{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T09:13:14Z","timestamp":1788513194143,"version":"build-2803163510"},"reference-count":34,"publisher":"American Chemical Society (ACS)","issue":"5","license":[{"start":{"date-parts":[[2018,5,9]],"date-time":"2018-05-09T00:00:00Z","timestamp":1525824000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccbyncnd_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100005416","name":"Norges Forskningsr\u00e5d","doi-asserted-by":"publisher","award":["231086"],"award-info":[{"award-number":["231086"]}],"id":[{"id":"10.13039\/501100005416","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005416","name":"Norges Forskningsr\u00e5d","doi-asserted-by":"publisher","award":["262229"],"award-info":[{"award-number":["262229"]}],"id":[{"id":"10.13039\/501100005416","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,5,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Although rather delicate on account of their propensity to undergo deiodination, \u03b2-octaiodoporphyrinoids are of considerable interest as potential precursors to novel \u03b2-octasubstituted macrocycles. Presented herein are early results of our efforts to synthesize \u03b2-octaiodocorrole derivatives. Oxidative condensation of 3,4-diiodopyrrole and aromatic aldehydes failed to yield free-base octaiodocorroles. Treatment of copper meso-tris(p-cyanophenyl)corrole with N-iodosuccinimide and trifluoroacetic acid over several hours, however, yielded the desired \u03b2-octaiodinated product in \u223c22% yield. Single-crystal X-ray structure determination of the product revealed a strongly saddled corrole macrocycle with metrical parameters very close to those of analogous Cu octabromocorrole complexes. The compound was also found to exhibit an exceptionally red-shifted Soret maximum (464 nm in dichloromethane), underscoring the remarkable electronic effect of \u03b2-octaiodo substitution.<\/jats:p>","DOI":"10.1021\/acsomega.8b00616","type":"journal-article","created":{"date-parts":[[2018,5,9]],"date-time":"2018-05-09T13:41:06Z","timestamp":1525873266000},"page":"5106-5110","source":"Crossref","is-referenced-by-count":12,"title":["Synthesis and Molecular Structure of a Copper Octaiodocorrole"],"prefix":"10.1021","volume":"3","author":[{"given":"Ivar K.","family":"Thomassen","sequence":"first","affiliation":[{"name":"UiT-The Arctic University of Norway , , ,","place":["Troms\u00f8, Norway, N-9037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6634-4717","authenticated-orcid":true,"given":"Laura J.","family":"McCormick","sequence":"additional","affiliation":[{"name":"Lawrence Berkeley National Laboratory , , , ,","place":["Berkeley, California, United States, 94720-8229"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1161-6364","authenticated-orcid":true,"given":"Abhik","family":"Ghosh","sequence":"additional","affiliation":[{"name":"UiT-The Arctic University of Norway , , ,","place":["Troms\u00f8, Norway, N-9037"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,5,9]]},"reference":[{"key":"2026090322125531500_cit1","first-page":"31","article-title":"Polyhaloporphyrins: Unusual Ligands for Metals and Metal-Catalyzed\nOxidations","volume":"27","author":"Dolphin","year":"1998","journal-title":"Acc. 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