{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T12:22:18Z","timestamp":1788524538709,"version":"build-2803163510"},"reference-count":29,"publisher":"American Chemical Society (ACS)","issue":"12","license":[{"start":{"date-parts":[[2018,12,24]],"date-time":"2018-12-24T00:00:00Z","timestamp":1545609600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,12,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Graphene has attracted lots of researchers attention because of its remarkable conductivity in both electrically and thermally. However, it has poor dispersibility in organic solvents which limited its applications. Polymers with aromatic end group which act as an intercalator were prepared by ring-opening polymerization with \u03b5-caprolactone by utilizing 1-naphthalene methanol (1-NM) as an initiator. These intercalators will exist between graphene oxide (GO) sheets to prevent aggregation via interactions. The attachment of 1-NM on polymer chains was supported by ultraviolet\u2013visible spectra, size exclusion chromatography profiles, and 1H nuclear magnetic resonance spectra. Exfoliated structured functionalized GO (fGO)\/polycaprolactone (PCL) (synthesized fGO) nanocomposites that dispersed well in acetone, chloroform, N,N-dimethylformamide, dimethyl sulfoxide, tetrahydrofuran, and toluene were successfully synthesized. This agreed well with the enlarged interlayer spacing in the optimized fGO as compared to that of GO from density functional theory simulations using the DMol3 module that implemented in the Materials Studio 6.0. Furthermore, its potential to be applied as green electronics in electronics, aerospace, and automotive industries was presented, by trailering the thermal conductivity enhancement from the incorporation of fGO\/PCL with commercialized biodegradable polymers, PCL, and poly[(R)-3-hydroxybutyric acid].<\/jats:p>","DOI":"10.1021\/acsomega.8b02478","type":"journal-article","created":{"date-parts":[[2018,12,24]],"date-time":"2018-12-24T10:01:53Z","timestamp":1545645713000},"page":"18124-18131","source":"Crossref","is-referenced-by-count":15,"title":["Development of Organo-Dispersible Graphene Oxide via\nPseudo-Surface Modification\nfor Thermally Conductive Green Polymer Composites"],"prefix":"10.1021","volume":"3","author":[{"given":"Siewteng","family":"Sim","sequence":"first","affiliation":[{"name":"Kyushu Institute of Technology , , 2-4 Hibikino , Wakamatsu-ku, , ,","place":["Kitakyushu, Fukuoka, Japan, 808-0196"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3839-0705","authenticated-orcid":true,"given":"Yoshito","family":"Andou","sequence":"additional","affiliation":[{"name":"Kyushu Institute of Technology , , 2-4 Hibikino , Wakamatsu-ku, , ,","place":["Kitakyushu, Fukuoka, Japan, 808-0196"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hamra A. A.","family":"Bashid","sequence":"additional","affiliation":[{"name":"Universiti Putra Malaysia , , UPM, , ,","place":["Serdang, Selangor, Malaysia, 43400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2436-8953","authenticated-orcid":true,"given":"Hongngee","family":"Lim","sequence":"additional","affiliation":[{"name":"Universiti Putra Malaysia , , UPM, , ,","place":["Serdang, Selangor, Malaysia, 43400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2832-3886","authenticated-orcid":true,"given":"Mohammednoor","family":"Altarawneh","sequence":"additional","affiliation":[{"name":"Murdoch University , , 90 South Street , , ,","place":["Murdoch, Western Australia, Australia, 6150"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4221-6841","authenticated-orcid":true,"given":"Zhongtao","family":"Jiang","sequence":"additional","affiliation":[{"name":"Murdoch University , , 90 South Street , , ,","place":["Murdoch, Western Australia, Australia, 6150"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kubra","family":"Eksiler","sequence":"additional","affiliation":[{"name":"Kyushu Institute of Technology , , 2-4 Hibikino , Wakamatsu-ku, , ,","place":["Kitakyushu, Fukuoka, Japan, 808-0196"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5186-4058","authenticated-orcid":true,"given":"Satoshi","family":"Iikubo","sequence":"additional","affiliation":[{"name":"Kyushu Institute of Technology , , 2-4 Hibikino , Wakamatsu-ku, , ,","place":["Kitakyushu, Fukuoka, Japan, 808-0196"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,12,24]]},"reference":[{"key":"2026090407153660900_cit1","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1126\/science.1157996","article-title":"Measurement of the elastic properties\nand intrinsic strength of monolayer graphene","volume":"321","author":"Lee","year":"2008","journal-title":"Science"},{"key":"2026090407153660900_cit2","doi-asserted-by":"publisher","first-page":"491","DOI":"10.1038\/nnano.2008.199","article-title":"Approaching ballistic\ntransport in suspended graphene","volume":"3","author":"Du","year":"2008","journal-title":"Nat. Nanotechnol."},{"key":"2026090407153660900_cit3","doi-asserted-by":"publisher","first-page":"902","DOI":"10.1021\/nl0731872","article-title":"Superior thermal\nconductivity of\nsingle-layer graphene","volume":"8","author":"Balandin","year":"2008","journal-title":"Nano Lett."},{"key":"2026090407153660900_cit4","doi-asserted-by":"publisher","first-page":"2458","DOI":"10.1021\/nl801457b","article-title":"Impermeable atomic\nmembranes from graphene sheets","volume":"8","author":"Bunch","year":"2008","journal-title":"Nano Lett."},{"key":"2026090407153660900_cit5","doi-asserted-by":"publisher","first-page":"914","DOI":"10.1016\/j.progpolymsci.2010.11.004","article-title":"Thermal conductivity of carbon nanotubes and their polymer nanocomposites:\nA review","volume":"36","author":"Han","year":"2011","journal-title":"Prog. Polym. Sci."},{"key":"2026090407153660900_cit6","doi-asserted-by":"crossref","first-page":"110","DOI":"10.1002\/9783527672790","volume-title":"Functionalization\nof Graphene","author":"Georgakilas","year":"2014"},{"key":"2026090407153660900_cit7","doi-asserted-by":"publisher","first-page":"1880","DOI":"10.1002\/app.26503","article-title":"Synthesis\nand characterization of poly(\u03b5-caprolactone)-graphite\noxide composites","volume":"106","author":"Hua","year":"2007","journal-title":"J. Appl. Polym. Sci."},{"key":"2026090407153660900_cit8","doi-asserted-by":"publisher","first-page":"29","DOI":"10.1016\/j.compositesa.2016.04.011","article-title":"Review of functionalization,\nstructure and properties of graphene\/polymer composite fibers","volume":"87","author":"Ji","year":"2016","journal-title":"Composites, Part A"},{"key":"2026090407153660900_cit9","doi-asserted-by":"publisher","first-page":"3301","DOI":"10.1039\/c0jm02708a","article-title":"graphene\nfilled polymer nanocomposites","volume":"21","author":"Verdejo","year":"2011","journal-title":"J. Mater. Chem."},{"key":"2026090407153660900_cit10","doi-asserted-by":"publisher","first-page":"160","DOI":"10.1016\/j.compscitech.2016.04.029","article-title":"Massive enhancement\nin the thermal conductivity of polymer composites by trapping graphene\nat the interface of a polymer blend","volume":"129","author":"Huang","year":"2016","journal-title":"Compos.\nSci. Technol."},{"key":"2026090407153660900_cit11","doi-asserted-by":"publisher","first-page":"5","DOI":"10.1016\/j.polymer.2010.11.042","article-title":"Graphene-based polymer\nnanocomposites","volume":"52","author":"Potts","year":"2011","journal-title":"Polymer"},{"key":"2026090407153660900_cit12","doi-asserted-by":"publisher","first-page":"186","DOI":"10.1016\/j.compscitech.2008.09.039","article-title":"graphite oxide\/poly(methyl\nmethacrylate)\nnanocomposites prepared by a novel method utilizing macroazoinitiator","volume":"69","author":"Jang","year":"2009","journal-title":"Compos. Sci. Technol."},{"key":"2026090407153660900_cit13","doi-asserted-by":"publisher","first-page":"2219","DOI":"10.1007\/s00289-011-0676-8","article-title":"Ring-opening\npolymerization of cyclic esters in the presence of choline\/SnOct2\ncatalytic system","volume":"68","author":"Sobczak","year":"2011","journal-title":"Polym. Bull."},{"key":"2026090407153660900_cit14","doi-asserted-by":"publisher","first-page":"5974","DOI":"10.1021\/ma021795s","article-title":"Physically\ncontrolled radical polymerization of vaporized vinyl monomers on surfaces.\nSynthesis of block copolymers of methyl methacrylate and styrene with\na conventional free radical initiator","volume":"36","author":"Yasutake","year":"2003","journal-title":"Macromolecules"},{"key":"2026090407153660900_cit15","doi-asserted-by":"publisher","first-page":"012036","DOI":"10.1088\/1757-899x\/139\/1\/012036","article-title":"A molecular dynamics study on the\ninteraction between epoxy and functionalized graphene sheets","volume":"139","author":"Melro","year":"2016","journal-title":"IOP Conf. Ser.: Mater. Sci. Eng."},{"key":"2026090407153660900_cit16","doi-asserted-by":"publisher","first-page":"130","DOI":"10.1080\/10584587.2013.788966","article-title":"Molecular\ndynamics simulation of interactions on graphene\/polypyrrole nanocomposites\ninterface","volume":"145","author":"Jia","year":"2013","journal-title":"Integr. Ferroelectr."},{"key":"2026090407153660900_cit17","doi-asserted-by":"publisher","first-page":"3208","DOI":"10.1021\/la903188a","article-title":"Measurement\nof multicomponent solubility parameters for graphene facilitates solvent\ndiscovery","volume":"26","author":"Hernandez","year":"2010","journal-title":"Langmuir"},{"key":"2026090407153660900_cit18","doi-asserted-by":"publisher","first-page":"10560","DOI":"10.1021\/la801744a","article-title":"Graphene\noxide dispersions in organic solvents","volume":"24","author":"Paredes","year":"2008","journal-title":"Langmuir"},{"key":"2026090407153660900_cit19","doi-asserted-by":"publisher","first-page":"1063","DOI":"10.1007\/s10853-007-2210-9","article-title":"Structural and morphological\nchanges in poly(caprolactone)\/poly(vinyl chloride) blends caused by\nUV irradiation","volume":"43","author":"Martins-Franchetti","year":"2007","journal-title":"J. Mater. Sci."},{"key":"2026090407153660900_cit20","doi-asserted-by":"publisher","first-page":"6966","DOI":"10.1021\/acsami.5b00937","article-title":"Preparation,\ncharacterization, and antibacterial activity of silver nanoparticle-decorated\ngraphene oxide nanocomposite","volume":"7","author":"Shao","year":"2015","journal-title":"ACS Appl. Mater.\nInterfaces"},{"key":"2026090407153660900_cit21","doi-asserted-by":"publisher","first-page":"95","DOI":"10.12691\/wjee-3-4-1","article-title":"Kinetic thermal degradation of cellulose, polybutylene succinate\nand a green composite: Comparative study","volume":"3","author":"Abderrahim","year":"2015","journal-title":"World\nJ. Environ. Eng."},{"key":"2026090407153660900_cit22","doi-asserted-by":"publisher","first-page":"3578","DOI":"10.1039\/c5ra19954a","article-title":"Synthesis\nand characterization of graphene and functionalized graphene via chemical\nand thermal treatment methods","volume":"6","author":"Dehghanzad","year":"2016","journal-title":"RSC Adv."},{"key":"2026090407153660900_cit23","doi-asserted-by":"publisher","first-page":"25","DOI":"10.1016\/j.tca.2015.05.005","article-title":"Crystallization of Poly(\u03f5-caprolactone) composites with graphite\nnanoplatelets: Relations between nucleation and platelet thickness","volume":"612","author":"Lv","year":"2015","journal-title":"Thermochim. Acta"},{"key":"2026090407153660900_cit24","doi-asserted-by":"publisher","first-page":"41915","DOI":"10.1002\/app.41915","article-title":"Effects of polycaprolactone\nmolecular weights on thermal and mechanical properties of polybenzoxazine","volume":"132","author":"Tiptipakorn","year":"2015","journal-title":"J. Appl. Polym. Sci."},{"key":"2026090407153660900_cit25","doi-asserted-by":"publisher","first-page":"75","DOI":"10.4236\/msce.2015.35009","article-title":"Graphite nanoplatelets\ncomposite materials: Role of the epoxy-system in the thermal conductivity","volume":"03","author":"Diaz-Chacon","year":"2015","journal-title":"J. Mater. Sci. Chem. Eng."},{"key":"2026090407153660900_cit26","doi-asserted-by":"publisher","first-page":"344","DOI":"10.1002\/er.3247","article-title":"Fabrication\nof flexible polypyrrole\/graphene oxide\/manganese oxide supercapacitor","volume":"39","author":"Ng","year":"2014","journal-title":"Int. J. Energy Res."},{"key":"2026090407153660900_cit27","doi-asserted-by":"publisher","first-page":"040802","DOI":"10.1115\/1.4034605","article-title":"Measurement\ntechniques for thermal conductivity and interfacial thermal conductance\nof bulk and thin film materials","volume":"138","author":"Zhao","year":"2016","journal-title":"J. Electron.\nPackag."},{"key":"2026090407153660900_cit28","doi-asserted-by":"publisher","first-page":"7441","DOI":"10.1039\/c6tb00746e","article-title":"Molecular simulation of pH-dependent\ndiffusion, loading, and release of doxorubicin in graphene and graphene\noxide drug delivery systems","volume":"4","author":"Mahdavi","year":"2016","journal-title":"J. Mater. Chem.\nB"},{"key":"2026090407153660900_cit29","doi-asserted-by":"publisher","first-page":"8352","DOI":"10.1039\/c5cp06569k","article-title":"Exploration\nof nanoporous graphene membranes for the separation of N2 from CO2:\na multi-scale computational study","volume":"18","author":"Wang","year":"2016","journal-title":"Phys. Chem.\nChem. Phys."}],"container-title":["ACS Omega"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsomega.8b02478","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/3\/12\/18124\/68367362\/acsomega.8b02478.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/acsodf\/article-pdf\/3\/12\/18124\/68367362\/acsomega.8b02478.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T12:11:11Z","timestamp":1788523871000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/acsodf\/article\/3\/12\/18124\/1574495\/Development-of-Organo-Dispersible-Graphene-Oxide"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,12,24]]},"references-count":29,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2018,12,24]]},"published-print":{"date-parts":[[2018,12,31]]}},"URL":"https:\/\/doi.org\/10.1021\/acsomega.8b02478","relation":{},"ISSN":["2470-1343"],"issn-type":[{"value":"2470-1343","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,12,24]]}}}