{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T16:19:39Z","timestamp":1780330779157,"version":"3.54.1"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"1","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ACS Appl. Mater. Interfaces"],"published-print":{"date-parts":[[2011,1,26]]},"DOI":"10.1021\/am1008584","type":"journal-article","created":{"date-parts":[[2010,12,31]],"date-time":"2010-12-31T15:33:15Z","timestamp":1293809595000},"page":"58-66","source":"Crossref","is-referenced-by-count":110,"title":["Photoelectrochemical Characterization of Nanocrystalline Thin-Film Cu<sub>2<\/sub>ZnSnS<sub>4<\/sub> Photocathodes"],"prefix":"10.1021","volume":"3","author":[{"given":"Shannon C.","family":"Riha","sequence":"first","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States, and Department of Chemistry and School of Energy Resources, University of Wyoming, Laramie, Wyoming 82071, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sarah J.","family":"Fredrick","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States, and Department of Chemistry and School of Energy Resources, University of Wyoming, Laramie, Wyoming 82071, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Justin B.","family":"Sambur","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States, and Department of Chemistry and School of Energy Resources, University of Wyoming, Laramie, Wyoming 82071, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuejiao","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States, and Department of Chemistry and School of Energy Resources, University of Wyoming, Laramie, Wyoming 82071, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amy L.","family":"Prieto","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States, and Department of Chemistry and School of Energy Resources, University of Wyoming, Laramie, Wyoming 82071, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"B. A.","family":"Parkinson","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States, and Department of Chemistry and School of Energy Resources, University of Wyoming, Laramie, Wyoming 82071, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2010,12,31]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1557\/mrs2008.71","volume":"33","author":"Ginley D.","year":"2008","journal-title":"MRS Bull."},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"1772","DOI":"10.1002\/pssb.200879539","volume":"245","author":"Scragg J. J.","year":"2008","journal-title":"Phys. Status Solidi B"},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"2072","DOI":"10.1021\/es8019534","volume":"43","author":"Wadia C.","year":"2009","journal-title":"J. Environ. Sci. Technol."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"5997","DOI":"10.1016\/j.tsf.2006.12.103","volume":"515","author":"Jimbo K.","year":"2007","journal-title":"Thin Solid Films"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"426","DOI":"10.1016\/j.tsf.2004.11.024","volume":"480","author":"Katagiri H.","year":"2005","journal-title":"Thin Solid Films"},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/S0927-0248(00)00088-X","volume":"65","author":"Katagiri H.","year":"2001","journal-title":"Sol. Energy Mater. Sol. Cells"},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"041201","DOI":"10.1143\/APEX.1.041201","volume":"1","author":"Katagiri H.","year":"2008","journal-title":"Appl. Phys. Express"},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"1978","DOI":"10.1016\/j.jpcs.2005.09.037","volume":"66","author":"Tanaka T.","year":"2005","journal-title":"J. Phys. Chem. Solids"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"5949","DOI":"10.1016\/j.tsf.2006.12.144","volume":"515","author":"Kamoun N.","year":"2007","journal-title":"Thin Solid Films"},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"1230","DOI":"10.1016\/j.solmat.2009.01.011","volume":"93","author":"Kumar Y. B. K.","year":"2009","journal-title":"Sol Energy Mater Sol. Cells"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"596","DOI":"10.1143\/JJAP.47.596","volume":"47","author":"Miyamoto Y.","year":"2008","journal-title":"Jpn. J. Appl. Phys."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"598","DOI":"10.1143\/JJAP.47.598","volume":"47","author":"Tanaka K.","year":"2008","journal-title":"Jpn. J. Appl. Phys."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"1199","DOI":"10.1016\/j.solmat.2007.04.012","volume":"91","author":"Tanaka K.","year":"2007","journal-title":"Sol. Energy Mater. Sol. Cells"},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"583","DOI":"10.1016\/j.solmat.2008.12.009","volume":"93","author":"Tanaka K.","year":"2009","journal-title":"Sol. Energy Mater. Sol. Cells"},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"2848","DOI":"10.1002\/pssc.200669588","volume":"3","author":"Moriya K.","year":"2006","journal-title":"Phys. Status Solidi C"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"3399","DOI":"10.1021\/cm100058q","volume":"22","author":"Fischereder A.","year":"2010","journal-title":"Chem. Mater."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"741108","DOI":"10.1117\/12.828172","volume":"7411","author":"Chan C. P.","year":"2009","journal-title":"Proc. SPIE"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"2511","DOI":"10.1016\/j.tsf.2008.11.061","volume":"517","author":"Ennaoui A.","year":"2009","journal-title":"Thin Solid Films"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"4057","DOI":"10.1016\/j.electacta.2010.02.051","volume":"55","author":"Pawar S. M.","year":"2010","journal-title":"Electrochim. Acta"},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.jelechem.2010.01.008","volume":"646","author":"Scragg J. J.","year":"2010","journal-title":"J. Electroanal. Chem."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"2481","DOI":"10.1016\/j.tsf.2008.11.022","volume":"517","author":"Scragg J. J.","year":"2009","journal-title":"Thin Solid Films"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"381","DOI":"10.1007\/s00339-008-4815-5","volume":"94","author":"Zhang X.","year":"2009","journal-title":"Appl. Phys. A"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1016\/j.solmat.2009.09.003","volume":"94","author":"Chan C. P.","year":"2010","journal-title":"Sol. Energy Mater. Sol. Cells"},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"E156","DOI":"10.1002\/adma.200904155","volume":"22","author":"Todorov T. K.","year":"2010","journal-title":"Adv. Mater."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"16770","DOI":"10.1021\/ja805845q","volume":"130","author":"Panthani M. G.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"252","DOI":"10.1149\/1.1390703","volume":"1","author":"Basol B. M.","year":"1998","journal-title":"Electrochem. Solid-State Lett."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"3134","DOI":"10.1021\/ja8080605","volume":"131","author":"Koo B.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"1962","DOI":"10.1021\/cm900363w","volume":"21","author":"Koo B.","year":"2009","journal-title":"Chem. Mater."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"6906","DOI":"10.1021\/cm801655w","volume":"20","author":"Tang J.","year":"2008","journal-title":"Chem. Mater."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"12054","DOI":"10.1021\/ja9044168","volume":"131","author":"Riha S. C.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"11672","DOI":"10.1021\/ja904981r","volume":"131","author":"Guo Q.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"4514","DOI":"10.1021\/ja909498c","volume":"132","author":"Shavel A.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"12554","DOI":"10.1021\/ja905922j","volume":"131","author":"Steinhagen C.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"3488","DOI":"10.1021\/nl802476m","volume":"8","author":"Luther J. M.","year":"2008","journal-title":"Nano Lett."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"5319","DOI":"10.1039\/c0jm00454e","volume":"20","author":"Kameyama T.","year":"2010","journal-title":"J. Mater. Chem."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1038\/35003535","volume":"404","author":"Peng X. G.","year":"2000","journal-title":"Nature"},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"3343","DOI":"10.1021\/ja0173167","volume":"124","author":"Peng Z. A.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"3893","DOI":"10.1021\/cr030027b","volume":"104","author":"Cushing B. L.","year":"2004","journal-title":"Chem. Rev."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1038\/nature02695","volume":"430","author":"Milliron D. J.","year":"2004","journal-title":"Nature"},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"664","DOI":"10.1038\/nature04165","volume":"437","author":"Yin Y.","year":"2004","journal-title":"Nature"},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"1960","DOI":"10.1021\/nl101284k","volume":"10","author":"Liu Y.","year":"2010","journal-title":"Nano Lett."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"271","DOI":"10.1021\/nn7003348","volume":"2","author":"Luther J. M.","year":"2008","journal-title":"ACS Nano"},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"5974","DOI":"10.1021\/ja800040c","volume":"130","author":"Law M.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref44\/cit44","volume-title":"Infrared Spectral Interpretation: A Systematic Approach","author":"Smith B.","year":"1999"},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"528","DOI":"10.1557\/JMR.1987.0528","volume":"2","author":"Ryan M. A.","year":"1987","journal-title":"J. Mater. Res."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"753","DOI":"10.1021\/cr00103a005","volume":"90","author":"Peter L. M.","year":"1990","journal-title":"Chem. Rev."},{"key":"ref47\/cit47","unstructured":"Films of each thickness were prepared and tested in triplicate from three different reaction batches of both stoichiometric and Zn-rich compositions. All sets showed similar trends between front and back illumination, in addtion to the maximum current for films around 300 nm. However, the magnitude of the IPCE values or photocurrent was not consistent, therefore we did not show error bars in our figures."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"977","DOI":"10.1021\/nl071588b","volume":"8","author":"Burke A.","year":"2008","journal-title":"Nano Lett."},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"1319","DOI":"10.1016\/j.electacta.2008.09.025","volume":"54","author":"Yu H.","year":"2009","journal-title":"Electrochim. Acta"}],"container-title":["ACS Applied Materials &amp; Interfaces"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/am1008584","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,22]],"date-time":"2023-04-22T08:50:05Z","timestamp":1682153405000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/am1008584"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,12,31]]},"references-count":49,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2011,1,26]]}},"alternative-id":["10.1021\/am1008584"],"URL":"https:\/\/doi.org\/10.1021\/am1008584","relation":{},"ISSN":["1944-8244","1944-8252"],"issn-type":[{"value":"1944-8244","type":"print"},{"value":"1944-8252","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,12,31]]}}}