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Their structures have been characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy (IR), thermogravimetric analysis, and powder X-ray diffraction. Compounds 1 and 2 are supramolecular isomeric frameworks without consideration of the solvent molecules. Complex 1 exhibits a binodal (3, 5)-connected two-dimensional (2D) layer structure with the point (Schla\u0308fli) symbol of (52\u00b76)(55\u00b764\u00b77), while complex 2 shows a 2D + 2D \u2192 3D (three-dimensional) framework. Complex 3 is a (3, 5, 6)-connected tetranodal 3D net with the point (Schla\u0308fli) symbol of (4\u00b782)2(45\u00b76\u00b784)2(45\u00b765)2(48\u00b766\u00b78). Compound 4 is a (3, 3, 8)-connected trinodal 3D net with the point (Schla\u0308fli) symbol based on a binuclear [Cd2N2O] subunit, while 5 is a 2-nodal (3, 4)-connected 2D V2O5-type network based on [Cd2N2(COO)2] SBU. The studies of molecular sensing properties show that the luminescent MOFs can be employed as fluorescent sensors for the detection of Fe3+ and nitro compounds. Compound 1 and 3 exhibit quenching responses for Fe3+ in dimethylformamide solution with detection limits of 2.3 \u00d7 10\u20136 and 8.6 \u00d7 10\u20137 M, respectively. Meanwhile, compound 5 can sense 4-nitrophenol with a detection limit as low as 5.75 \u00d7 10\u20137 M.<\/jats:p>","DOI":"10.1021\/acsomega.9b01108","type":"journal-article","created":{"date-parts":[[2019,7,2]],"date-time":"2019-07-02T15:10:11Z","timestamp":1562080211000},"page":"11540-11553","source":"Crossref","is-referenced-by-count":41,"title":["Series of Cadmium(II) Coordination Polymers Based\non a Versatile Multi-N-Donor Tecton or Mixed Carboxylate Ligands:\nSynthesis, Structure, and Selectively Sensing Property"],"prefix":"10.1021","volume":"4","author":[{"given":"Xing-Zhe","family":"Guo","sequence":"first","affiliation":[{"name":"Fuyang Normal University , , ,","place":["Fuyang, China, 236041"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0404-5444","authenticated-orcid":true,"given":"Shui-Sheng","family":"Chen","sequence":"additional","affiliation":[{"name":"Fuyang Normal University , , ,","place":["Fuyang, China, 236041"]},{"name":"Nanjing University , , ,","place":["Nanjing, China, 210093"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei-Dong","family":"Li","sequence":"additional","affiliation":[{"name":"Fuyang Normal University , , ,","place":["Fuyang, China, 236041"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuai-Shuai","family":"Han","sequence":"additional","affiliation":[{"name":"Fuyang Normal University , , ,","place":["Fuyang, China, 236041"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Deng","sequence":"additional","affiliation":[{"name":"Fuyang Normal University , , ,","place":["Fuyang, China, 236041"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Qiao","sequence":"additional","affiliation":[{"name":"Fuyang Normal University , , ,","place":["Fuyang, China, 236041"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6094-4087","authenticated-orcid":true,"given":"Yue","family":"Zhao","sequence":"additional","affiliation":[{"name":"Nanjing University , , ,","place":["Nanjing, China, 210093"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,7,2]]},"reference":[{"key":"2026090317493628200_cit1","doi-asserted-by":"publisher","first-page":"907","DOI":"10.1093\/nsr\/nwx127","article-title":"Controlling\nflexibility of metal\u2013organic frameworks","volume":"5","author":"Zhang","year":"2018","journal-title":"Natl. 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