{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T19:13:11Z","timestamp":1788549191624,"version":"build-2803163510"},"reference-count":75,"publisher":"American Chemical Society (ACS)","issue":"4","license":[{"start":{"date-parts":[[2019,4,29]],"date-time":"2019-04-29T00:00:00Z","timestamp":1556496000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2019,4,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>In this work, a series of three copper(II) metal-organic frameworks (MOFs), [Cu(4,4\u2032-DP)Cl]n (1), [Cu(4,4\u2032-DP)0.5Cl]n (2), and [Cu(4,4\u2032-TMDP)Cl]n (3) (4,4\u2032-DP = 4,4\u2032-dipyridyl, 4,4\u2032-TMDP = 4,4\u2032-trimethylenedipyridyl), is designed and synthesized under solvothermal conditions. Crystallographic investigations reveal that 1 and 2 have tetrahedral and 3 has octahedral environment around the Cu(II) ion. By varying the solvent conditions and ligand derivatives, the topology can be interestingly tuned. TOPOS Pro provides topological conclusions that 1 is stabilized by unusual 2D + 2D \u2192 3D polycatenation of layers lying in (110) and (11\u03050) planes with dihedral angle of 90\u00b0 showing altogether fes, hcb, and sql topologies. On the other hand, 2 exhibits a bey (3,4-c net) topology and 3 shows 4-fold interpenetration with the dia topology. The dc measurements for 1\u20133 performed on polycrystalline samples in a 0.1 T field confirm strong ferromagnetic behaviors for 1 and 2 and moderate antiferromagnetic behavior for 3. To examine the sensing properties of the three MOFs, various hazardous nitroaromatic compounds (NACs) were used as analytes. While 1 is a potent fluorescence sensor for highly sensitive detection of multiple NACs, 2 selectively detects meta-dinitrobenzene (m-DNB) with KSV = 5.73 \u00d7 105 M\u20131 and a remarkably lower limit of detection (LOD) value of 1.23 \u00d7 10\u20137 M. 3 does not show sensing ability toward any NAC probably due to the coordination environment being different from those in 1 and 2. The work demonstrates fine-tuning of the topology and in turn magnetic and sensing properties by changing the reaction conditions.<\/jats:p>","DOI":"10.1021\/acsomega.9b00715","type":"journal-article","created":{"date-parts":[[2019,4,29]],"date-time":"2019-04-29T06:36:13Z","timestamp":1556519773000},"page":"7738-7749","source":"Crossref","is-referenced-by-count":71,"title":["Cu(II) MOFs Based on Bipyridyls: Topology, Magnetism,\nand Exploring Sensing Ability toward Multiple Nitroaromatic Explosives"],"prefix":"10.1021","volume":"4","author":[{"given":"M. Naqi","family":"Ahamad","sequence":"first","affiliation":[{"name":"Aligarh Muslim University , , ,","place":["Aligarh, India, 202002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3817-0286","authenticated-orcid":true,"given":"M.","family":"Shahid","sequence":"additional","affiliation":[{"name":"Aligarh Muslim University , , ,","place":["Aligarh, India, 202002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7446-0232","authenticated-orcid":true,"given":"Musheer","family":"Ahmad","sequence":"additional","affiliation":[{"name":"Aligarh Muslim University , , ,","place":["Aligarh, India, 202002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Farasha","family":"Sama","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Kanpur , , ,","place":["Kanpur, India, 208016"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,4,29]]},"reference":[{"key":"2026090414081456800_cit1a","doi-asserted-by":"publisher","first-page":"1213","DOI":"10.1039\/b903811f","article-title":"The Pervasive\nChemistry of Metal-Organic\nFrameworks","volume":"38","author":"Long","year":"2009","journal-title":"Chem. 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