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The present report provides a mild, catalytic method that couples thioamides and donor\/acceptor-substituted diazocarbonyl compounds to form enamino esters and enaminones. Unlike traditional methods for the synthesis of enamino esters and enaminones from thioamides, both N-alkyl thioamides and thiocarbamates are suitable substrates in this coupling reaction. Copper(I) bromide catalyzes the reaction and provides enamino esters and enaminones chemo- and diastereoselectively in less time than Rh2(OAc)4 or Ru(PPh3)3Cl2 catalysts.<\/jats:p>","DOI":"10.1021\/acsomega.8b02633","type":"journal-article","created":{"date-parts":[[2019,1,4]],"date-time":"2019-01-04T13:10:16Z","timestamp":1546607416000},"page":"269-280","source":"Crossref","is-referenced-by-count":14,"title":["Copper-Catalyzed Coupling of Thioamides and Donor\/Acceptor-Substituted\nCarbenoids: Synthesis of Enamino Esters and Enaminones"],"prefix":"10.1021","volume":"4","author":[{"given":"Arpan","family":"Pal","sequence":"first","affiliation":[{"name":"The University of Tulsa , , 800 S. Tucker Dr. , , ,","place":["Tulsa, Oklahoma, United States, 74104"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5425-3332","authenticated-orcid":true,"given":"Syed Raziullah","family":"Hussaini","sequence":"additional","affiliation":[{"name":"The University of Tulsa , , 800 S. Tucker Dr. , , ,","place":["Tulsa, Oklahoma, United States, 74104"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,1,4]]},"reference":[{"key":"2026090318092261200_cit1","doi-asserted-by":"publisher","first-page":"979","DOI":"10.1351\/pac199971060979","article-title":"Enaminones:\nversatile intermediates for natural product\nsynthesis","volume":"71","author":"Michael","year":"1999","journal-title":"Pure Appl. 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