{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T15:10:52Z","timestamp":1789657852513,"version":"4.0.1"},"reference-count":45,"publisher":"American Chemical Society (ACS)","issue":"4","license":[{"start":{"date-parts":[[2019,4,18]],"date-time":"2019-04-18T00:00:00Z","timestamp":1555545600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20140969"],"award-info":[{"award-number":["BK20140969"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012246","name":"Priority Academic Program Development of Jiangsu Higher Education Institutions","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100012246","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Jiangsu Key Laboratory of Biomass Energy and Materials, Chinese Academy of Forestry","award":["JSBEM201915"],"award-info":[{"award-number":["JSBEM201915"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2019,4,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Selective synthesis of various versatile compounds from biomass is of great importance to displace traditional fossil fuel resources. Here, homogeneous metal nitrate (M(NO3)x)\/(2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and M(NO3)x\/TEMPO\/NaNO2 catalyst systems in glacial acetic acid and acetonitrile, respectively, have been found to be highly active and practically sustainable for selective oxidation of 5-hydroxymethylfurfural (HMF) into 2,5-diformylfuran (DFF) using pure O2 or even O2 in air as the oxidant. The catalytic methods enable full HMF conversion with a nearly 100% DFF selectivity at 50 \u00b0C under atmospheric pressure using a very simple reaction setup and workup. Mechanistic aspects are discussed. The influences of reaction conditions such as different metal catalysts, catalyst loading, solvents, and reaction temperature on the promotion effect were studied. Meanwhile, the catalyst systems had also good performance for aerobic oxidation of other alcohols.<\/jats:p>","DOI":"10.1021\/acsomega.9b00391","type":"journal-article","created":{"date-parts":[[2019,4,18]],"date-time":"2019-04-18T12:35:36Z","timestamp":1555590936000},"page":"7054-7060","source":"Crossref","is-referenced-by-count":54,"title":["Metal Nitrate Catalysis for Selective Oxidation of\n5-Hydroxymethylfurfural into 2,5-Diformylfuran under Oxygen\nAtmosphere"],"prefix":"10.1021","volume":"4","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6098-0368","authenticated-orcid":true,"given":"Mei","family":"Hong","sequence":"first","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]},{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Min","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuangyan","family":"Wu","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huangui","family":"Cui","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxin","family":"Zhao","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiatong","family":"Li","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shifa","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]},{"name":"Nanjing Forestry University , , ,","place":["Nanjing, People\u2019s Republic of China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,4,18]]},"reference":[{"key":"2026090408091845500_cit1","doi-asserted-by":"publisher","first-page":"1938","DOI":"10.1039\/C5GC02188J","article-title":"Evaluation of transition metal phosphides\nsupported on ordered mesoporous materials as catalysts for phenol\nhydrodeoxygenation","volume":"18","author":"Berenguer","year":"2016","journal-title":"Green Chem."},{"key":"2026090408091845500_cit2","doi-asserted-by":"publisher","first-page":"171","DOI":"10.1016\/j.cattod.2015.12.009","article-title":"Lamellar and pillared ZSM-5 zeolites\nmodified with MgO and ZnO for catalytic fast-pyrolysis of eucalyptus\nwoodchips","volume":"277","author":"Fermoso","year":"2016","journal-title":"Catal. 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Synth. Catal."},{"key":"2026090408091845500_cit34","doi-asserted-by":"publisher","first-page":"758","DOI":"10.1002\/cctc.201301081","article-title":"Fe3O4@ SiO2-TEMPO as a magnetically recyclable catalyst\nfor highly selective\naerobic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran\nunder Metal- and halogen-free conditions","volume":"6","author":"Karimi","year":"2014","journal-title":"ChemCatChem"},{"key":"2026090408091845500_cit35","doi-asserted-by":"publisher","first-page":"3008","DOI":"10.1039\/C7CY00463J","article-title":"Polymers from\nbiomass: one pot two-step synthesis of furilydenepropanenitrile derivatives\nwith MIL-100(Fe) catalyst","volume":"7","author":"Rapeyko","year":"2017","journal-title":"Catal. Sci. 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A: Chem."},{"key":"2026090408091845500_cit45","doi-asserted-by":"publisher","first-page":"2616","DOI":"10.1002\/anie.201711531","article-title":"Silver(I)-catalyzed widely applicable\naerobic 1,2-diol oxidative cleavage","volume":"57","author":"Zhou","year":"2018","journal-title":"Angew.\nChem., Int. 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