{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T17:18:07Z","timestamp":1788542287812,"version":"build-2803163510"},"reference-count":43,"publisher":"American Chemical Society (ACS)","issue":"2","license":[{"start":{"date-parts":[[2019,2,26]],"date-time":"2019-02-26T00:00:00Z","timestamp":1551139200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2019,2,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>We report a selective and sensitive nanosensor probe based on polyethylenimine (PEI)-capped downconverting nanophosphors \u03b2-NaYF4:Gd3+,Tb3+@PEI for the detection of 2,4,6-trinitrotoluene (TNT), both in water and buffer media. These downconverting phosphors were synthesized via a hydrothermal route and are known to show excellent chemical, thermal, and photostability. They emit sharp emission peaks centered at \u223c488, 544, 584, and 619 nm, among which the peak at \u223c544 nm was remarkably quenched (\u223c90%) by the addition of TNT without giving any new emission peak. The sensing mechanism is based on the formation of a Meisenheimer complex between the electron-rich amine-functionalized \u03b2-NaYF4:Gd3+,Tb3+ nanophosphors and electron-deficient TNT molecule, which was prominently visualized by the change in the color of the solution from whitish to brownish yellow, enabling visual detection, followed by luminescence resonance energy transfer between the nanophosphors and the complex. A linear range for TNT detection was obtained from 0.1 to 300 \u03bcM with a limit of detection as low as 119.9 nM. This method displayed excellent selectivity toward TNT over other nitroaromatic compounds, which had no influence on the detection. Moreover, various other classes of analytes, viz., amino acids, pesticides, and sugars, did not quench the luminescence intensity of the nanophosphors. This developed nanosensor probe possesses high, stable fluorescence brightness and capability for the selective and sensitive on-site recognition of TNT molecules in aqueous media, avoiding complicated strategies and instruments. Thus, this work promises to pave ways to many applications in the detection of ultratrace analytes.<\/jats:p>","DOI":"10.1021\/acsomega.8b03491","type":"journal-article","created":{"date-parts":[[2019,2,26]],"date-time":"2019-02-26T19:05:48Z","timestamp":1551207948000},"page":"4259-4268","source":"Crossref","is-referenced-by-count":22,"title":["Downconversion Luminescence-Based Nanosensor for Label-Free Detection\nof Explosives"],"prefix":"10.1021","volume":"4","author":[{"given":"Monika","family":"Malik","sequence":"first","affiliation":[{"name":"CSIR-National Chemical Laboratory , , ,","place":["Pune, India, 411008"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , Anusandhan Bhawan, 2, Rafi Marg , ,","place":["New Delhi, India, 110001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Preeti","family":"Padhye","sequence":"additional","affiliation":[{"name":"CSIR-National Chemical Laboratory , , ,","place":["Pune, India, 411008"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , Anusandhan Bhawan, 2, Rafi Marg , ,","place":["New Delhi, India, 110001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2273-588X","authenticated-orcid":true,"given":"Pankaj","family":"Poddar","sequence":"additional","affiliation":[{"name":"CSIR-National Chemical Laboratory , , ,","place":["Pune, India, 411008"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , Anusandhan Bhawan, 2, Rafi Marg , ,","place":["New Delhi, India, 110001"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,2,26]]},"reference":[{"key":"2026090411090906200_cit1","doi-asserted-by":"publisher","first-page":"2343","DOI":"10.1021\/cr4001594","article-title":"Recent Progress in Rare Earth Micro\/Nanocrystals: Soft Chemical Synthesis,\nLuminescent Properties, and Biomedical Applications","volume":"114","author":"Gai","year":"2014","journal-title":"Chem. 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