{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T06:15:45Z","timestamp":1788329745107,"version":"build-2803163510"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"1","license":[{"start":{"date-parts":[[2018,1,22]],"date-time":"2018-01-22T00:00:00Z","timestamp":1516579200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF-2017R1D1A1B03028214"],"award-info":[{"award-number":["NRF-2017R1D1A1B03028214"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF-2017R1D1A1B03029633"],"award-info":[{"award-number":["NRF-2017R1D1A1B03029633"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RE201606017"],"award-info":[{"award-number":["RE201606017"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,1,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>For a solid acid-catalyzed dehydration of biomass-derived carbohydrates into useful furan derivatives, a suitable porous solid acid catalyst having an optimum acidic density and its strength is required to avoid cascade reactions in biomass conversion processes. A large-pore mesoporous zirconium phosphate (m-ZrP) was prepared hydrothermally using P123 as a template in water solvent, which resulted in a higher pore diameter (&amp;gt;9 nm) having wormhole-like pore structures with balanced Lewis (L) to Bro\u0308nsted (B) acid sites. The effects of calcination temperature (500\u2013800 \u00b0C) on the textural, acidic\/basic, and structural properties of the m-ZrP with its catalytic performance for glucose dehydration to 5-hydroxymethylfurfural (HMF) were investigated in a pure water media as a green and sustainable alternative solvent. The larger number of L and B acid sites and basic sites with their appropriate strengths were clearly related with a better catalytic performance in terms of glucose conversion and HMF yield. The strong L acid and basic sites in the m-ZrP efficiently promoted the glucose isomerization to fructose, which dehydrated exclusively on the weak B acid sites resulting in a maximum conversion of glucose (83.8%) and HMF yield (46.6%). The adjusted acidic and basic sites with large mesopore sizes make the m-ZrP yield a higher reaction rate (2.78 mmol gcat\u20131 h\u20131) and turnover frequency (11.68\/h) for conversion of glucose to HMF, which showed higher catalytic activity than those of a small-pore m-ZrP and other mesoporous heterogeneous and homogeneous acid catalysts.<\/jats:p>","DOI":"10.1021\/acsomega.7b01357","type":"journal-article","created":{"date-parts":[[2018,1,22]],"date-time":"2018-01-22T14:51:45Z","timestamp":1516632705000},"page":"808-820","source":"Crossref","is-referenced-by-count":83,"title":["Aqueous Phase Synthesis of 5-Hydroxymethylfurfural\nfrom Glucose over Large Pore Mesoporous Zirconium Phosphates: Effect\nof Calcination Temperature"],"prefix":"10.1021","volume":"3","author":[{"given":"K.","family":"Saravanan","sequence":"first","affiliation":[{"name":"Sungkyunkwan University (SKKU) , , 2066 Seobu-ro , , ,","place":["Jangan-gu, Suwon, Gyeonggi-do, Republic of Korea, 16419"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kyung Soo","family":"Park","sequence":"additional","affiliation":[{"name":"Sungkyunkwan University (SKKU) , , 2066 Seobu-ro , , ,","place":["Jangan-gu, Suwon, Gyeonggi-do, Republic of Korea, 16419"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seongho","family":"Jeon","sequence":"additional","affiliation":[{"name":"Sungkyunkwan University (SKKU) , , 2066 Seobu-ro , , ,","place":["Jangan-gu, Suwon, Gyeonggi-do, Republic of Korea, 16419"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2959-520X","authenticated-orcid":true,"given":"Jong Wook","family":"Bae","sequence":"additional","affiliation":[{"name":"Sungkyunkwan University (SKKU) , , 2066 Seobu-ro , , ,","place":["Jangan-gu, Suwon, Gyeonggi-do, Republic of Korea, 16419"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,1,22]]},"reference":[{"key":"2026090201494038700_cit1","doi-asserted-by":"publisher","first-page":"494","DOI":"10.1016\/j.apcatb.2017.05.085","article-title":"Recent progress for direct synthesis\nof dimethyl ether from syngas on the heterogeneous bifunctional hybrid\ncatalysts","volume":"217","author":"Saravanan","year":"2017","journal-title":"Appl. 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