSPR Effect Enhanced R-CeO2\/G-C3N4 S-scheme Heterojunction for\nAccelerating CO2 Photoreduction Performance","volume":"22","author":"Li","year":"2026","journal-title":"Small"},{"key":"2026092911083519500_cit51","doi-asserted-by":"publisher","first-page":"637","DOI":"10.1007\/s40242-025-5164-z","article-title":"Step-scheme 0D\/2D Heterojunctions Based on Ag2S Nanoparticles\/Graphite-C3N4 Nanosheets with\nEnhanced Visible-light Photocatalytic CO2 Reduction Performance","volume":"42","author":"Wang","year":"2026","journal-title":"Chemical Research in Chinese Universities"},{"key":"2026092911083519500_cit52","doi-asserted-by":"publisher","first-page":"185","DOI":"10.1016\/j.jmst.2024.05.017","article-title":"TiO2 doping\npromoted nucleation of CsPbX3 (X = Cl, Br, I) quantum dots\nin glass with improved luminescent\nperformance and stability","volume":"209","author":"Yang","year":"2025","journal-title":"Journal of Materials\nScience & Technology"},{"key":"2026092911083519500_cit53","doi-asserted-by":"publisher","first-page":"182","DOI":"10.1016\/j.jmst.2024.09.041","article-title":"Structural reconstruction\nsynthesis of highly luminous water-stable CsPbBr3@CsPb2Br5@DSPE core-shell perovskite nanocrystals for\nbioimaging, pattering, and LEDs","volume":"222","author":"Ren","year":"2025","journal-title":"Journal of\nMaterials Science & Technology"},{"key":"2026092911083519500_cit54","doi-asserted-by":"publisher","first-page":"227","DOI":"10.1016\/S1872-2067(25)64866-2","article-title":"Rational construction\nof MXene-derived\nTiO2\/CoNiO2 dual-site S-scheme heterojunction\nfor boosting C-C coupling toward efficient photocatalytic CO2-to-C2H4 conversion","volume":"81","author":"Hu","year":"2026","journal-title":"Chinese Journal of Catalysis"},{"key":"2026092911083519500_cit55","doi-asserted-by":"publisher","first-page":"4581","DOI":"10.1021\/acsomega.3c07326","article-title":"Visible Light-Driven\nPhotocatalytic Degradation of Methylene Blue Dye Using a Highly Efficient\nMg-Al LDH@g-C3N4@Ag3PO4 Nanocomposite","volume":"9","author":"Salehi","year":"2024","journal-title":"ACS Omega"},{"key":"2026092911083519500_cit56","doi-asserted-by":"publisher","first-page":"104402","DOI":"10.1016\/j.surfin.2024.104402","article-title":"Low-crystallinity\nporous Ni2P2O7 nanowires with excellent\nCO2 capture ability for highly-efficient CO2 reduction","volume":"49","author":"Sun","year":"2024","journal-title":"Surfaces and Interfaces"},{"key":"2026092911083519500_cit57","doi-asserted-by":"publisher","first-page":"138147","DOI":"10.1016\/j.jcis.2025.138147","article-title":"Highly\ncrystalline hydrogen-bonded\norganic framework towards stable Zn metal anodes","volume":"699","author":"Yang","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"2026092911083519500_cit58","doi-asserted-by":"publisher","first-page":"127377","DOI":"10.1016\/j.cej.2020.127377","article-title":"S-scheme heterojunction based on\np-type ZnMn2O4 and n-type ZnO with improved\nphotocatalytic CO2 reduction activity","volume":"409","author":"Deng","year":"2021","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit59","doi-asserted-by":"publisher","first-page":"109097","DOI":"10.1016\/j.surfin.2026.109097","article-title":"CO2 mass transfer optimization\nfor enhanced photocatalytic CO2 reduction via a surface\nCO32- layer reconstruction","volume":"88","author":"Wang","year":"2026","journal-title":"Surfaces and Interfaces"},{"key":"2026092911083519500_cit60","doi-asserted-by":"publisher","first-page":"2408002","DOI":"10.3866\/PKU.WHXB202408002","article-title":"In Situ Assembled ZnWO4\/g-C3N4 S-Scheme Heterojunction with Nitrogen\nDefect for CO2 Photoreduction","volume":"40","author":"Qin","year":"2024","journal-title":"Acta\nPhysico-Chimica Sinica"},{"key":"2026092911083519500_cit61","doi-asserted-by":"publisher","first-page":"6238","DOI":"10.1021\/acsaem.2c00612","article-title":"Enhanced Photocatalytic Activity\nfor CO2 Reduction over a CsPbBr3\/CoAl-LDH Composite:\nInsight into the S-Scheme Charge Transfer Mechanism","volume":"5","author":"Li","year":"2022","journal-title":"ACS Applied Energy Materials"},{"key":"2026092911083519500_cit62","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.70153","article-title":"Elucidating\nthe Charge-Separation and Oxidation Dynamics in Fluorenone-COF\/CdS\nS-Scheme Heterojunction for Photocatalytic Benzaldehyde and Hydrogen\nProduction","volume":"9","author":"Feng","year":"2026","journal-title":"Energy & Environmental Materials"},{"key":"2026092911083519500_cit63","doi-asserted-by":"publisher","first-page":"239","DOI":"10.1016\/S1872-2067(23)64477-8","article-title":"1D S-scheme heterojunction\nof urchin-like SiC-W18O49 for enhancing photocatalytic\nCO2 reduction","volume":"50","author":"Lin","year":"2023","journal-title":"Chinese Journal of\nCatalysis"},{"key":"2026092911083519500_cit64","doi-asserted-by":"publisher","first-page":"142","DOI":"10.1016\/j.jmst.2023.08.038","article-title":"A review of\nupdated S-scheme heterojunction photocatalysts","volume":"177","author":"Li","year":"2024","journal-title":"Journal of Materials Science & Technology"},{"key":"2026092911083519500_cit65","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202512163","article-title":"Enriched Oxygen Vacancy-Mediated\nEfficient Charge Transfer in S-Scheme ZnO-VO@Zn0.5Cd0.5S Heterojunction for Rapid U(VI) Removal From Nuclear\nWastewater","volume":"12","author":"Liu","year":"2025","journal-title":"Advanced Science"},{"key":"2026092911083519500_cit66","doi-asserted-by":"publisher","first-page":"167","DOI":"10.1016\/S1872-2067(22)64201-3","article-title":"S-scheme\nheterojunction of ZnCdS\nnanospheres and dibenzothiophene modified graphite carbon nitride\nfor enhanced H2 production","volume":"46","author":"Li","year":"2023","journal-title":"Chinese\nJournal of Catalysis"},{"key":"2026092911083519500_cit67","doi-asserted-by":"publisher","first-page":"147","DOI":"10.1016\/S1872-2067(25)64723-1","article-title":"Systematic assessment\nof emerging\ncontaminants elimination using an S-scheme Mn0.5Cd0.5S\/In2S3 photocatalyst: Degradation\npathways, toxicity evaluation and mechanistic analysis","volume":"75","author":"Ai","year":"2025","journal-title":"Chinese Journal of Catalysis"},{"key":"2026092911083519500_cit68","doi-asserted-by":"publisher","first-page":"2400934","DOI":"10.1002\/advs.202400934","article-title":"M\/BiOCl-(M = Pt, Pd,\nand Au) Boosted Selective Photocatalytic CO2 Reduction\nto C2 Hydrocarbons via *CHO Intermediate Manipulation","volume":"11","author":"Liu","year":"2024","journal-title":"Advanced Science"},{"key":"2026092911083519500_cit69","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.70150","article-title":"Enhanced\nPhotocatalytic Reduction of CO2 to Complete CO Mediated\nby Donor-Acceptor Covalent Organic Frameworks","volume":"9","author":"Li","year":"2026","journal-title":"Energy & Environmental Materials"},{"key":"2026092911083519500_cit70","doi-asserted-by":"publisher","first-page":"807","DOI":"10.1038\/s41929-024-01179-4","article-title":"Probing\nelectrolyte effects on cation-enhanced CO2 reduction on\ncopper in acidic media","volume":"7","author":"Zhang","year":"2024","journal-title":"Nature Catalysis"},{"key":"2026092911083519500_cit71","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418269","article-title":"A Highly\nConjugated Nickel(II)-Acetylide Framework for Efficient Photocatalytic\nCarbon Dioxide Reduction","volume":"64","author":"Qin","year":"2025","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026092911083519500_cit72","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1802256115","article-title":"On the origin of the elusive first\nintermediate of CO2 electroreduction","volume":"115","author":"Chernyshova","year":"2018","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"key":"2026092911083519500_cit73","doi-asserted-by":"publisher","first-page":"40174","DOI":"10.1039\/D5RA06450C","article-title":"Fabrication\nof a 3D\/0D S-scheme heterojunction based on ZnO nanoflowers and ZnIn2S4 nanoparticles with enhanced CO2 photoreduction\nperformance","volume":"15","author":"Wang","year":"2025","journal-title":"RSC Adv."},{"key":"2026092911083519500_cit74","doi-asserted-by":"publisher","first-page":"168965","DOI":"10.1016\/j.cej.2025.168965","article-title":"Electrochemical and photoelectrochemical\nCO2 reduction to hydrocarbons by a copper-based molecular\ncatalyst","volume":"524","author":"Wen","year":"2025","journal-title":"Chemical Engineering Journal"},{"key":"2026092911083519500_cit75","doi-asserted-by":"publisher","first-page":"1262","DOI":"10.1038\/s41560-025-01869-8","article-title":"Tandem amine scrubbing\nand CO2 electrolysis via direct piperazine carbamate reduction","volume":"10","author":"Li","year":"2025","journal-title":"Nature Energy"},{"key":"2026092911083519500_cit76","doi-asserted-by":"publisher","first-page":"30199","DOI":"10.1021\/acsami.3c04308","article-title":"Facet Engineering-Induced\nConstruction\nof Ni2P\/ZnIn2S4 Heterostructures\nfor Boosted Photocatalytic CO2 Reduction","volume":"15","author":"Song","year":"2023","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026092911083519500_cit77","doi-asserted-by":"publisher","first-page":"190","DOI":"10.1016\/S1872-2067(24)60066-5","article-title":"Molten salt construction of core-shell structured S-scheme CuInS2@CoS2 heterojunction to boost charge transfer for\nefficient photocatalytic CO2 reduction","volume":"63","author":"Wang","year":"2024","journal-title":"Chinese Journal of Catalysis"},{"key":"2026092911083519500_cit78","doi-asserted-by":"publisher","first-page":"239","DOI":"10.1038\/s41929-025-01301-0","article-title":"Electrified synthesis of n-propanol\nusing a dilute\nalloy catalyst","volume":"8","author":"Chen","year":"2025","journal-title":"Nature Catalysis"},{"key":"2026092911083519500_cit79","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411508","article-title":"Delocalized Orbitals\nover Metal Clusters\nand Organic Linkers Enable Boosted Charge Transfer in Metal-Organic\nFramework for Overall CO2 Photoreduction","volume":"63","author":"Liu","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026092911083519500_cit80","doi-asserted-by":"publisher","first-page":"124724","DOI":"10.1016\/j.apcatb.2024.124724","article-title":"Modulation of catalyst microenvironments\nin ZnIn2S4\/g-C3N4 S-scheme\nheterojunction for ratio-tunable syngas production from CO2 photoreduction","volume":"362","author":"Liu","year":"2025","journal-title":"Applied Catalysis B: Environment\nand Energy"},{"key":"2026092911083519500_cit81","doi-asserted-by":"publisher","first-page":"21807","DOI":"10.1021\/jacs.6c02677","article-title":"Thermal\nRegulation of CO2 Activation Pathways via Interfacial\nWater Restructuring Enables Ampere-Level, Near-Unity CO Electrosynthesis","volume":"148","author":"Li","year":"2026","journal-title":"J. Am. Chem. Soc."},{"key":"2026092911083519500_cit82","doi-asserted-by":"publisher","first-page":"2409031","DOI":"10.1002\/adfm.202409031","article-title":"Photocatalytic CO2-to-CH4 Conversion\nwith Ultrahigh Selectivity of 95.93% on S-Vacancy Modulated Spatial\nIn2S3\/In2O3 Heterojunction","volume":"34","author":"Lai","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"2026092911083519500_cit83","doi-asserted-by":"publisher","first-page":"124","DOI":"10.1016\/S1872-2067(24)60149-X","article-title":"LSPR-assisted W18O49\/ZnO S-scheme heterojunction\nfor efficient photocatalytic CO2 N-formylation of aniline","volume":"67","author":"Chen","year":"2024","journal-title":"Chinese Journal of Catalysis"}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.6c07948","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/38\/58112\/68492054\/acsomega.6c07948.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/11\/38\/58112\/68492054\/acsomega.6c07948.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T15:50:49Z","timestamp":1790697049000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/11\/38\/58112\/5428907\/Construction-of-a-0D-2D-S-Scheme-Heterojunction"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,12]]},"references-count":83,"journal-issue":{"issue":"38","published-online":{"date-parts":[[2026,9,12]]},"published-print":{"date-parts":[[2026,9,29]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.6c07948","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,12]]}}}