{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T09:12:46Z","timestamp":1788513166421,"version":"build-2803163510"},"reference-count":64,"publisher":"American Chemical Society (ACS)","issue":"7","license":[{"start":{"date-parts":[[2018,7,17]],"date-time":"2018-07-17T00:00:00Z","timestamp":1531785600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018978","name":"Indian Institute of Technology Ropar","doi-asserted-by":"crossref","award":["9-35\/2009\/IITRPR\/43"],"award-info":[{"award-number":["9-35\/2009\/IITRPR\/43"]}],"id":[{"id":"10.13039\/501100018978","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,7,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Selective catalytic oxidation of carbohydrate-derived 5-hydroxymethylfurfural, furfuryl alcohol, and various aromatic and aliphatic compounds to the corresponding aldehyde is a challenging task. The development of a sustainable heterogeneous catalyst is crucial in achieving high selectivity for the desired aldehyde, especially using O2 or air. In this study, a RuO2-supported Mn3O4 catalyst is reported for the selective oxidation reaction. Treatment of MnO2 molecular sieves with RuCl3 in aqueous formaldehyde solution gives a new type of RuO2-supported Mn3O4 catalyst. Detailed catalyst characterization using powder X-ray diffraction, N2 adsorption, scanning and transmission electron microscopes, diffuse reflectance UV\u2013visible spectrometer, and X-ray photoelectron spectroscopy proves that the RuO2 species are dispersed on the highly crystalline Mn3O4 surface. This catalytic conversion process involves molecular oxygen or air (flow, 10 mL\/min) as an oxidant. No external oxidizing reagent, additive, or cocatalyst is required to carry out this transformation. This oxidation protocol affords 2,5-diformylfuran, 2-formylfuran, and other aromatic and aliphatic aldehydes in good to excellent yield (70\u201399%). Moreover, the catalyst is easily recycled and reused without any loss in the catalytic activity.<\/jats:p>","DOI":"10.1021\/acsomega.8b01009","type":"journal-article","created":{"date-parts":[[2018,7,17]],"date-time":"2018-07-17T09:27:28Z","timestamp":1531819648000},"page":"7944-7954","source":"Crossref","is-referenced-by-count":39,"title":["Selective Oxidation of Biomass-Derived Alcohols and Aromatic and Aliphatic Alcohols\nto Aldehydes with O2\/Air Using a RuO2-Supported\nMn3O4 Catalyst"],"prefix":"10.1021","volume":"3","author":[{"given":"Bhaskar","family":"Sarmah","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Ropar , , ,","place":["Rupnagar, India, 140001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1175-7562","authenticated-orcid":true,"given":"Biswarup","family":"Satpati","sequence":"additional","affiliation":[{"name":"Saha Institute of Nuclear Physics , , 1\/AF, Bidhannagar , ,","place":["Kolkata, India, 700 064"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2271-5376","authenticated-orcid":true,"given":"Rajendra","family":"Srivastava","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Ropar , , ,","place":["Rupnagar, India, 140001"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,7,17]]},"reference":[{"key":"2026090322102476900_cit1","doi-asserted-by":"publisher","first-page":"559","DOI":"10.1021\/cr00035a006","article-title":"Inorganic\nsolid acids and their use in acid-catalyzed hydrocarbon reactions","volume":"95","author":"Corma","year":"1995","journal-title":"Chem. 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