{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T10:16:27Z","timestamp":1788344187456,"version":"build-2803163510"},"reference-count":53,"publisher":"American Chemical Society (ACS)","issue":"7","license":[{"start":{"date-parts":[[2017,7,13]],"date-time":"2017-07-13T00:00:00Z","timestamp":1499904000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2017R1A2A1A05001484"],"award-info":[{"award-number":["2017R1A2A1A05001484"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2017,7,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Of the several electrochemical methods for pollutant degradation, the mediated electrooxidation (MEO) process is widely used. However, the MEO process utilizes only one (anodic) compartment toward pollutant degradation. To effectively utilize the full electrochemical cell, an improved electrolytic cell producing both oxidant and reductant mediators at their respective half-cells, which can be employed for treating two pollutants simultaneously, was investigated. The cathodic half-cell was studied first toward maximum [CoI(CN)5]4\u2013 (Co+) generation (21%) from a [CoII(CN)6]3\u2013 precursor by optimizing several experimental factors such as the electrolyte, cathode material, and orientation of the Nafion324 membrane. The anodic half-cell was optimized similarly for higher Co3(SO4)2 (Co3+) yields (41%) from a CoIISO4 precursor. The practical utility of the newly developed full cell setup, combining the optimized cathodic half-cell and optimized anodic half-cell, was demonstrated by electroscrubbing experiments with simultaneous dichloromethane removal by Co+ via the mediated electroreduction process and phenol removal by Co3+ via the MEO process, showing not only utilization of the full electrochemical cell, but also degradation of two different pollutants by the same applied current that was used in the conventional cell to remove only one pollutant.<\/jats:p>","DOI":"10.1021\/acsomega.7b00352","type":"journal-article","created":{"date-parts":[[2017,7,13]],"date-time":"2017-07-13T08:35:04Z","timestamp":1499934904000},"page":"3562-3571","source":"Crossref","is-referenced-by-count":10,"title":["Studies on Effective Generation of Mediators Simultaneously\nat Both Half-Cells for VOC Degradation by Mediated Electroreduction\nand Mediated Electrooxidation"],"prefix":"10.1021","volume":"2","author":[{"given":"Muthuraman","family":"Govindan","sequence":"first","affiliation":[{"name":"Sunchon National University , , , , ,","place":["Suncheon-si, Jeollanam-do, South Korea, 57922"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"K. Chandrasekara","family":"Pillai","sequence":"additional","affiliation":[{"name":"Sunchon National University , , , , ,","place":["Suncheon-si, Jeollanam-do, South Korea, 57922"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Balaji","family":"Subramanian","sequence":"additional","affiliation":[{"name":"Sunchon National University , , , , ,","place":["Suncheon-si, Jeollanam-do, South Korea, 57922"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8191-9662","authenticated-orcid":true,"given":"Il-Shik","family":"Moon","sequence":"additional","affiliation":[{"name":"Sunchon National University , , , , ,","place":["Suncheon-si, Jeollanam-do, South Korea, 57922"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2017,7,13]]},"reference":[{"key":"2026090205420610200_cit1","doi-asserted-by":"publisher","first-page":"244","DOI":"10.1021\/acscentsci.5b00227","article-title":"In Situ Electrochemical Oxidation\nTuning of Transition Metal Disulfides to Oxides for Enhanced Water\nOxidation","volume":"1","author":"Chen","year":"2015","journal-title":"ACS Cent. Sci."},{"key":"2026090205420610200_cit2","doi-asserted-by":"publisher","first-page":"6446","DOI":"10.1021\/cr1002326","article-title":"Solar Water Splitting Cells","volume":"110","author":"Walter","year":"2010","journal-title":"Chem. Rev."},{"key":"2026090205420610200_cit3","doi-asserted-by":"publisher","first-page":"277","DOI":"10.1016\/S1381-1169(00)00262-4","article-title":"Nafion\u2013RuO2\u2013Ru(bpy)32+ composite electrodes for efficient electrocatalytic\nwater oxidation","volume":"160","author":"Pillai","year":"2000","journal-title":"J. Mol. Catal. A: Chem."},{"key":"2026090205420610200_cit4","doi-asserted-by":"publisher","first-page":"234","DOI":"10.1021\/acscentsci.5b00163","article-title":"High-Potential Electrocatalytic\nO2 Reduction\nwith Nitroxyl\/NOx Mediators: Implications for Fuel Cells and Aerobic\nOxidation Catalysis","volume":"1","author":"Gerken","year":"2015","journal-title":"ACS Cent. Sci."},{"key":"2026090205420610200_cit5","doi-asserted-by":"publisher","first-page":"3400","DOI":"10.1002\/anie.200300630","article-title":"Palladium\nOxidase Catalysis: Selective Oxidation of Organic Chemicals by Direct\nDioxygen-Coupled Turnover","volume":"43","author":"Stahl","year":"2004","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026090205420610200_cit6","doi-asserted-by":"crossref","first-page":"1507","DOI":"10.1128\/aem.61.4.1507-1513.1995","article-title":"Characterization\nof a new pathway\nfor epichlorohydrin degradation by whole cells of Xanthobacter Strain Py2","volume":"61","author":"Small","year":"1995","journal-title":"Appl. Environ. Microbiol."},{"key":"2026090205420610200_cit7","doi-asserted-by":"crossref","first-page":"559","DOI":"10.1002\/9783527610426.bard090017","article-title":"Mediated\nElectron-Transfer\nbetween Redox-Enzymes and Electrode Supports","volume-title":"Encyclopedia of Electrochemistry","author":"Katz","year":"2002"},{"key":"2026090205420610200_cit8","doi-asserted-by":"publisher","first-page":"745","DOI":"10.1016\/j.snb.2006.03.048","article-title":"Direct amperometric\ndetermination of L-ascorbic acid (Vitamin C) at octacyanomolybdate-doped-poly(4-vinylpyridine)\nmodified electrode in fruit juice and pharmaceuticals","volume":"120","author":"Thangamuthu","year":"2007","journal-title":"Sens. Actuators, B"},{"key":"2026090205420610200_cit9","unstructured":"Global Environmental Facility.\n          , Report of United Nations Environmental Programme:\nOn Review of Emerging Innovative Technologies for the Destruction\nand Decontamination of POPs and the Identification of Promising Technologies\nfor Use in Developing Countries, Washington, DC, October 3\u20137, 2003."},{"key":"2026090205420610200_cit10","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1595\/003214090X3411014","article-title":"Electrochemical\ndestruction of toxic organic industrial waste","volume":"34","author":"Steele","year":"1990","journal-title":"Platinum Met. Rev."},{"key":"2026090205420610200_cit11","doi-asserted-by":"publisher","first-page":"654","DOI":"10.1149\/1.2069280","article-title":"Electrochemical treatment of mixed and hazardous wastes:\nOxidation of ethylene glycol and benzene by silver(II)","volume":"139","author":"Farmer","year":"1992","journal-title":"J. Electrochem. Soc."},{"key":"2026090205420610200_cit12","doi-asserted-by":"publisher","first-page":"846","DOI":"10.1007\/BF00772203","article-title":"Electrochemical\nmediators for total oxidation of chlorinated hydrocarbons: formation\nkinetics of Ag(II), Co(III), and Ce(IV)","volume":"25","author":"Bringmann","year":"1995","journal-title":"J.\nAppl. Electrochem."},{"key":"2026090205420610200_cit13","doi-asserted-by":"publisher","first-page":"230","DOI":"10.1002\/(SICI)1521-4125(200003)23:3&lt;230::AID-CEAT230&gt;3.0.CO;2-3","article-title":"Process for\ntotal degradation of organic wastes by mediated electrooxidation","volume":"23","author":"Galla","year":"2000","journal-title":"Chem. Eng. Technol."},{"key":"2026090205420610200_cit14","doi-asserted-by":"publisher","first-page":"191","DOI":"10.1021\/ie00026a003","article-title":"Simulation\nof NO, Scrubbing by Ceric\nSolutions: Oxidation of Nitrous Acid by Ce(1V) Species in Acidic Solutions","volume":"33","author":"Aurousseau","year":"1994","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026090205420610200_cit15","doi-asserted-by":"publisher","first-page":"1243","DOI":"10.1021\/ie950553w","article-title":"Scrubbing of sulfur\ndioxide using a cerium(IV)-containing acidic solution: A kinetic investigation","volume":"35","author":"Aurousseau","year":"1996","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026090205420610200_cit16","doi-asserted-by":"publisher","first-page":"43","DOI":"10.1205\/095758297528760","article-title":"A process\nfor the simultaneous removal of SO2 and NOx using\nCe(IV) redox catalysis","volume":"75","author":"Hoffmann","year":"1997","journal-title":"Process Saf. Environ.\nProt."},{"key":"2026090205420610200_cit17","doi-asserted-by":"publisher","first-page":"870","DOI":"10.1023\/A:1018489232316","article-title":"Oxidative\nseparation of nitrogen oxides from off-gases by electrochemical mediators","volume":"27","author":"Bringmann","year":"1997","journal-title":"J. Appl. Electrochem."},{"key":"2026090205420610200_cit18","doi-asserted-by":"publisher","first-page":"1423","DOI":"10.1016\/j.watres.2006.12.003","article-title":"Destruction of EDTA\nby mediated electrochemical oxidation process: Monitoring by continuous\nCO2 measurements","volume":"41","author":"Balaji","year":"2007","journal-title":"Water Res."},{"key":"2026090205420610200_cit19","doi-asserted-by":"publisher","first-page":"596","DOI":"10.1016\/j.jhazmat.2007.05.009","article-title":"Destruction\nof organic pollutants by cerium(IV) MEO process: A study on the influence\nof process conditions for EDTA mineralization","volume":"150","author":"Balaji","year":"2008","journal-title":"J. Hazard. Mater."},{"key":"2026090205420610200_cit20","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1016\/j.chemosphere.2007.05.050","article-title":"Mineralization of\nphenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic\nacid medium: A preliminary study","volume":"69","author":"Matheswaran","year":"2007","journal-title":"Chemosphere"},{"key":"2026090205420610200_cit21","first-page":"231","article-title":"Silver-Mediated\nElectrochemical Oxidation: Production of Silver (II) in Nitric Acid\nMedium and in situ Destruction of Phenol in Semi-batch Process","volume":"13","author":"Matheswaran","year":"2007","journal-title":"J. Ind. Eng. Chem."},{"key":"2026090205420610200_cit22","doi-asserted-by":"publisher","first-page":"7464","DOI":"10.1021\/es801174k","article-title":"Novel process for simultaneous removal\nof NOx and SO2 from simulated flue gas by using a sustainable\nAg(I)\/Ag(II) redox mediator","volume":"42","author":"Raju","year":"2008","journal-title":"Environ. Sci. Technol."},{"key":"2026090205420610200_cit23","doi-asserted-by":"publisher","first-page":"657","DOI":"10.1016\/j.chemosphere.2009.04.013","article-title":"Experimental\naspects of combined NOx and SO2 removal from flue-gas mixture\nin an integrated wet scrubber-electrochemical cell system","volume":"76","author":"Chandrasekara Pillai","year":"2009","journal-title":"Chemosphere"},{"key":"2026090205420610200_cit24","doi-asserted-by":"publisher","first-page":"156","DOI":"10.1016\/j.seppur.2008.10.030","article-title":"A sustainable environmentally friendly\nNOx removal process using Ag(II)\/Ag(I)-mediated electrochemical\noxidation","volume":"65","author":"Chung","year":"2009","journal-title":"Sep. Purif. Technol."},{"key":"2026090205420610200_cit25","doi-asserted-by":"publisher","first-page":"447","DOI":"10.1002\/jctb.2062","article-title":"Removal\nof H2S using a new Ce(IV) redox mediator by a mediated\nelectrochemical oxidation process","volume":"84","author":"Chandrasekara Pillai","year":"2009","journal-title":"J. Chem.\nTechnol. Biotechnol."},{"key":"2026090205420610200_cit26","doi-asserted-by":"publisher","first-page":"359","DOI":"10.1021\/co300012a","article-title":"Mineralization\nof Gaseous Acetaldehyde\nby Electrochemically Generated Co(III) in H2SO4 with Wet Scrubber Combinatorial System","volume":"14","author":"Govindan","year":"2012","journal-title":"ACS\nComb. Sci."},{"key":"2026090205420610200_cit27","doi-asserted-by":"publisher","first-page":"439","DOI":"10.1021\/co400046g","article-title":"Development\nof a Biphasic Electroreactor with a Wet Scrubbing System for the Removal\nof Gaseous Benzene","volume":"15","author":"Govindan","year":"2013","journal-title":"ACS Comb. Sci."},{"key":"2026090205420610200_cit28","doi-asserted-by":"publisher","first-page":"601","DOI":"10.1016\/j.cej.2012.08.017","article-title":"Removal of hydrogen\nsulfide through an electrochemically assisted scrubbing process using\nan active Co(III) catalyst at low temperatures","volume":"209","author":"Govindan","year":"2012","journal-title":"Chem. Eng. J."},{"key":"2026090205420610200_cit29","doi-asserted-by":"publisher","first-page":"1064","DOI":"10.1016\/j.jhazmat.2013.06.055","article-title":"A single catalyst\nof aqueous CoIII for deodorization\nof mixture odor gases: A development and reaction pathway study at\nelectro-scrubbing process","volume":"260","author":"Govindan","year":"2013","journal-title":"J. Hazard. Mater."},{"key":"2026090205420610200_cit30","doi-asserted-by":"publisher","first-page":"1364","DOI":"10.1021\/acssuschemeng.5b01383","article-title":"Sustainable Generation\nof a Homogeneous Ni(I) Catalyst\nin the Cathodic Compartment of a Divided Flow Electrolytic Cell for\nthe Degradation of Gaseous Carbon Tetrachloride by Electroscrubbing","volume":"4","author":"Govindan","year":"2016","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026090205420610200_cit31","doi-asserted-by":"publisher","first-page":"210","DOI":"10.1016\/j.jhazmat.2016.03.011","article-title":"Gaseous Trichloroethylene\nRemoval\nUsing an Electrochemically Generated Homogeneous Low-valent Ligand-free\nCo(I) Electrocatalyst by Electro-scrubbing","volume":"311","author":"Govindan","year":"2016","journal-title":"J. Hazard. Mater."},{"key":"2026090205420610200_cit32","doi-asserted-by":"publisher","first-page":"401","DOI":"10.1016\/S0022-328X(00)82420-1","article-title":"The catalysis of the\nelectrochemical reduction of alkyl\nbromides by nickel complexes: The formation of carbon-carbon bonds","volume":"186","author":"Gosden","year":"1980","journal-title":"J. Organomet. Chem."},{"key":"2026090205420610200_cit33","doi-asserted-by":"publisher","first-page":"3951","DOI":"10.1021\/ic00320a005","article-title":"Effect\nof steric crowding on the rates of reactions of a Nickel(1) tetraaza\nmacrocycle with organic halides and hydroperoxides","volume":"28","author":"Sadler","year":"1989","journal-title":"Inorg. Chem."},{"key":"2026090205420610200_cit34","doi-asserted-by":"publisher","first-page":"5397","DOI":"10.1021\/ja00224a026","article-title":"Reactions of the\nNickel(I) octaethylisobacteriochlorin\nanion with alkyl halides","volume":"110","author":"Stolzenberg","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"2026090205420610200_cit35","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1016\/0022-0728(92)80345-5","article-title":"In-situ electrogeneration of [2,2\u2032\nethylenebis(nitrilomethylidyne)diphenolato]\nnickelate(I)\u2013nickel(I) salen \u2013 as a catalyst for reductive\nintramolecular cyclizations of 6-iodo and 6-bromo-1-phenyl-1-hexyne","volume":"332","author":"Mubarak","year":"1992","journal-title":"J. Electroanal. Chem."},{"key":"2026090205420610200_cit36","doi-asserted-by":"publisher","first-page":"137","DOI":"10.1016\/S1381-1169(00)00546-X","article-title":"Surfactant\neffects on mediated electrocatalytic dechlorination\nof allylchloride","volume":"169","author":"Govindan","year":"2001","journal-title":"J. Mol. Catal. A: Chem."},{"key":"2026090205420610200_cit37","doi-asserted-by":"publisher","first-page":"687","DOI":"10.1016\/j.jcis.2005.11.010","article-title":"Dechlorination\nof \u03b2-methylallyl chloride by electrogenerated[Co(I)(bipyridine)3]+: An electrochemical study in the presence of\ncationic surfactants","volume":"297","author":"Govindan","year":"2006","journal-title":"J. Colloid Interface Sci."},{"key":"2026090205420610200_cit38","doi-asserted-by":"crossref","first-page":"8408","DOI":"10.1016\/S1452-3981(23)18003-5","article-title":"Electrochemical\nStability of Cu, Ni, Co, Pt and Ir Metals Sheet and Their Composite\nElectrodes in Potassium Hydroxide Solution","volume":"7","author":"Othman","year":"2012","journal-title":"Int. J. Electrochem. Sci."},{"key":"2026090205420610200_cit39","doi-asserted-by":"publisher","first-page":"828","DOI":"10.1038\/nchem.2032","article-title":"High-performance Ag-Co alloy catalysts\nfor electrochemical oxygen reduction","volume":"6","author":"Holewinski","year":"2014","journal-title":"Nat. Chem."},{"key":"2026090205420610200_cit40","doi-asserted-by":"publisher","first-page":"2578","DOI":"10.1002\/cphc.200600385","article-title":"First Principles\nand Experimental 1H NMR Signatures of Solvated Ions: The\nCase of HCl(aq)","volume":"7","author":"Murakhtina","year":"2006","journal-title":"Chem. Phys. Chem."},{"key":"2026090205420610200_cit41","doi-asserted-by":"publisher","first-page":"653","DOI":"10.3762\/bjnano.2.69","article-title":"How to remove the influence\nof trace\nwater from the absorption spectra of SWNTs dispersed in ionic liquids","volume":"2","author":"Yang","year":"2011","journal-title":"Beilstein J. Nanotechnol."},{"key":"2026090205420610200_cit42","doi-asserted-by":"publisher","first-page":"227","DOI":"10.1016\/j.psep.2014.06.008","article-title":"Uncovering results in electro-scrubbing process toward\ngreen methodology during environmental air pollutants removal","volume":"93","author":"Govindan","year":"2015","journal-title":"Process Saf. Environ."},{"key":"2026090205420610200_cit43","doi-asserted-by":"publisher","first-page":"3800","DOI":"10.1039\/C4CY00669K","article-title":"Developments and\nperspectives of oxide-based catalysts\nfor the oxygen evolution reaction","volume":"4","author":"Fabbri","year":"2014","journal-title":"Catal. Sci.\nTechnol."},{"key":"2026090205420610200_cit44","doi-asserted-by":"publisher","first-page":"47","DOI":"10.1039\/C29690000047","article-title":"Formation of the Pentacyanocobalt(1)\nIon in Highly Alkaline Solutions","author":"Hanzli\u0301k","year":"1969","journal-title":"J. Chem. Soc.\nD"},{"key":"2026090205420610200_cit45","first-page":"429","volume-title":"Electrochemical Methods,\nFundamentals and Applications","author":"Bard","year":"1980","edition":"1"},{"key":"2026090205420610200_cit46","first-page":"991","volume-title":"Modern Electrochemistry","author":"Bockris","year":"1977"},{"key":"2026090205420610200_cit47","doi-asserted-by":"publisher","first-page":"182","DOI":"10.1002\/elan.1140071216","article-title":"Behavior of\nCathodically Pretreated Platinum on Fe(CN)63\u2013 Electroreduction in KNO3: Dependence on Pretreatment","volume":"7","author":"Chandrasekara Pillai","year":"1995","journal-title":"Electroanalysis"},{"key":"2026090205420610200_cit48","doi-asserted-by":"publisher","first-page":"2151","DOI":"10.2166\/wst.2010.131","article-title":"Using RuO2 anode for chlorine dioxide production in an un-divided electrochemical\ncell","volume":"61","author":"Chandrasekara Pillai","year":"2010","journal-title":"Water Sci. Technol."},{"key":"2026090205420610200_cit49","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1007\/s10800-007-9405-2","article-title":"Electrochemical synthesis of peroxomonophosphate\nusing boron-doped diamond anodes","volume":"38","author":"Weiss","year":"2007","journal-title":"J. Appl. Electrochem."},{"key":"2026090205420610200_cit50","doi-asserted-by":"publisher","first-page":"701","DOI":"10.1016\/j.electacta.2009.09.039","article-title":"Electrochemical abatement\nof chloroethanes in water: Reduction, oxidation and combined processes","volume":"55","author":"Scialdone","year":"2010","journal-title":"Electrochim. Acta"},{"key":"2026090205420610200_cit51","doi-asserted-by":"publisher","first-page":"613","DOI":"10.1023\/A:1003202203067","article-title":"Electrochemical\nreduction of dichloromethane\nto higher hydrocarbons","volume":"28","author":"Kotsinaris","year":"1998","journal-title":"J. Appl. Electrochem."},{"key":"2026090205420610200_cit52","doi-asserted-by":"publisher","first-page":"4035","DOI":"10.1016\/j.electacta.2003.12.061","article-title":"Electrocatalysis on silver and silver\nalloys for dichloromethane\nand trichloromethane dehalogenation","volume":"49","author":"Rondinini","year":"2004","journal-title":"Electrochim.\nActa"},{"key":"2026090205420610200_cit53","doi-asserted-by":"publisher","first-page":"5710","DOI":"10.1021\/ja01156a063","article-title":"Exchange\nStudies with Complex Ions. III. The Nature of the Complex Formed between\nCobalt(II) and Potassium Cyanide, and its Exchange with Radiocyanide\nIon in Aqueous Solution","volume":"73","author":"Adamson","year":"1951","journal-title":"J. Am. Chem. Soc."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.7b00352","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/2\/7\/3562\/67677825\/acsomega.7b00352.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/2\/7\/3562\/67677825\/acsomega.7b00352.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T09:42:17Z","timestamp":1788342137000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/2\/7\/3562\/751042\/Studies-on-Effective-Generation-of-Mediators"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,7,13]]},"references-count":53,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2017,7,13]]},"published-print":{"date-parts":[[2017,7,31]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.7b00352","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,7,13]]}}}