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Selectivity toward dibenzylamine (DBA, 62% yield) was achieved by varying the amount of 1,4-butanediol in the catalytic system. A reaction mechanism was proposed, involving a ligand-assisted O\u2013H bond activation, end-on substrate coordination, and a key dihydrido-Ni(II) intermediate, leading to the in situ formation of primary imines and amines to ultimately yield the secondary imines observed.<\/jats:p>","DOI":"10.1021\/acsomega.7b00545","type":"journal-article","created":{"date-parts":[[2017,5,26]],"date-time":"2017-05-26T06:38:10Z","timestamp":1495780690000},"page":"2337-2343","source":"Crossref","is-referenced-by-count":36,"title":["Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles\nwith 2-Propanol and 1,4-Butanediol as the Hydrogen Source"],"prefix":"10.1021","volume":"2","author":[{"given":"Jorge A.","family":"Gardun\u0303o","sequence":"first","affiliation":[{"name":"Universidad Nacional Auto\u0301noma de Me\u0301xico , , ,","place":["Mexico City, Mexico, 04510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1839-1938","authenticated-orcid":true,"given":"Juventino J.","family":"Garci\u0301a","sequence":"additional","affiliation":[{"name":"Universidad Nacional Auto\u0301noma de Me\u0301xico , , ,","place":["Mexico City, Mexico, 04510"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2017,5,26]]},"reference":[{"key":"2026090317490004300_cit1a","doi-asserted-by":"publisher","first-page":"1037","DOI":"10.1002\/1615-4169(200212)344:10&lt;1037::aid-adsc1037&gt;3.0.co;2-3","volume":"344","author":"Gomez","year":"2002","journal-title":"Adv. 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