{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T12:15:18Z","timestamp":1788524118698,"version":"build-2803163510"},"reference-count":89,"publisher":"American Chemical Society (ACS)","issue":"12","license":[{"start":{"date-parts":[[2018,12,5]],"date-time":"2018-12-05T00:00:00Z","timestamp":1543968000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["SB\/S1\/IC-108\/2014"],"award-info":[{"award-number":["SB\/S1\/IC-108\/2014"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001409","name":"Department of Science and Technology, Ministry of Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001409","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,12,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>In this article, the synthesis, structural studies, and luminescence properties of CuI, AgI, and AuI complexes of pyrimidine-based phosphine [C4H3N2-2-NH(CH2PPh2)] (1) are described. The reactions of 1 with CuX led to the isolation of one-dimensional (1D) chain, tetranuclear ladder, or cyclic derivatives. The structural features of these complexes are greatly influenced by the metal-to-ligand ratio, reaction conditions, and CuX (X = Cl, Br or I) employed. In the case of CuCl and CuBr, one-dimensional coordination polymers [{CuCl}{C4H3N2-2-NH(CH2PPh2)}]\u221e (2) and [{CuBr}{C4H3N2-2-NH(CH2PPh2)}]\u221e (3) were obtained, whereas CuI afforded tetracopper complex [{CuI}4{C4H3N2-2-NH(CH2PPh2)}2(NCCH3)2] (4) having Cu4 ladder structure supported by P\u2229N-bridging coordination of 1. The reaction of 1 with AgOTf yielded unprecedented one-dimensional chain structure [{AgOTf}{C4H3N2-2-NH(CH2PPh2)}]\u221e (5), whereas the reaction with AgBF4 produced a 12-membered dinuclear complex, [{Ag}{C4H3N2-2-NH(CH2PPh2)}]2[BF4]2 (6), with each silver atom having a linear geometry. Gold complex [{AuCl}{C4H3N2-2-NH(CH2PPh2)}]2 (7) was synthesized by reacting 1 with [AuCl(SMe2)]. Compounds 2\u20134 were also prepared using a pestle and mortar by grinding method in almost quantitative yield. Complex 4 with a Cu\u00b7\u00b7\u00b7Cu distance of 2.828(5) \u00c5 shows high luminescence due to the nonbonded metal\u00b7\u00b7\u00b7metal interactions.<\/jats:p>","DOI":"10.1021\/acsomega.8b02484","type":"journal-article","created":{"date-parts":[[2018,12,5]],"date-time":"2018-12-05T09:35:23Z","timestamp":1544002523000},"page":"16601-16614","source":"Crossref","is-referenced-by-count":30,"title":["Diverse Architectures and Luminescence Properties\nof Group 11 Complexes Containing Pyrimidine-Based Phosphine,\n                    <i>N<\/i>\n                    -((Diphenylphosphine)methyl)pyrimidin-2-amine"],"prefix":"10.1021","volume":"3","author":[{"given":"Saurabh","family":"Kumar","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Bombay , , Powai, ,","place":["Mumbai, India, 400076"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dipanjan","family":"Mondal","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Bombay , , Powai, ,","place":["Mumbai, India, 400076"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3736-6148","authenticated-orcid":true,"given":"Maravanji S.","family":"Balakrishna","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Bombay , , Powai, ,","place":["Mumbai, India, 400076"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,12,5]]},"reference":[{"key":"2026090407165802600_cit1","doi-asserted-by":"publisher","first-page":"636","DOI":"10.1016\/j.ccr.2015.03.022","article-title":"Luminescent\nCopper(I) Complexes with\nHalogenido-Bridged Dimeric Core","volume":"306","author":"Tsuge","year":"2016","journal-title":"Coord. 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