{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T12:17:20Z","timestamp":1788351440856,"version":"build-2803163510"},"reference-count":36,"publisher":"American Chemical Society (ACS)","issue":"6","license":[{"start":{"date-parts":[[2018,6,25]],"date-time":"2018-06-25T00:00:00Z","timestamp":1529884800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100002338","name":"Ministry of Education of the People's Republic of China","doi-asserted-by":"publisher","award":["3142017065"],"award-info":[{"award-number":["3142017065"]}],"id":[{"id":"10.13039\/501100002338","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005064","name":"Hebei Province Science and Technology Support Program","doi-asserted-by":"publisher","award":["17211225"],"award-info":[{"award-number":["17211225"]}],"id":[{"id":"10.13039\/501100005064","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Key Laboratory of Mine Disaster Prevention and Control in Hebei Province","doi-asserted-by":"publisher","award":["KJZH2017K12"],"award-info":[{"award-number":["KJZH2017K12"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,6,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A novel microencapsulated intumescent flame retardant (TMAPP) was prepared, in which ammonium polyphosphate (APP) is the core and functions as an acid source, melamine\u2013urea formaldehyde (MUF) resin is in the intermediate layer and functions as a blowing agent, and ferric tannin (mimicking mussel) is in the outermost shell layer and functions as a carbonization agent and also as a smoke inhibitor and surface modifier. TMAPP was prepared by treating MUF-microencapsulated APP with tannin acid and FeCl3. Its structure is characterized by Fourier transform infrared, elemental analysis, and thermogravimetry (TG). TMAPP in epoxy was evaluated for its effect on flame retardancy and mechanical properties. The flame-retardant and smoke suppression performances of EP\/TMAPP were studied using cone calorimetry (CONE) and limit oxygen index, and the flame-retardant mechanism was investigated by scanning electron microscopy and TG. The resultant data indicate that EP\/TMAPP has very good mechanical properties, flame retardancy, and smoke suppression, whose char residue and thermal stability are increased, and the initial decomposition temperatures are decreased. Meanwhile, the char residue structures were very intumescent and compact. The char residue effectively prevents the underlying materials of EP\/TMAPP from further combustion.<\/jats:p>","DOI":"10.1021\/acsomega.8b00364","type":"journal-article","created":{"date-parts":[[2018,6,25]],"date-time":"2018-06-25T13:50:06Z","timestamp":1529934606000},"page":"6888-6894","source":"Crossref","is-referenced-by-count":23,"title":["Design, Preparation, and Application of a Novel, Microencapsulated,\nIntumescent, Flame-Retardant-Based Mimicking Mussel"],"prefix":"10.1021","volume":"3","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7936-9895","authenticated-orcid":true,"given":"Ming","family":"Gao","sequence":"first","affiliation":[{"name":"North China Institute of Science and Technology , , Box 206, Yanjiao, ,","place":["Beijing, China, 101601"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shun","family":"Chen","sequence":"additional","affiliation":[{"name":"North China Institute of Science and Technology , , Box 206, Yanjiao, ,","place":["Beijing, China, 101601"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Wang","sequence":"additional","affiliation":[{"name":"North China Institute of Science and Technology , , Box 206, Yanjiao, ,","place":["Beijing, China, 101601"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihua","family":"Chai","sequence":"additional","affiliation":[{"name":"North China Institute of Science and Technology , , Box 206, Yanjiao, ,","place":["Beijing, China, 101601"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,6,25]]},"reference":[{"key":"2026090207353647100_cit1","doi-asserted-by":"publisher","first-page":"42016","DOI":"10.1002\/app.42016","article-title":"Flame retardancy and mechanical properties\nof pet-based composites containing phosphorus and boron-based additives","volume":"132","author":"Kilinc","year":"2015","journal-title":"J. Appl. Polym. Sci."},{"key":"2026090207353647100_cit2","doi-asserted-by":"publisher","first-page":"9","DOI":"10.1002\/mame.201500250","article-title":"Flame Retardancy\nof Polymers: The\nRole of Specific Reactions in the Condensed Phase","volume":"301","author":"Schartel","year":"2016","journal-title":"Macromol. Mater. Eng."},{"key":"2026090207353647100_cit3","doi-asserted-by":"publisher","first-page":"971","DOI":"10.1002\/pat.3715","article-title":"Effect of Fe3O4-doped sepiolite\non the flammability and thermal\ndegradation properties of epoxy composites","volume":"28","author":"Liu","year":"2017","journal-title":"Polym. Adv. Technol."},{"key":"2026090207353647100_cit4","doi-asserted-by":"publisher","first-page":"2375","DOI":"10.1021\/acssuschemeng.6b02712","article-title":"Regulating\nEffects of Nitrogenous Bases on the Char\nStructure and Flame Retardancy of Polypropylene\/Intumescent Flame\nRetardant Composites","volume":"5","author":"Wang","year":"2017","journal-title":"ACS Sustainable Chem.\nEng."},{"key":"2026090207353647100_cit5","doi-asserted-by":"publisher","first-page":"7363","DOI":"10.1021\/am500789q","article-title":"An Efficient Mono-Component\nPolymeric Intumescent Flame\nRetardant for Polypropylene: Preparation and Application","volume":"6","author":"Shao","year":"2014","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026090207353647100_cit6","doi-asserted-by":"publisher","first-page":"2047","DOI":"10.1021\/ie101737n","article-title":"Flame-Retardant Effect of Sepiolite on an Intumescent\nFlame-Retardant Polypropylene System","volume":"50","author":"Liu","year":"2011","journal-title":"Ind. Eng.\nChem. Res."},{"key":"2026090207353647100_cit7","doi-asserted-by":"publisher","first-page":"2312","DOI":"10.1002\/pc.23813","article-title":"Surface Microencapsulated Ammonium\nPolyphosphate With Beta-Cyclodextrin\nand Its Application in Wood-Flour\/Polypropylene Composites","volume":"38","author":"Wang","year":"2017","journal-title":"Polym. Compos."},{"key":"2026090207353647100_cit8","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1016\/j.reactfunctpolym.2005.05.004","article-title":"Microencapsulation\nof ammonium phosphate with a polyurethane shell part I: Coacervation\ntechnique","volume":"64","author":"Saihi","year":"2005","journal-title":"React. Funct. Polym."},{"key":"2026090207353647100_cit9","doi-asserted-by":"publisher","first-page":"1042","DOI":"10.1016\/j.compscitech.2012.03.022","article-title":"Preparation of silane precursor microencapsulated\nintumescent flame\nretardant and its enhancement on the properties of ethylene\u2013vinyl\nacetate copolymer cable","volume":"72","author":"Wang","year":"2012","journal-title":"Compos. Sci. Technol."},{"key":"2026090207353647100_cit10","doi-asserted-by":"publisher","first-page":"163","DOI":"10.1002\/pc.20289","article-title":"Synthesis of in situ\nencapsulated intumescent flame retardant and\nthe flame retardancy in polypropylene","volume":"28","author":"Liu","year":"2007","journal-title":"Polym.\nCompos."},{"key":"2026090207353647100_cit11","doi-asserted-by":"publisher","first-page":"1382","DOI":"10.1016\/j.polymdegradstab.2011.03.016","article-title":"The influence of KH-550\non properties of ammonium polyphosphate and polypropylene flame retardant\ncomposites","volume":"96","author":"Lin","year":"2011","journal-title":"Polym. Degrad. Stab."},{"key":"2026090207353647100_cit12","doi-asserted-by":"publisher","first-page":"36","DOI":"10.1002\/app.38661","article-title":"Microencapsulation of APP-I and influence\nof microencapsulated APP-I\non microstructure and flame retardancy of PP\/APP-I\/PER composites","volume":"129","author":"Zhou","year":"2013","journal-title":"J. Appl. Polym. Sci."},{"key":"2026090207353647100_cit13","doi-asserted-by":"publisher","first-page":"3960","DOI":"10.1021\/ma0703002","article-title":"Simplified\npolymer mimics of cross-linking\nadhesive proteins","volume":"40","author":"Westwood","year":"2007","journal-title":"Macromolecules"},{"key":"2026090207353647100_cit14","doi-asserted-by":"publisher","first-page":"2042","DOI":"10.1016\/j.compscitech.2008.02.036","article-title":"Mimicking mussel adhesion to improve interfacial properties\nin composites","volume":"68","author":"Hamming","year":"2008","journal-title":"Compos. Sci. Technol."},{"key":"2026090207353647100_cit15","doi-asserted-by":"publisher","first-page":"276","DOI":"10.1016\/j.cbpa.2009.11.009","article-title":"Marine\nbioinorganic materials: mussels pumping iron","volume":"14","author":"Wilker","year":"2010","journal-title":"Curr. Opin. Chem. 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Mater."},{"key":"2026090207353647100_cit18","doi-asserted-by":"publisher","first-page":"1744","DOI":"10.1002\/smll.201503662","article-title":"Pathogen-Mimicking\nPolymeric Nanoparticles based on Dopamine Polymerization as Vaccines\nAdjuvants Induce Robust Humoral and Cellular Immune Responses","volume":"12","author":"Liu","year":"2016","journal-title":"Small"},{"key":"2026090207353647100_cit19","doi-asserted-by":"publisher","first-page":"630","DOI":"10.1002\/psc.2776","article-title":"Adsorption\nof chemically synthesized mussel adhesive peptide sequences containing\nDOPA on stainless steel","volume":"21","author":"Chandrasekaran","year":"2015","journal-title":"J. Pept. Sci."},{"key":"2026090207353647100_cit20","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1002\/maco.201307277","article-title":"Tannic acid as corrosion inhibitor for metals and alloys","volume":"66","author":"Kusmierek","year":"2015","journal-title":"Mater. Corros."},{"key":"2026090207353647100_cit21","doi-asserted-by":"publisher","first-page":"1765","DOI":"10.1002\/app.37787","article-title":"Adsorption characteristics\nof tannic acid onto the novel protonated\npalygorskite\/chitosan resin microspheres","volume":"127","author":"Wu","year":"2013","journal-title":"J.\nAppl. Polym. Sci."},{"key":"2026090207353647100_cit22","first-page":"37","article-title":"Study on\nComplexation Properties of Black Wattle Tannin with Metals Ions","volume":"27","author":"Su","year":"2007","journal-title":"Chem. Ind. For. Prod."},{"key":"2026090207353647100_cit23","doi-asserted-by":"publisher","first-page":"854","DOI":"10.1002\/pc.20459","article-title":"Microencapsulation of Ammonium Polyphosphate:\nPreparation, Characterization, and Its Flame Retardance in Polypropylene","volume":"29","author":"Wu","year":"2008","journal-title":"Polym. 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Technol."},{"key":"2026090207353647100_cit26","doi-asserted-by":"publisher","first-page":"95","DOI":"10.1002\/pol.1978.170160110","article-title":"Influence of the fire retardant,\nammonium polyphosphate, on the thermal degradation of poly(methyl\nmethacrylate)","volume":"16","author":"Camino","year":"1978","journal-title":"J. Polym. Sci., Polym. Chem.\nEd."},{"key":"2026090207353647100_cit27","doi-asserted-by":"publisher","first-page":"715","DOI":"10.1002\/pc.22715","article-title":"Co-microencapsulation\nof ammonium polyphosphate and aluminum hydroxide\nin halogen-free and intumescent flame retarding polypropylene","volume":"35","author":"Zheng","year":"2014","journal-title":"Polym. 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Pyrolysis"},{"key":"2026090207353647100_cit30","doi-asserted-by":"publisher","first-page":"339","DOI":"10.1016\/j.jaap.2011.07.007","article-title":"A novel zinc\nchelate complex containing both phosphorus and nitrogen for improving\nthe flame retardancy of low density polyethylene","volume":"92","author":"Cao","year":"2011","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"2026090207353647100_cit31","doi-asserted-by":"publisher","first-page":"9","DOI":"10.1016\/j.polymdegradstab.2007.11.002","article-title":"Synergistic effects\nof lanthanum oxide on a novel intumescent flame retardant polypropylene\nsystem","volume":"93","author":"Li","year":"2008","journal-title":"Polym. Degrad. Stab."},{"key":"2026090207353647100_cit32","doi-asserted-by":"publisher","first-page":"1493","DOI":"10.1007\/s10973-015-4424-4","article-title":"Smoke suppression\nproperties of fumed silica on flame-retardant thermoplastic polyurethane\nbased on ammonium polyphosphate","volume":"120","author":"Chen","year":"2015","journal-title":"J. Therm. Anal.\nCalorim."},{"key":"2026090207353647100_cit33","doi-asserted-by":"publisher","first-page":"1895","DOI":"10.1002\/app.41681","article-title":"Flame retardancy\nand mechanical properties of ferrum ammonium phosphate\u2013halloysite\/epoxy\npolymer nanocomposites","volume":"132","author":"Dong","year":"2015","journal-title":"J. Appl. Polym. Sci."},{"key":"2026090207353647100_cit34","doi-asserted-by":"publisher","first-page":"4505","DOI":"10.1007\/s10853-005-0855-9","article-title":"Synthesis and properties of polystyrene\/Fe-montmorillonite\nnanocomposites using synthetic Fe-montmorillonite by bulk polymerization","volume":"40","author":"Kong","year":"2005","journal-title":"J. Mater. Sci."},{"key":"2026090207353647100_cit35","doi-asserted-by":"publisher","first-page":"2422","DOI":"10.1021\/acssuschemeng.6b00112","article-title":"Fabrication\nof green lignin-based flame retardants for enhancing the thermal and\nfire retardancy properties of polypropylene\/wood composites","volume":"4","author":"Liu","year":"2016","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026090207353647100_cit36","doi-asserted-by":"publisher","first-page":"4732","DOI":"10.1021\/acssuschemeng.6b00955","article-title":"Converting\nIndustrial Alkali Lignin to Biobased Functional Additives for Improving\nFire Behavior and Smoke Suppression of Polybutylene Succinate\u201d","volume":"4","author":"Liu","year":"2016","journal-title":"ACS Sustainable Chem. Eng."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.8b00364","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/3\/6\/6888\/67711341\/acsomega.8b00364.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/3\/6\/6888\/67711341\/acsomega.8b00364.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T11:35:47Z","timestamp":1788348947000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/3\/6\/6888\/744851\/Design-Preparation-and-Application-of-a-Novel"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,6,25]]},"references-count":36,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2018,6,25]]},"published-print":{"date-parts":[[2018,6,30]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.8b00364","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,6,25]]}}}