{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T12:08:53Z","timestamp":1790251733331,"version":"4.1.0"},"reference-count":42,"publisher":"American Chemical Society (ACS)","issue":"9","license":[{"start":{"date-parts":[[2026,6,25]],"date-time":"2026-06-25T00:00:00Z","timestamp":1782345600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278366"],"award-info":[{"award-number":["22278366"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22578394"],"award-info":[{"award-number":["22578394"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Plasma\u2013electrocatalytic cascade ammonia synthesis offers a promising route for decentralized nitrogen fixation, yet remains hindered by excessive NO3\u2013 formation and poor energy matching between the two stages. Here, we propose a strategy that breaks this bottleneck by selectively generating NO2\u2013 via spark-discharge plasma and efficiently reducing it over a CuRu0.5 nanoalloy. Systematic optimization of the plasma discharge and electrocatalytic interface enables synergistic energy matching, delivering a record-low specific energy consumption of 273.41 kWh\/kg NH3. Mechanistic studies reveal that Ru modulates the electronic structure of Cu, enhancing NO2\u2013 adsorption and deoxygenation while suppressing the hydrogen evolution reaction. This work establishes a generalized paradigm for low-energy, high-selectivity ammonia synthesis from air and water.<\/jats:p>","DOI":"10.1021\/cbe.6c00044","type":"journal-article","created":{"date-parts":[[2026,6,25]],"date-time":"2026-06-25T04:07:02Z","timestamp":1782360422000},"page":"780-792","source":"Crossref","is-referenced-by-count":0,"title":["Energy-Efficient Cascade\nSynthesis of Ammonia from\nAir via Spark Plasma-Mediated Nitrite Generation and CuRu Nanoalloy\nElectrocatalysis"],"prefix":"10.1021","volume":"3","author":[{"given":"Jian","family":"Sun","sequence":"first","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310027"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Wu","sequence":"additional","affiliation":[{"name":"Zhejiang Ecological Environment Group Co. Ltd. , ,","place":["Hangzhou, China, 310012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heyang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310027"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuyue","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Zhejiang University \u2013 Quzhou , ,","place":["Quzhou, China, 324000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3048-4678","authenticated-orcid":true,"given":"Shaodong","family":"Zhou","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310027"]},{"name":"Institute of Zhejiang University \u2013 Quzhou , ,","place":["Quzhou, China, 324000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3685-381X","authenticated-orcid":true,"given":"Zhongjian","family":"Li","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310027"]},{"name":"Institute of Zhejiang University \u2013 Quzhou , ,","place":["Quzhou, China, 324000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lecheng","family":"Lei","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310027"]},{"name":"Institute of Zhejiang University \u2013 Quzhou , ,","place":["Quzhou, China, 324000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5136-9743","authenticated-orcid":true,"given":"Bin","family":"Yang","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310027"]},{"name":"Institute of Zhejiang University \u2013 Quzhou , ,","place":["Quzhou, China, 324000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,6,25]]},"reference":[{"key":"2026092407080850600_cit1","doi-asserted-by":"publisher","first-page":"1055","DOI":"10.1016\/j.joule.2018.04.017","article-title":"Greening Ammonia toward the Solar Ammonia Refinery","volume":"2","author":"Wang","year":"2018","journal-title":"Joule"},{"key":"2026092407080850600_cit2","doi-asserted-by":"publisher","first-page":"3676","DOI":"10.1021\/acsenergylett.1c01614","article-title":"Ammonia and Nitric\nAcid Demands for Fertilizer Use in 2050","volume":"6","author":"Lim","year":"2021","journal-title":"ACS\nEnergy Lett."},{"key":"2026092407080850600_cit3","doi-asserted-by":"publisher","first-page":"1186","DOI":"10.1016\/j.joule.2020.04.004","article-title":"A Roadmap to the\nAmmonia Economy","volume":"4","author":"MacFarlane","year":"2020","journal-title":"Joule"},{"key":"2026092407080850600_cit4","first-page":"1","article-title":"Industrial\nAmmonia Production Emits More CO2 than Any Other Chemical-Making\nReaction","volume":"97","author":"Boerner","year":"2019","journal-title":"Chem. 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