{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T19:28:22Z","timestamp":1789586902051,"version":"build-2803163510"},"reference-count":90,"publisher":"American Chemical Society (ACS)","issue":"1","license":[{"start":{"date-parts":[[2018,1,4]],"date-time":"2018-01-04T00:00:00Z","timestamp":1515024000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100004663","name":"Ministry of Science and Technology, Taiwan","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100004663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,1,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The effect of substitution on the potential energy surfaces of RB\u2261PR (R = H, F, OH, SiH3, and CH3) is studied using density functional theories (M06-2X\/Def2-TZVP, B3PW91\/Def2-TZVP, and B3LYP\/LANL2DZ+dp). There is significant theoretical evidence that RB\u2261PR compounds with smaller substituents are fleeting intermediates, so they would be difficult to be detected experimentally. These theoretical studies using the M06-2X\/Def2-TZVP method demonstrate that only the triply bonded R\u2032B\u2261PR\u2032 molecules bearing sterically bulky groups (R\u2032 = Tbt (=C6H2-2,4,6-{CH(SiMe3)2}3), SiMe(SitBu3)2, Ar* (=C6H3-2,6-(C6H2-2,4,6-i-Pr3)2), and SiiPrDis2) are significantly stabilized and can be isolated experimentally. Using the simple valence-electron bonding model and some sophisticated theories, the bonding character of R\u2032B\u2261PR\u2032 should be viewed as R\u2032BI PR\u2032. The present theoretical observations indicate that both the electronic and the steric effect of bulkier substituent ligands play a key role in making triply bonded R\u2032B\u2261PR\u2032 species synthetically accessible and isolable in a stable form.<\/jats:p>","DOI":"10.1021\/acsomega.7b01480","type":"journal-article","created":{"date-parts":[[2018,1,4]],"date-time":"2018-01-04T12:41:56Z","timestamp":1515069716000},"page":"76-85","source":"Crossref","is-referenced-by-count":16,"title":["Triple-Bonded Boron\u2261Phosphorus Molecule: Is\nThat Possible?"],"prefix":"10.1021","volume":"3","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6776-0889","authenticated-orcid":true,"given":"Jia-Syun","family":"Lu","sequence":"first","affiliation":[{"name":"National Chiayi University , , ,","place":["Chiayi, Taiwan, 60004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming-Chung","family":"Yang","sequence":"additional","affiliation":[{"name":"National Chiayi University , , ,","place":["Chiayi, Taiwan, 60004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5847-4271","authenticated-orcid":true,"given":"Ming-Der","family":"Su","sequence":"additional","affiliation":[{"name":"National Chiayi University , , ,","place":["Chiayi, Taiwan, 60004"]},{"name":"Kaohsiung Medical University , , ,","place":["Kaohsiung, Taiwan, 80708"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,1,4]]},"reference":[{"key":"2026090206581148000_cit1","doi-asserted-by":"publisher","first-page":"3463","DOI":"10.1021\/cr9408989","article-title":"\u03c0-Bonding\nand the Lone Pair Effect in Multiple Bonds between Heavier Main Group\nElements","volume":"99","author":"Power","year":"1999","journal-title":"Chem. 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