{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T05:20:24Z","timestamp":1789881624889,"version":"4.0.1"},"reference-count":51,"publisher":"American Chemical Society (ACS)","issue":"10","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Acc. Chem. Res."],"published-print":{"date-parts":[[2005,10,1]]},"DOI":"10.1021\/ar050089j","type":"journal-article","created":{"date-parts":[[2005,10,18]],"date-time":"2005-10-18T04:15:54Z","timestamp":1129608954000},"page":"794-802","source":"Crossref","is-referenced-by-count":129,"title":["Evolution of Functional Cyclohexadiene-Based Synthetic Reagents:\u2009 The Importance of Becoming Aromatic"],"prefix":"10.1021","volume":"38","author":[{"given":"John C.","family":"Walton","sequence":"first","affiliation":[{"name":"School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, U.K., and Organisch-Chemisches Institut, Westf\u00e4lische Wilhelms-Universit\u00e4t, Corrensstrasse 40, 48149 M\u00fcnster, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Armido","family":"Studer","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, U.K., and Organisch-Chemisches Institut, Westf\u00e4lische Wilhelms-Universit\u00e4t, Corrensstrasse 40, 48149 M\u00fcnster, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2005,8,13]]},"reference":[{"key":"ar050089jb00001\/ar050089jb00001_1","doi-asserted-by":"crossref","first-page":"3082","DOI":"10.1002\/(SICI)1521-3773(19981204)37:22<3072::AID-ANIE3072>3.0.CO;2-9","volume":"37","author":"Baguley P. A.","year":"1998","journal-title":"Angew. Chem., Int. Ed."},{"key":"ar050089jb00002\/ar050089jb00002_1","volume-title":"Free Radical Chain Reactions in Organic Synthesis","author":"Motherwell W. B.","year":"1992"},{"key":"ar050089jb00002\/ar050089jb00002_2","doi-asserted-by":"crossref","DOI":"10.1002\/9783527618293","volume-title":"Radicals in Organic Synthesis","author":"Renaud P.","year":"2001"},{"key":"ar050089jb00002\/ar050089jb00002_3","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198502418.001.0001","volume-title":"Radical Reactions in Organic Synthesis","author":"Zard S. Z.","year":"2003"},{"key":"ar050089jb00002\/ar050089jb00002_4","volume-title":"Advanced Free Radical Reactions for Organic Synthesis","author":"Togo H.","year":"2004"},{"key":"ar050089jb00003\/ar050089jb00003_1","first-page":"849","volume":"835","author":"Studer A.","year":"2002","journal-title":"Synthesis"},{"key":"ar050089jb00004\/ar050089jb00004_1","first-page":"349","volume":"32","author":"Laarhoven L. J. J.","year":"1999","journal-title":"Acc. Chem. Res."},{"key":"ar050089jb00005\/ar050089jb00005_1","doi-asserted-by":"crossref","first-page":"1155","DOI":"10.1021\/j100278a039","volume":"90","author":"Tsang W","year":"1986","journal-title":"J. Phys. Chem."},{"key":"ar050089jb00005\/ar050089jb00005_2","doi-asserted-by":"crossref","first-page":"6381","DOI":"10.1021\/ja9837102","volume":"121","author":"Ciriano M. V.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ar050089jb00006\/ar050089jb00006_1","first-page":"28","volume":"27","author":"Binmore G.","year":"1995","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ar050089jb00007\/ar050089jb00007_1","first-page":"762","volume":"757","author":"Binmore G.","year":"1997","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ar050089jb00008\/ar050089jb00008_1","first-page":"2200","volume":"2199","author":"Baguley P. A.","year":"1996","journal-title":"Chem. Commun."},{"key":"ar050089jb00008\/ar050089jb00008_2","first-page":"2082","volume":"2073","author":"Baguley P. A.","year":"1998","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"ar050089jb00010\/ar050089jb00010_1","first-page":"309","volume":"304","author":"Baguley P. A.","year":"2002","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"ar050089jb00011\/ar050089jb00011_1","doi-asserted-by":"crossref","first-page":"2067","DOI":"10.1021\/cr9601425","volume":"99","author":"Chatgilialoglu C.","year":"1999","journal-title":"Chem. Rev."},{"key":"ar050089jb00012\/ar050089jb00012_1","first-page":"2328","volume":"2327","author":"Jackson L. V.","year":"2000","journal-title":"Chem. Commun."},{"key":"ar050089jb00012\/ar050089jb00012_2","first-page":"428","volume":"2","author":"Bella A. F.","year":"2004","journal-title":"Org. Biomol. Chem."},{"key":"ar050089jb00013\/ar050089jb00013_1","doi-asserted-by":"crossref","first-page":"35","DOI":"10.1039\/a804291h","volume":"28","author":"Roberts B. P","year":"1999","journal-title":"Chem. Soc. Rev."},{"key":"ar050089jb00013\/ar050089jb00013_2","first-page":"2068","volume":"2061","author":"Dang H.-S.","year":"1999","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"ar050089jb00013\/ar050089jb00013_3","doi-asserted-by":"crossref","first-page":"4064","DOI":"10.1016\/S0040-4039(01)00630-X","volume":"42","author":"Fielding A. J.","year":"2001","journal-title":"Tetrahedron Lett."},{"key":"ar050089jb00014\/ar050089jb00014_1","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1071\/CH9950291","volume":"48","author":"Tomaszewski M. J.","year":"1995","journal-title":"Aust. J. Chem."},{"key":"ar050089jb00015\/ar050089jb00015_1","doi-asserted-by":"crossref","first-page":"17594","DOI":"10.1016\/S0040-4020(97)10060-6","volume":"53","author":"Fallis A. G.","year":"1997","journal-title":"Tetrahedron"},{"key":"ar050089jb00015\/ar050089jb00015_2","doi-asserted-by":"crossref","first-page":"5496","DOI":"10.1016\/S0040-4020(01)00384-2","volume":"57","author":"Friestad G. K","year":"2001","journal-title":"Tetrahedron"},{"key":"ar050089jb00015\/ar050089jb00015_3","doi-asserted-by":"crossref","first-page":"541","DOI":"10.3987\/REV-98-SR(H)2","volume":"50","author":"Naito T","year":"1999","journal-title":"Heterocycles"},{"key":"ar050089jb00016\/ar050089jb00016_1","doi-asserted-by":"crossref","first-page":"5933","DOI":"10.1021\/jo049617f","volume":"69","author":"Bella A. F.","year":"2004","journal-title":"J. Org. Chem."},{"key":"ar050089jb00017\/ar050089jb00017_1","doi-asserted-by":"crossref","first-page":"3082","DOI":"10.1002\/1521-3773(20000901)39:17<3082::AID-ANIE3082>3.0.CO;2-2","volume":"39","author":"Studer A.","year":"2000","journal-title":"Angew. Chem., Int. Ed."},{"key":"ar050089jb00017\/ar050089jb00017_2","doi-asserted-by":"crossref","first-page":"5733","DOI":"10.1021\/ja0341743","volume":"125","author":"Studer A.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ar050089jb00018\/ar050089jb00018_1","doi-asserted-by":"crossref","first-page":"4101","DOI":"10.1002\/1521-3773(20021104)41:21<4098::AID-ANIE4098>3.0.CO;2-P","volume":"41","author":"Fettes A.","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"ar050089jb00019\/ar050089jb00019_1","doi-asserted-by":"crossref","first-page":"2360","DOI":"10.1021\/ol016160c","volume":"3","author":"Amrein S.","year":"2001","journal-title":"Org. Lett."},{"key":"ar050089jb00019\/ar050089jb00019_2","doi-asserted-by":"crossref","first-page":"3573","DOI":"10.1002\/1522-2675(200210)85:10<3559::AID-HLCA3559>3.0.CO;2-6","volume":"85","author":"Amrein S.","year":"2002","journal-title":"Helv. Chim. Acta"},{"key":"ar050089jb00020\/ar050089jb00020_1","first-page":"1593","volume":"1592","author":"Amrein S.","year":"2002","journal-title":"Chem. Commun."},{"key":"ar050089jb00021\/ar050089jb00021_1","doi-asserted-by":"crossref","first-page":"960","DOI":"10.1016\/0040-4020(89)80007-9","volume":"45","author":"Neumann W. P.","year":"1989","journal-title":"Tetrahedron"},{"key":"ar050089jb00022\/ar050089jb00022_1","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1002\/9783527618293.ch45","volume-title":"Radicals in Organic Synthesis","volume":"2","author":"Stella","year":"2001"},{"key":"ar050089jb00023\/ar050089jb00023_1","first-page":"703","volume":"98","author":"M\u00fcller T. E.","year":"1998","journal-title":"Chem. Rev."},{"key":"ar050089jb00024\/ar050089jb00024_1","doi-asserted-by":"crossref","first-page":"4917","DOI":"10.1002\/anie.200463032","volume":"44","author":"Kemper J.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ar050089jb00025\/ar050089jb00025_1","doi-asserted-by":"crossref","first-page":"200","DOI":"10.1021\/ar50151a002","volume":"13","author":"Griller D.","year":"1980","journal-title":"Acc. Chem. Res."},{"key":"ar050089jb00026\/ar050089jb00026_1","first-page":"2164","volume":"61","author":"Schuh H. H.","year":"1978","journal-title":"Helv. Chim. Acta"},{"key":"ar050089jb00027\/ar050089jb00027_1","first-page":"450","volume":"443","author":"Maillard B.","year":"1985","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ar050089jb00028\/ar050089jb00028_1","first-page":"1764","volume":"1758","author":"Jackson L. V.","year":"2001","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ar050089jb00029\/ar050089jb00029_1","first-page":"1843","volume":"1839","author":"Bella A. F.","year":"2002","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ar050089jb00030\/ar050089jb00030_1","doi-asserted-by":"crossref","first-page":"1597","DOI":"10.1021\/ja00894a013","volume":"85","author":"Walling C.","year":"1963","journal-title":"J. Am. Chem. Soc."},{"key":"ar050089jb00031\/ar050089jb00031_1","doi-asserted-by":"crossref","unstructured":"Newcomb, M. Competition methods and scales for alkyl-radical reaction kinetics.Tetrahedron1993,49, 1151\u22121176. Newcomb, M. InRadicals inOrganic Synthesis; Renaud, P., Sibi, M. P., Eds.; Wiley-VCH:\u2009 Weinheim, Germany, 2001; Vol. 1, p 317.","DOI":"10.1016\/S0040-4020(01)85808-7"},{"key":"ar050089jb00032\/ar050089jb00032_1","doi-asserted-by":"crossref","first-page":"6068","DOI":"10.1021\/ja00539a016","volume":"102","author":"Effio A.","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"ar050089jb00033\/ar050089jb00033_1","doi-asserted-by":"crossref","first-page":"1219","DOI":"10.1002\/kin.550171107","volume":"17","author":"Hawari J. A.","year":"1985","journal-title":"Int. J. Chem. Kinet."},{"key":"ar050089jb00034\/ar050089jb00034_1","first-page":"4134","volume":"108","author":"Newcomb M.","year":"1986","journal-title":"Measurements of rate constants for hydrogen-atom-abstraction reactions. J. Am. Chem. Soc."},{"key":"ar050089jb00035\/ar050089jb00035_1","first-page":"7742","volume":"103","author":"Chatgilialoglu C.","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"ar050089jb00036\/ar050089jb00036_1","doi-asserted-by":"crossref","first-page":"6403","DOI":"10.1021\/jo00022a035","volume":"56","author":"Chatgilialoglu C.","year":"1991","journal-title":"J. Org. Chem."},{"key":"ar050089jb00037\/ar050089jb00037_1","doi-asserted-by":"crossref","first-page":"3580","DOI":"10.1021\/ja00349a037","volume":"105","author":"Lusztyk J.","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"ar050089jb00038\/ar050089jb00038_1","first-page":"1429","volume":"1423","author":"Baguley P. A.","year":"1998","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ar050089jb00039\/ar050089jb00039_1","doi-asserted-by":"crossref","first-page":"4280","DOI":"10.1016\/S0040-4020(03)00632-X","volume":"59","author":"McCarroll A. J.","year":"2003","journal-title":"Tetrahedron"},{"key":"ar050089jb00040\/ar050089jb00040_1","doi-asserted-by":"crossref","first-page":"2041","DOI":"10.1021\/jo035477i","volume":"69","author":"Vaillard S. E.","year":"2004","journal-title":"J. Org. Chem."}],"container-title":["Accounts of Chemical Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ar050089j","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,31]],"date-time":"2024-01-31T02:13:17Z","timestamp":1706667197000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ar050089j"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,8,13]]},"references-count":51,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2005,10,1]]}},"alternative-id":["10.1021\/ar050089j"],"URL":"https:\/\/doi.org\/10.1021\/ar050089j","relation":{},"ISSN":["0001-4842","1520-4898"],"issn-type":[{"value":"0001-4842","type":"print"},{"value":"1520-4898","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,8,13]]}}}