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J.","year":"2004","journal-title":"Nano Lett."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"4260","DOI":"10.1021\/ac069419j","volume":"78","author":"Patolsky F.","year":"2006","journal-title":"Anal. Chem."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"2177","DOI":"10.1021\/nl9008474","volume":"9","author":"Yang F.","year":"2009","journal-title":"Nano Lett."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1038\/nmat2028","volume":"6","author":"Lu W.","year":"2007","journal-title":"Nat. Mater."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"3146","DOI":"10.1021\/nl801347x","volume":"8","author":"Lin Y.-F.","year":"2008","journal-title":"Nano Lett."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"1014","DOI":"10.1557\/JMR.1994.1014","volume":"9","author":"Al-Mawlawi D.","year":"1994","journal-title":"J. Mater. Res."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"2216","DOI":"10.1039\/B304021F","author":"Viau G.","year":"2003","journal-title":"Chem. Commun."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"14150","DOI":"10.1021\/jp0744782","volume":"111","author":"Navaladian S.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"8900","DOI":"10.1021\/ja803343m","volume":"130","author":"Lu X.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"1249","DOI":"10.1002\/adfm.200700953","volume":"18","author":"Wang H.","year":"2008","journal-title":"Adv. Funct. Mater."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"2020","DOI":"10.1021\/cm802481v","volume":"21","author":"Lazzara T. D.","year":"2009","journal-title":"Chem. Mater."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"617","DOI":"10.1039\/b100521i","author":"Jana N. R.","year":"2001","journal-title":"Chem. Commun."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"833","DOI":"10.1002\/1521-4095(20020605)14:11<833::AID-ADMA833>3.0.CO;2-K","volume":"14","author":"Sun Y.","year":"2002","journal-title":"Adv. Mater."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"667","DOI":"10.1021\/nl0341178","volume":"3","author":"Caswell K. K.","year":"2003","journal-title":"Nano Lett."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"1854","DOI":"10.1002\/adma.200602325","volume":"19","author":"Halder A.","year":"2007","journal-title":"Adv. Mater."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"9576","DOI":"10.1021\/ja073050d","volume":"129","author":"Mohanty P.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"7401","DOI":"10.1021\/ja00095a051","volume":"116","author":"Reetz M. T.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"837","DOI":"10.1021\/jp952291h","volume":"100","author":"Zoval J. V.","year":"1996","journal-title":"J. Phys. Chem."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"6661","DOI":"10.1021\/jp971656q","volume":"101","author":"Yu Y.-Y.","year":"1997","journal-title":"J. Phys. Chem. B"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"2927","DOI":"10.1039\/b310898h","volume":"13","author":"Carotenuto G.","year":"2003","journal-title":"J. Mater. Chem."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"1584","DOI":"10.1002\/chem.200701570","volume":"14","author":"Lu X.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"6169","DOI":"10.1021\/cm801634b","volume":"20","author":"Susha A. S.","year":"2008","journal-title":"Chem. Mater."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"801","DOI":"10.1039\/C39940000801","author":"Brust M.","year":"1994","journal-title":"Chem. Commun."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"9582","DOI":"10.1021\/ja104011b","volume":"132","author":"Goulet P. J. G.","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"16572","DOI":"10.1021\/ja803490n","volume":"130","author":"Marin M. L.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"5774","DOI":"10.1021\/cm051085b","volume":"17","author":"Corbierre M. K.","year":"2005","journal-title":"Chem. Mater."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"2628","DOI":"10.1021\/cm060235v","volume":"18","author":"Corbierre M. K.","year":"2006","journal-title":"Chem. Mater."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"1309","DOI":"10.1126\/science.1172104","volume":"324","author":"Zheng H.","year":"2009","journal-title":"Science"},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"2319","DOI":"10.1021\/nl051834o","volume":"5","author":"Murray B. J.","year":"2005","journal-title":"Nano Lett."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"508","DOI":"10.1021\/cm000763l","volume":"13","author":"Liu R.","year":"2001","journal-title":"Chem. Mater."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"13519","DOI":"10.1021\/jp051007b","volume":"109","author":"Xu L.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"11560","DOI":"10.1021\/jp071536a","volume":"111","author":"Xu L.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"2369","DOI":"10.1021\/ja067219j","volume":"129","author":"Nafady A.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"16195","DOI":"10.1021\/ja9063519","volume":"131","author":"Zhao C.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"3339","DOI":"10.1021\/jp013219o","volume":"106","author":"Penner R. M.","year":"2002","journal-title":"J. Phys. Chem. 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D.","year":"2010","journal-title":"ACS Nano"},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"3197","DOI":"10.1021\/la00060a046","volume":"7","author":"Bond A. M.","year":"1991","journal-title":"Langmuir"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"3573","DOI":"10.1021\/cm0341336","volume":"15","author":"Neufeld A. K.","year":"2003","journal-title":"Chem. Mater."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"4375","DOI":"10.1021\/cm060852j","volume":"18","author":"Nafady A.","year":"2006","journal-title":"Chem. Mater."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"604","DOI":"10.1002\/chem.200600172","volume":"13","author":"Xiao W.","year":"2007","journal-title":"Chem.\u2014Eur. J."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/j.elecom.2004.12.003","volume":"7","author":"Hasse U.","year":"2005","journal-title":"Electrochem. Commun."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","DOI":"10.1007\/b137048","volume-title":"Electrochemistry of Immobilized Particles and Droplets","author":"Scholz F.","year":"2005"},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"792","DOI":"10.1021\/j100863a002","volume":"71","author":"Bode D. D.","year":"1967","journal-title":"J. Phys. Chem."},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"6352","DOI":"10.1021\/jp0726539","volume":"112","author":"Bozzini B.","year":"2008","journal-title":"J. Phys. Chem. C"},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1021\/nl048204r","volume":"5","author":"Redmond P. L.","year":"2005","journal-title":"Nano Lett."},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1080\/08927020512331328716","volume":"31","author":"Malardier-Jugroot C.","year":"2005","journal-title":"Mol. Simul."},{"key":"ref53\/cit53","doi-asserted-by":"crossref","first-page":"10179","DOI":"10.1021\/la050888a","volume":"21","author":"Malardier-Jugroot C.","year":"2005","journal-title":"Langmuir"},{"key":"ref54\/cit54","volume-title":"CRC Handbook of Chemistry and Physics","author":"Lide D. R.","year":"2010","edition":"90"},{"key":"ref55\/cit55","doi-asserted-by":"crossref","first-page":"3968","DOI":"10.1021\/ic9714697","volume":"37","author":"Bowmaker G. A.","year":"1998","journal-title":"Inorg. Chem."},{"key":"ref56\/cit56","unstructured":"The reader might naturally question the safety issues related to the generation of CN\u2212in neutral aqueous media, which react with H+to form toxic HCN gas (HCN pKa= 9.21) as well as the generation of toxic (CN)2gas. However, (CN)2has a high solubility in water (>700 g\u00b7L\u22121\u21d4 13.5 M\u00b7L\u22121)a,bbecause of its hydrolysis (see theSI), and HCN is soluble in water.cThe quantity of HCN and (CN)2generated in this work is typically 0.25 \u03bcmol, corresponding to concentrations of ca. 50 \u03bcM\u00b7L\u22121. Scale-up of this process would require some precautions, and conducting these electrochemical reactions in neutral solutions in a fumehood is strongly advised."},{"key":"ref56\/cit56a","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1021\/cr50029a003","volume":"59","author":"Brotherton T. K.","year":"1959","journal-title":"Chem. Rev."},{"key":"ref56\/cit56b","doi-asserted-by":"crossref","DOI":"10.1201\/9780203490396","volume-title":"Handbook of Aqueous Solubility Data","author":"Yalkowsky S. H.","year":"2003"},{"key":"ref56\/cit56c","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1016\/0010-8545(82)85013-3","volume":"47","author":"Corain B.","year":"1982","journal-title":"Coord. Chem. Rev."},{"key":"ref57\/cit57","unstructured":"An additional electrochemical process is evident at slightly more anodic potentials. We are unable at the present time to provide an assignment for this peak."},{"key":"ref58\/cit58","doi-asserted-by":"crossref","first-page":"063722","DOI":"10.1063\/1.3226859","volume":"106","author":"Peterson M. S. M.","year":"2009","journal-title":"J. Appl. Phys."},{"key":"ref59\/cit59","doi-asserted-by":"crossref","first-page":"1901","DOI":"10.1126\/science.1066541","volume":"294","author":"Jin R.","year":"2001","journal-title":"Science"},{"key":"ref60\/cit60","doi-asserted-by":"crossref","first-page":"646","DOI":"10.1002\/smll.200801480","volume":"5","author":"Millstone J. E.","year":"2009","journal-title":"Small"},{"key":"ref61\/cit61","doi-asserted-by":"crossref","first-page":"1471","DOI":"10.1021\/ja003312a","volume":"123","author":"Malinsky M. D.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref62\/cit62","doi-asserted-by":"crossref","first-page":"6961","DOI":"10.1021\/jp036261n","volume":"108","author":"Haes A. J.","year":"2004","journal-title":"J. Phys. Chem. B"},{"key":"ref63\/cit63","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1002\/anie.200802248","volume":"48","author":"Xia Y.","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref64\/cit64","doi-asserted-by":"crossref","first-page":"2036","DOI":"10.1002\/anie.200604637","volume":"46","author":"Xue C.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref65\/cit65","doi-asserted-by":"crossref","first-page":"2005","DOI":"10.1002\/adfm.200800233","volume":"18","author":"Aherne D.","year":"2008","journal-title":"Adv. Funct. Mater."},{"key":"ref66\/cit66","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1016\/S0022-0728(83)80202-2","volume":"150","author":"Zei M. S.","year":"1983","journal-title":"J. Electroanal. Chem."},{"key":"ref67\/cit67","doi-asserted-by":"crossref","first-page":"3714","DOI":"10.1063\/1.1377627","volume":"78","author":"Chen X. Q.","year":"2001","journal-title":"Appl. Phys. Lett."},{"key":"ref68\/cit68","doi-asserted-by":"crossref","first-page":"915","DOI":"10.1021\/nl049659j","volume":"4","author":"Jin S.","year":"2004","journal-title":"Nano Lett."},{"key":"ref69\/cit69","doi-asserted-by":"crossref","first-page":"13244","DOI":"10.1021\/jp074156y","volume":"111","author":"Talapin D. V.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref70\/cit70","doi-asserted-by":"crossref","first-page":"791","DOI":"10.1016\/0010-938X(82)90014-2","volume":"22","author":"Wilhelm S. M.","year":"1982","journal-title":"Corros. Sci."},{"key":"ref71\/cit71","volume-title":"Atlas of Electrochemical Equilibria in Aqueous Solutions","author":"Pourbaix M.","year":"1974","edition":"2"},{"key":"ref72\/cit72","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1023\/A:1016529314840","volume":"32","author":"Reyes Cruz V.","year":"2002","journal-title":"J. Appl. 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