{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T08:17:19Z","timestamp":1788509839495,"version":"build-2803163510"},"reference-count":24,"publisher":"American Chemical Society (ACS)","issue":"2","license":[{"start":{"date-parts":[[2018,2,7]],"date-time":"2018-02-07T00:00:00Z","timestamp":1517961600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DEAC02-06CH11357"],"award-info":[{"award-number":["DEAC02-06CH11357"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,2,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Flame retardant tris(2-chloroethyl phosphate) (TCP) is successfully encapsulated in core\u2013shell poly(urea-formaldehyde) microcapsules by in situ polymerization. The microcapsules are electrochemically stable in lithium-ion (Li-ion) battery electrolytes and thermally stable to ca. 200 \u00b0C. Thermal triggering of these microcapsules at higher temperatures ruptures the shell wall, releasing the liquid core (flame retardant), and NMR spectroscopy confirms the presence of the flame retardant in the electrolyte solution. Li-ion pouch cell experiments demonstrate that microencapsulation of TCP and its incorporation into the battery electrolyte provide latent fire retardants that improve battery safety while maintaining inherent battery performance and cycling capability.<\/jats:p>","DOI":"10.1021\/acsomega.7b01950","type":"journal-article","created":{"date-parts":[[2018,2,7]],"date-time":"2018-02-07T14:07:17Z","timestamp":1518012437000},"page":"1609-1613","source":"Crossref","is-referenced-by-count":65,"title":["Core\u2013Shell Microcapsules Containing Flame Retardant\nTris(2-chloroethyl phosphate) for Lithium-Ion Battery Applications"],"prefix":"10.1021","volume":"3","author":[{"given":"Marta","family":"Baginska","sequence":"first","affiliation":[{"name":"University of Illinois Urbana-Champaign , , 306 Talbot Laboratory, 104 S. Wright Street , , ,","place":["Urbana, Illinois, United States, 61801"]},{"name":"University of Illinois Urbana-Champaign , , 405 N. Mathews Avenue , , ,","place":["Urbana, Illinois, United States, 61801"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5818-520X","authenticated-orcid":true,"given":"Nancy R.","family":"Sottos","sequence":"additional","affiliation":[{"name":"University of Illinois Urbana-Champaign , , Materials Science and Engineering Building, 1304 W. Green Street , , ,","place":["Urbana, Illinois, United States, 61801"]},{"name":"University of Illinois Urbana-Champaign , , 405 N. Mathews Avenue , , ,","place":["Urbana, Illinois, United States, 61801"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0831-9097","authenticated-orcid":true,"given":"Scott R.","family":"White","sequence":"additional","affiliation":[{"name":"University of Illinois Urbana-Champaign , , 306 Talbot Laboratory, 104 S. Wright Street , , ,","place":["Urbana, Illinois, United States, 61801"]},{"name":"University of Illinois Urbana-Champaign , , 405 N. Mathews Avenue , , ,","place":["Urbana, Illinois, United States, 61801"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,2,7]]},"reference":[{"key":"2026090319080441000_cit1","doi-asserted-by":"publisher","first-page":"166","DOI":"10.1016\/S0378-7753(02)00537-2","article-title":"Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent\nfor nonflammable electrolytes in Li-ion batteries","volume":"113","author":"Zhang","year":"2003","journal-title":"J. Power Sources"},{"key":"2026090319080441000_cit2","doi-asserted-by":"publisher","first-page":"648","DOI":"10.1016\/j.jpowsour.2006.04.088","article-title":"Diagnostic examination\nof thermally abused high-power lithium-ion\ncells","volume":"161","author":"Abraham","year":"2006","journal-title":"J. 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