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Sci."},{"key":"ref15\/cit15","unstructured":"The dissolution protocol is based on the reaction of each ligand with CaCO3(calcite) in aqueous mixtures at specific pH values. In general, the procedure is as follows (details for each experiment are given in tabular form in theSupporting Information): A quantity of calcite (Mississippi Lime Co., Alton, IL; Brunauer\u2212Emmett\u2212Teller surface area 10.0 m2\/g) is suspended in deionized water. Then a quantity of the ligand is added as a solid, and the pH is adjusted with HCl or NaOH stock solutions to 5.4. The suspension is left under mild stirring for a specified time period (anywhere from 24 h to 10 days, depending on the experiment) and then filtered to isolate CaCO3, which did not dissolve. The latter is washed with deionized water, oven-dried, and weighed. On the basis of the initial and final CaCO3mass, the dissolution efficiency of each ligand is calculated. Control experiments (no ligands added) are also carried out."},{"key":"ref16\/cit16","unstructured":"See theSupporting Information."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"2056","DOI":"10.1107\/S0567740874006376","volume":"30","author":"Sheldrick B.","year":"1974","journal-title":"Acta Crystallogr."},{"key":"ref18\/cit18","unstructured":"X-ray data: X-ray diffraction data were collected on a SMART 1K CCD diffractometer at 293(2) K with Mo K\u03b1 (\u03bb = 0.710\u200973 \u00c5). Crystallographic details for Ca-CEPA: colorless plates (0.21 \u00d7 0.10 \u00d7 0.08 mm), monoclinic, space groupP21\/c, witha= 5.5362(6) \u00c5,b= 18.135(4) \u00c5,c= 7.915(2) \u00c5, \u03b2 = 95.013(17)\u00b0,V= 791.6(3) \u00c53, andZ= 4,dcalcd= 1.914 g\/cm3, total reflections 4817, refined reflections [Inet> 2\u03c3(Inet)] 1551, no. of parameters 126, R1 = 0.0249 (0.0278, all data), wR2 = 0.0689 (0.0702, all data), GOF = 1.072. Crystallographic details for Ca-MAL: colorless plates (0.40 \u00d7 0.35 \u00d7 0.04 mm), triclinic, space groupP1\u0305, witha= 6.32(3) \u00c5,b= 7.50(2) \u00c5,c= 9.06(3) \u00c5, \u03b1 = 97.4(3)\u00b0, \u03b2 = 97.2(3)\u00b0, \u03b3 = 93.24(18)\u00b0,V= 421(3) \u00c53, andZ= 2,dcalcd= 1.784 g\/cm3, total reflections 2011, refined reflections [Inet> 2\u03c3(Inet)] 1112, no. of parameters 122, R1 = 0.0685 (0.0710, all data), wR2 = 0.1818 (0.868, all data), GOF = 1.094. Crystallographic details for Sr-BTCA: colorless plates (0.17 \u00d7 0.14 \u00d7 0.08 mm), orthorhombic, space groupPbcn, witha= 11.286(3) \u00c5,b= 9.1194(17) \u00c5,c= 11.107(3) \u00c5,V=1143.2(5) \u00c53, andZ= 4,dcalcd= 2.067 g\/cm3, total reflections 6654, refined reflections [Inet> 2\u03c3(Inet)] 1084, no. of parameters 99, R1 = 0.0254 (0.0314, all data), wR2 = 0.0660 (0.0684, all data), GOF = 1.073."},{"key":"ref19\/cit19a","doi-asserted-by":"crossref","first-page":"1335","DOI":"10.1021\/cg0500829","volume":"5","author":"Zhang X.-M.","year":"2005","journal-title":"Cryst. Growth Des."},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1016\/j.jssc.2004.10.047","volume":"178","author":"Anillo A.","year":"2005","journal-title":"J. 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